Volatile inventories on Mars     

Tobias Owen 《Icarus》1976,28(2):171-177

Predictions for the total inventory of outgassed volatiles on Mars can be developed by studying volatiles in meteorites, terrestial rocks, and the atmospheres of Venus, the Moon, and the Earth. Two models are presented following the basic assumption that the devolatilization of Mars has been analogous to that of the Earth. The recent discovery of a high abundance of argon in the Martian atmosphere appears to indicate that Mars has outgassed as completely as the Earth, but present uncertainties and lacunae in the essential data set permit several other interpretations.  相似文献   

STATE ATLASES: FUNDING SOURCES AND THEMATIC CONTENT*   总被引：1，自引：0，他引：1  

Robert B. Kent  Thomas J. Tobias 《The Professional geographer》1990,42(3):313-323

Is the thematic content of state atlases influenced by the primary sources of atlas funding, private or public? Maps portraying economic conditions, the physical environment, and population dominated state atlases produced between 1970 and 1986, accounting for over 80% of all thematic content. Funding sources effected modest differences in content. Publicly funded state atlases devoted more attention to introductory, physical, and cultural topics, and privately funded state atlases emphasized population, industrial, and agricultural themes.  相似文献   

Sedimentary profiles of Fe, Mn, V, Cr, As and Mo as indicators of benthic redox conditions in Baldeggersee     

Tobias Schaller  H. Christoph Moor  Bernhard Wehrli 《Aquatic Sciences - Research Across Boundaries》1997,59(4):345-361

Concentration profiles of Mg, K, La, Fe, Mn, V, Cr, As and Mo were determined in samples from a freeze core taken at the deepest site of Baldeggersee in 1993. The special coring technique allowed an exact dating of the sediment samples and an annual resolution of the profiles. Long term changes in benthic redox conditions produce diagnostic trends in several metal profiles. Fe, As and Mn enrichments trace the onset of anoxia at the deepest site of the lake. High values of Mo concentrations and Cr/V ratios indicate periods of stable anoxic conditions in a meromictic hypolimnion. A comparison of oxygen time series with metal profiles between 1950 and 1990 indicates that Mn reacts sensitively to large seasonal variations of deep-water oxygen concentrations.  相似文献   

Ultra-high degree spherical harmonic analysis and synthesis using extended-range arithmetic   总被引：3，自引：2，他引：1  

Tobias Wittwer  Roland Klees  Kurt Seitz  Bernhard Heck 《Journal of Geodesy》2008,82(4-5):223-229

We present software for spherical harmonic analysis (SHA) and spherical harmonic synthesis (SHS), which can be used for essentially arbitrary degrees and all co-latitudes in the interval (0°, 180°). The routines use extended-range floating-point arithmetic, in particular for the computation of the associated Legendre functions. The price to be paid is an increased computation time; for degree 3,000, the extended-range arithmetic SHS program takes 49 times longer than its standard arithmetic counterpart. The extended-range SHS and SHA routines allow us to test existing routines for SHA and SHS. A comparison with the publicly available SHS routine GEOGFG18 by Wenzel and HARMONIC SYNTH by Holmes and Pavlis confirms what is known about the stability of these programs. GEOGFG18 gives errors <1 mm for latitudes [-89°57.5′, 89°57.5′] and maximum degree 1,800. Higher degrees significantly limit the range of acceptable latitudes for a given accuracy. HARMONIC SYNTH gives good results up to degree 2,700 for almost the whole latitude range. The errors increase towards the North pole and exceed 1 mm at latitude 82° for degree 2,700. For a maximum degree 3,000, HARMONIC SYNTH produces errors exceeding 1 mm at latitudes of about 60°, whereas GEOGFG18 is limited to latitudes below 45°. Further extending the latitudinal band towards the poles may produce errors of several metres for both programs. A SHA of a uniform random signal on the sphere shows significant errors beyond degree 1,700 for the SHA program SHA by Heck and Seitz.  相似文献   

A high-resolution pigment and productivity record from the varved Ponte Tresa basin (Lake Lugano,Switzerland) since 1919: insight from an approach that combines hyperspectral imaging and high-performance liquid chromatography     

Tobias Schneider  Denise Rimer  Christoph Butz  Martin Grosjean 《Journal of Paleolimnology》2018,60(3):381-398

Eutrophication, prompted by anthropogenic activities and climate change has led to multiple adverse effects in freshwater systems across the world. As instrumental measurements are typically short, lake sediment proxies of aquatic primary productivity (PP) are often used to extend the observational record of eutrophication back in time. Sedimentary pigments provide specific information on PP and major algal communities, but the records are often limited in the temporal resolution. Hyperspectral imaging (HSI) data, in contrast, provide very high seasonal (sub-varve-scale) resolution, but the pigment speciation is limited. Here, we explore a combined approach on varved sediments from the Ponte Tresa basin, southern Switzerland, taking the advantages of both methods (HSI and high performance liquid chromatography, HPLC) with the goal to reconstruct the recent eutrophication history at seasonal to interannual resolution. We propose a modified scheme for the calibration of HSI data (here: Relative Absorption Band Depth between 590 and 730 nm RABD_590–730) and HPLC-inferred pigment concentrations (here: ‘green pigments’ {chlorophyll a and pheophytin a}) and present a calibration model (R²?=?0.82; RMSEP?~?12%). The calibration range covers >?98% of the spectral index values of all individual pixels (68 µm?×?68 µm) in the sediment core. This allows us to identify and quantify extreme pigment concentrations related to individual major algal blooms, to identify multiple algal blooms within one season, and to assess interannual variability of PP. Prior to the 1930s, ‘green pigment’ concentrations and fluxes (~?50 µg g^?1;?~?2 µg cm^?2a^?1, chlorophyll a and pheophytin a) and interannual variability was very low. From the 1930s to 1964, chlorophyll a and pheophytin a increased by a factor of ~?4, and ββ-carotene appeared in substantial amounts (~?0.4 µg cm^?2a^?1). Interannual variability increased markedly and a first strong algal bloom with ‘green pigment’ concentrations as high as 700 µg g^?1 is observed in 1958. Peak eutrophication (~?12 µg cm^?2a^?1 chlorophyll a and pheophytin a) and very high interannual variability with extreme algal blooms (‘green pigment’ concentrations up to 1400 µg g^?1) is observed until ca. 1990, when eutrophication decreases slightly. Maximum PP values after 2009 are likely the result of internal nutrient cycling related to repeated deep mixing of the lake.  相似文献   

On the abundance of NO₂ in the Martian atmosphere     

Tobias Owen  Thomas Scattergood  Jerry H. Woodman 《Icarus》1975,24(2):193-196

Spectrophotometric scans of Mars and the Moon in the region 4000–5000 Å were obtained and ratioed. No evidence of any absorption greater than 3% is visible in the Martian spectrum. Using our own laboratory spectra of NO₂ as well as the published work of Hall and Blacet (1952) we confirm Marshall's (1964) upper limit of 8 μm atmospheres (0.0008 cm amagat) for the abundance of NO₂ in the atmosphere of Mars.  相似文献   

Limitations of Majority Agreement in Crowdsourced Image Interpretation   总被引：1，自引：1，他引：0       下载免费PDF全文

Carl F Salk  Tobias Sturn  Linda See  Steffen Fritz 《Transactions in GIS》2017,21(2):207-223

Crowdsourcing can efficiently complete tasks that are difficult to automate, but the quality of crowdsourced data is tricky to evaluate. Algorithms to grade volunteer work often assume that all tasks are similarly difficult, an assumption that is frequently false. We use a cropland identification game with over 2,600 participants and 165,000 unique tasks to investigate how best to evaluate the difficulty of crowdsourced tasks and to what extent this is possible based on volunteer responses alone. Inter‐volunteer agreement exceeded 90% for about 80% of the images and was negatively correlated with volunteer‐expressed uncertainty about image classification. A total of 343 relatively difficult images were independently classified as cropland, non‐cropland or impossible by two experts. The experts disagreed weakly (one said impossible while the other rated as cropland or non‐cropland) on 27% of the images, but disagreed strongly (cropland vs. non‐cropland) on only 7%. Inter‐volunteer disagreement increased significantly with inter‐expert disagreement. While volunteers agreed with expert classifications for most images, over 20% would have been mis‐categorized if only the volunteers’ majority vote was used. We end with a series of recommendations for managing the challenges posed by heterogeneous tasks in crowdsourcing campaigns.  相似文献   

Geochemical and mineralogical composition of black weathering crusts on limestones from seven different European countries     

Orsolya Farkas  Siegfried Siegesmund  Tobias Licha  Ákos Török 《Environmental Earth Sciences》2018,77(5):211

Twenty-seven samples of black weathering crust and host carbonates were studied from seven European countries (Germany, Hungary, Belgium, Czech Republic, France, Italy and Poland) representing 11 different sites. The samples were collected for sites for which long-term air pollution records are available. The mineralogical analyses (XRD, polarizing microscopy, SEM) have shown that despite decreasing SO₂ emissions crust samples are still very rich in gypsum. Further, in all host rock samples gypsum was also detected. Good correlations (R² > 0.9) were also found between water-soluble calcium and gypsum content and between sulphate and gypsum content both for black crusts and host rocks. The black gypsum crusts are four or five times richer in sulphate than the host rock. The conductivity of dissolved crust and host rock samples also shows a positive correlation with gypsum content of the samples. LA-ICP-MS analyses allowed the detection of high Pb-levels in black crusts and a negative shift in lead concentration at the crust/host rock transition. The lead content of the host rock is 2–5 mg/kg, while that of the crust is 3–25 mg/kg in the sample collected from Germany, while in the Belgian sample these values are 2–14 mg/kg and 80–870 mg/kg for the host rock and crust, respectively. The GC–MS technique allowed to detect the PAH content of black crusts and host rocks. The former one contains 0.6–15.6 (102.5) mg/kg, while in the host rock values between 0.2 and 2.4 mg/kg were found. The present study suggests that still large amounts of air pollution-related minerals and organic pollutants are found in the black weathering crusts of European carbonate buildings despite decreasing trends in air pollution.  相似文献   

On the long-term stability of terrestrial reference frame solutions based on Kalman filtering     

Benedikt Soja  Richard S. Gross  Claudio Abbondanza  Toshio M. Chin  Michael B. Heflin  Jay W. Parker  Xiaoping Wu  Tobias Nilsson  Susanne Glaser  Kyriakos Balidakis  Robert Heinkelmann  Harald Schuh 《Journal of Geodesy》2018,92(9):1063-1077

The Global Geodetic Observing System requirement for the long-term stability of the International Terrestrial Reference Frame is 0.1 mm/year, motivated by rigorous sea level studies. Furthermore, high-quality station velocities are of great importance for the prediction of future station coordinates, which are fundamental for several geodetic applications. In this study, we investigate the performance of predictions from very long baseline interferometry (VLBI) terrestrial reference frames (TRFs) based on Kalman filtering. The predictions are computed by extrapolating the deterministic part of the coordinate model. As observational data, we used over 4000 VLBI sessions between 1980 and the middle of 2016. In order to study the predictions, we computed VLBI TRF solutions only from the data until the end of 2013. The period of 2014 until 2016.5 was used to validate the predictions of the TRF solutions against the measured VLBI station coordinates. To assess the quality, we computed average WRMS values from the coordinate differences as well as from estimated Helmert transformation parameters, in particular, the scale. We found that the results significantly depend on the level of process noise used in the filter. While larger values of process noise allow the TRF station coordinates to more closely follow the input data (decrease in WRMS of about 45%), the TRF predictions exhibit larger deviations from the VLBI station coordinates after 2014 (WRMS increase of about 15%). On the other hand, lower levels of process noise improve the predictions, making them more similar to those of solutions without process noise. Furthermore, our investigations show that additionally estimating annual signals in the coordinates does not significantly impact the results. Finally, we computed TRF solutions mimicking a potential real-time TRF and found significant improvements over the other investigated solutions, all of which rely on extrapolating the coordinate model for their predictions, with WRMS reductions of almost 50%.  相似文献   

Stratigraphic and geotechnical characterization of regionally extensive and highly competent shallow sand units in the southern North Sea     

Matthias Fleischer  Ayobami Abegunrin  Daniel A. Hepp  Stefan Kreiter  Mark Coughlan  Tobias Mörz 《Boreas: An International Journal of Quaternary Research》2023,52(1):78-98

A detailed stratigraphic and geotechnical investigation of the uppermost 50 m below the sea floor was carried out for parts of the German North Sea sector using combined information from shallow seismic reflection surveys, 50-m-long sediment cores and cone penetration tests covering an area of ~150 km². While most recent studies concentrate on unusual features such as buried tunnel- or river-valleys, this study focused on the less well understood, regionally dominant sand units deposited after the retreat of the last glaciers in this region. We identified two sandy units which dominate the late- to post-Saalian geology: (i) the Upper Fluvial Member, believed to be derived from deposition of the Weser, Ems and Elbe palaeorivers as well as other tributaries of the Elbe Palaeovalley in the NE during the Saalian; and (ii) the Aeolian Member, which correlates with periglacial deposits of Weichselian age. Additionally, a Saalian Buried Valley Member believed to comprise fluvial deposit was also identified. Key stratigraphic units within the uppermost 50 m below the sea floor were also identified and mapped. Detailed geotechnical properties were obtained for each of the individual stratigraphic units. The regional extent of the Aeolian and Upper Fluvial Members was documented in the region west of the Elbe Palaeovalley and south of the Dogger Bank, where their geotechnical properties are important for foundation design. In conclusion, the study complements the established regional geotechno-stratigraphy and offers new and detailed publically accessible information beneficial for offshore wind farm development within the region.  相似文献