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Variations of carbon and oxygen isotopic ratios in response to cyclical sea level fluctuations have been documented from a Paleoproterozoic peritidal stromatolite succession. The upper division of the Kajrahat Limestone, Vindhyan Supergroup of central India consists of several shallowing upward stromatolite cycles identified by regular and systematic changes in stromatolite size. Normally, larger stromatolites are followed upward in the succession by smaller stromatolites and microbial laminites that occupy the top of the cycle. Desiccation cracks are found in all the facies indicating subaerial exposure. We investigated the stable isotope compositional variations across nine complete stromatolite cycles showing frequent subaerial emergence. Carbon and oxygen isotopic values of the limestones, in general, are comparable to contemporary marine values available from earlier studies but show regular depletion in response to shallowing of the water level. The δ13C and δ18O values of the limestones vary within an individual stromatolite cycle; depleted values characterize the topmost part of the cycles. The isotope pattern is explained by micritic carbonate deposition in different sub environments of the shallow marine domain having different salinity and variable duration of exposure. These variations also probably caused the observed scatter in δ13C and δ18O values of supratidal microbial laminites.  相似文献   
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In laboratory experiments the interactions of ammonia with ice crystals were studied within the temperature range between 0 and −20°C. In a first series of experiments dendritic ice crystals were grown from water vapor in presence of ammonia gas in various concentrations between 4 and 400 ppbv. In a second series of experiments pure ice crystals were exposed to a humidified ammonia–air mixture inside a horizontal flow tube. The influence of temperature, ammonia gas concentration (0.6, 1.5, and 10 ppmv), exposure time, and the presence of impurities such as sulfate on the ammonia uptake by the ice surface was investigated by determining the ammonium content in the melt water of the ice crystals by ion chromatography. During the growth of ice crystals significant amounts of ammonia (around 200 μg/l) were taken up even at small gas concentrations. In contrast, even at high gas concentrations the uptake of ammonia by non-growing ice crystals was lower by approximately one order of magnitude. The presence of sulfate on the ice surface affected an enhanced uptake of ammonia by a factor of 5–10. A model is presented which describes the uptake of ammonia by ice considering the chemical processes occurring in the ice surface layer and simultaneous diffusion of ammonia into bulk ice. Even the increased uptake of ammonia by growing ice is rather small compared to the uptake by water droplets; thus, the major process for scavenging of ammonia from the atmosphere via the ice phase might not be the direct uptake by ice crystals but the riming involving super-cooled droplets containing ammonia.  相似文献   
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Batch kinetic studies were carried out for the removal of safranin from aqueous solution using a biomatrix prepared from rice husk. The adsorption kinetic data were modeled using the pseudo‐first‐order and pseudo‐second‐order kinetic equations. The linear and non‐linear forms of these two widely used kinetic models were compared in this study. In order to determine the best‐fitting equation, the coefficient of determination (r2), the sum of the squares of the errors (SSE), sum of the absolute errors (SAE), average relative error (ARE), hybrid fractional error function (HYBRID), Marquardt's percent standard deviation (MPSD), and the Chi‐squared test (χ2) were used as error analysis methods. Results showed that the non‐linear forms of pseudo‐first‐order and pseudo‐second‐order models were more suitable than the linear forms for fitting the experimental data. Non‐linear method is thus more appropriate for estimating the kinetic parameters and should primarily be used to describe adsorption kinetics.  相似文献   
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Fossil leaf impressions and pollen grains comparable to modern Sloanea sp. of Elaeocarpaceae collected from the middle part of the Siwalik sediments (Geabdat Sandstone Formation; Pliocene) in Darjeeling foothills of eastern Himalaya are reported in the present communication. On the basis of macro morphological features, leaf remains are described as a new species Sloanea siwalika sp. nov. This is the first authentic record of the occurrence of leaf and pollen grains comparable to the genus Sloanea L. from the Cenozoic sediments of India and Asia as well. The recovery of this species and other earlier-described evergreen taxa from the same formation, suggests the existence of a tropical, warm and humid climatic conditions during the depositional period. The present study further suggests that after Pliocene the taxon might have shifted from Darjeeling Himalayan region to the adjoining southeast Asian land masses, due to possible climate change caused by post-Pliocene orogenic movement of the Himalaya.  相似文献   
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Demand for irrigation water increases day by day along with meteorological vagaries and extension of irrigated area in the drought-prone Barind area of Bangladesh. This increasing stress on water resource is gradually making the area water scare. The study is aimed at studying the morphometric parameters of the Atrai-Sib river basin in the Barind area and on their relevance in water resource management based on satellite images and SRTM DEM. Computation and delineation of linear and areal aspects of the river basin and its morphometric components reveals that stream order ranges from first to eighth order showing dendritic drainage pattern. The basin represents homogeneity of soil texture; possibility of flash flood after heavy rainfall with low discharge of runoff; and is not largely affected by structural disturbance. Moderate drainage density of the river basin area indicates semipermeable soil lithology with moderate vegetation. Mean bifurcation ratio of the basin is calculated as 3.92 and elongation ratio 0.75, which indicate elongated shape of the river basin with low to moderate relief bounded in the east and west by ‘moderate to steep’ sloping land area. It reveals a flatter peak of runoff flow for longer duration and gravity flow of water. The gentle but undulating slope of the basin represents ‘excellent’ category for groundwater management as the site is favorable for infiltration due to maximum time of runoff water percolation. The east facing slopes of the basin show higher moisture content and higher vegetation than the west-facing slope. The land use pattern of the area shows that major part (95.29%) comes under the cultivated land which will support future river basin development and management. Results obtained from the study would be useful in categorization of river basins for future water resource development and management, and selection of suitable sites for water conservation structures such as check dam, percolation tank, artificial recharge of groundwater through MAR technique etc.  相似文献   
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Understanding groundwater salinity sources in the Gulf Coast Aquifer System (GCAS) is a critical issue due to depletion of fresh groundwater and concerns for potential seawater intrusion. The study objective was to assess sources of groundwater salinity in the GCAS using ~1,400 chemical analyses and ~90 isotopic analyses along nine well transects in the Texas Gulf Coast, USA. Salinity increases from northeast (median total dissolved solids (TDS) 340 mg/L) to southwest (median TDS 1,160 mg/L), which inversely correlates with the precipitation distribution pattern (1,370– 600 mm/yr, respectively). Molar Cl/Br ratios (median 540–600), depleted δ2H and δ18O (?24.7‰, ?4.5‰) relative to seawater (Cl/Br ~655 and δ2H, δ18O 0‰, 0‰, respectively), and elevated 36Cl/Cl ratios (~100), suggest precipitation enriched with marine aerosols as the dominant salinity source. Mass balance estimates suggest that marine aerosols could adequately explain salt loading over the large expanse of the GCAS. Evapotranspiration enrichment to the southwest is supported by elevated chloride concentrations in soil profiles and higher δ18O. Secondary salinity sources include dissolution of salt domes or upwelling brines from geopressured zones along growth faults, mainly near the coast in the northeast. The regional extent and large quantities of brackish water have the potential to support moderate-sized desalination plants in this location. These results have important implications for groundwater management, suggesting a current lack of regional seawater intrusion and a suitable source of relatively low TDS water for desalination.  相似文献   
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