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101.
A new model for Archaean granitoid magmatism is presented which reconciles the most important geochemical similarities and differences between tonalite–trondhjemite–granodiorite (TTG) and potassic granitoids. Trace element abundances reveal a strong arc magmatism signature in all studied granitoids from Barberton Mountain Land. Characteristic features include HFSE depletion as well as distinct enrichment peaks of fluid-sensitive trace elements such as Pb in N-MORB normalisation, clearly indicating that all studied granitoids are derived from refertilised mantle above subduction zones. We envisage hydrous basaltic (s.l.) melts as parental liquids, which underwent extensive fractional crystallisation. Distinctive residual cumulates evolved depending on initial water content. High-H2O melts crystallised garnet/amphibole together with pyroxenes and minor plagioclase, but no olivine. This fractionation path ultimately led to TTG-like melts. Less hydrous basaltic melts also crystallised garnet/amphibole, but the lower compatible element content indicates that olivine was also a liquidus phase. Pronounced negative Eu-anomalies of the granitic melts, correlating with Na, Ca and Al, indicate plagioclase to be of major importance. In the context of our model, the post-Archaean disappearance of TTG and concomitant preponderance of granites (s.l.), therefore, is explained with secular decrease of aqueous fluid transport into subduction zones and/or efficiency of deep fluid release from slabs.  相似文献   
102.
This paper examines how people explain reasons and impacts of environmental change in the low-rain savanna of the central Sudan and mountainous forest lands of northern Thailand. The explanations are analyzed by using the concept of environmental literacy, which refers to the people’s ability to grasp the environment and its interactions. The paper aims to study people’s conceptions of the environment, which compose one factor in directing their behavior. For the study, rural inhabitants in the State of North Kordofan, the Sudan, and the Chiang Mai Province in Thailand were interviewed.It was noted that an individual’s capability to understand the environment is alone insufficient to address environmental problems because the efficient alleviation of the problems requires collective actions at all levels, and because of factors beyond an individual’s control. However, the results supported the assumption that the local people have knowledge of their environment that may help in developing sustainable environmental management practices. The main advantages of using the environmental literacy concept are argued to be its dynamic and synthetic essence, its link to sustainable behavior, and wide applicability in various contexts within heterogeneous communities.  相似文献   
103.
We present data for the rare earth elements and yttrium (REY) in the National Research Council of Canada natural river water reference material SLRS-4 and 19 natural river waters from small catchments in South-East Queensland, Australia, by a direct ICP-MS method. The 0.22 μm filtered river water samples show a large degree of variability in both the REY concentration, e.g., La varies from 13 to 1157 ppt, and shape of the alluvial-sediment-normalised REY patterns with different samples displaying light, middle or heavy rare earth enrichment. In addition, a spatial study was undertaken along the freshwater section of Beerburrum Creek, which demonstrates that ~75% of the total REYs in this waterway are removed prior to estuarine mixing without evidence of fractionation.  相似文献   
104.
We present new whole rock trace element and Pb-isotope data for a suite of Neogene adakitic rocks that formed during the post-collisional stage of the India-Asia collision in an east-west- trending array along the Yalu Tsangpo suture. Compared to classic ‘adakites’ that form along certain active convergent plate margins, the Tibetan adakitic rocks show even stronger enrichment in incompatible elements (i.e. Rb, Ba, Th, K and LREEs) and even larger variation in radiogenic (Pb, Sr, Nd) isotope ratios. Tibetan adakitic rocks have extraordinarily low HREE (Yb: 0.34–0.61 ppm) and Y (3.71–6.79 ppm), high Sr/Y (66–196), high Dyn/Ybn and Lan/Ybn. They show strong evidence of binary mixing both in isotopic space (Sr-Nd, common Pb, thorogenic Pb) and trace element systematics. The majority of the adakitic rocks in south Tibet, including published and our new data, have variational Mg# (0.32–0.70), clear Nb (and HFSE) enrichment, the lowest initial 87Sr/86Sr and 206Pb/204Pb ratios, and the highest 144Nd/143Nd ratios of all Neogene volcanic rocks in south Tibet. These results indicate an involvement of slab melts in petrogenesis. Major and trace element characteristics of the isotopically more enriched adakites are compatible with derivation from subducted sediment but not with assimilation of crustal material. Thus, the south Tibetan adakitic magmas are inferred to have been derived from an upper mantle source metasomatised by slab-derived melts. An interesting observation is that temporally coeval and spatially related lamproites could be genetically related to the adakitic rocks in representing partial melts of distinct mantle domains metasomatised by subducted sediment. Our favoured geodynamic interpretation is that along-strike variation in south Tibetan post-collisional magma compositions may be related to release of slab melts and fluids along the former subduction zone resulting in compositionally distinct mantle domains.  相似文献   
105.
Aircraft observations of the atmospheric boundary layer (ABL) over Arctic sea ice were made during non-stationary conditions of cold-air advection with a cloud edge retreating through the study region. The sea-ice concentration, roughness, and ABL stratification varied in space. In the ABL heat budget, 80% of the Eulerian change in time was explained by cold-air advection and 20% by diabatic heating. With the cloud cover and inflow potential temperature profile prescribed as a function of time, the air temperature and near-surface fluxes of heat and momentum were well simulated by the applied two-dimensional mesoscale model. Model sensitivity tests demonstrated that several factors can be active in generating unstable stratification in the ABL over the Arctic sea ice in March. In this case, the upward sensible heat flux resulted from the combined effect of clouds, leads, and cold-air advection. These three factors interacted non-linearly with each other. From the point of view of ABL temperatures, the lead effect was far less important than the cloud effect, which influenced the temperature profiles via cloud-top radiative cooling and radiative heating of the snow surface. The steady-state simulations demonstrated that under overcast skies the evolution towards a deep, well-mixed ABL may take place through the merging of two mixed layers one related to mostly shear-driven surface mixing and the other to buoyancy-driven top-down mixing due to cloud-top radiative cooling.  相似文献   
106.
An SEM, REE, and mineral Sm-Nd isotope study on olivine-plagioclase coronas in the Vestre Dale gabbro, Norway, was carried out in order to solve the temporal relationships within these coronas. It is demonstrated that in contrast to common models, corona formation is a multistage, late-magmatic process, starting with the formation of orthopyroxene by (partial) dissolution of olivine, followed by the nucleation and rapid outward growth of orthopyroxene+spinel symplectites at its outer margin, and concluded by replacement of this precursory outer shell by calcic amphibole. Isotopic equilibrium between inner shell orthopyroxene and the magmatic assemblage, and the REE contents of orthopyroxene and outer shell amphibole also provide strong arguments for a magmatic origin, with the local availability of fractionated magma acting as a limiting factor. The absence of replacement of intercumulus clinopyroxene by amphibole also favours a late stage magmatic rather than a metamorphic origin for corona amphibole.  相似文献   
107.
Old geochemical datasets from the Paraná Shield of southern Brazil have been integrated into a new geochemical database and the results are presented as a series of multipurpose geochemical maps. Although the 24 datasets retrieved were analysed by three different laboratories, the maps produced correlate surprisingly well with bedrock geological features.The retrieval of old geochemical exploration data sets for the purpose of generating maps showing element depletions and enrichments is a powerful tool with a wide range of applications: trace elements such as Zn, Cu and Mo can significantly affect crop productivity; areas with high abundances of harmful elements such as As and F can be delineated in order to identify public health hazards; heavy metals such as Cd, Pb and Hg can be measured in order to better constrain knowledge of chemical background levels for environmental monitoring. The integration and manipulation of different data sets can however be complicated by the heterogeneity in sampling and analytical procedures.  相似文献   
108.
In this study we estimated the amount of carbon (C) stored in the forest growing stock and in wood-based products, and the C-sequestration capacity of the forest sector in Finland. Comparison of different management and utilization options for forest resources over the period 1990-2039 indicates that C is stored more efficiently in standing timber than in wood-based products. This implies that an appropriate increase in the length of the rotation in forestry could be optimal for balancing the needs of forest resources for C sequestration and timber production. Increased use of wood, based on sustainable use of forest resources, to substitute for fossil fuels and materials, could decrease the overall C emissions. Release of sequestered C back to the atmosphere can be delayed by prolonging product lifespans, by increasing recycling, or by disposing of discarded products in landfills. To delay C release, and affect the C balance, however, these changes should be substantial.In 1990, the net C balance of the growing stemwood stock was 5.5 Tg C/a, which increased to 16.3 Tg C/a by 2039 if in the future the use of wood would be at the level of the late 1980s. Increased use of wood resulted in a balance of 6.6 Tg C/a or -0.2 Tg C/a, depending on the extent of the use of wood. The average C balance in wood products for the whole period was 3.9, 5.6 or 6.6 Tg C/a, respectively. Changes in production capacity, and consideration of timber and product import and export decreased the average balance from 6.6 Tg C/a to 0.9–1.3 Tg C/a. By comparison, emission from the use of fossil fuels in 1990 C was 14.5 Tg C/a.  相似文献   
109.
Boundary-Layer Meteorology - We characterize the turbulent flow, using direct numerical simulations (DNS), within a closed channel between two parallel walls with a canopy of constant areal density...  相似文献   
110.
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