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131.
The Hvalfjördur area, 30 km north of Iceland’s capital Reykjavik, belongs to the sequence of Late Tertiary to early Quaternary flood basalts with minor intercalations of hyaloclastites and rhyolites. The basalts are affected by progressive low-temperature metamorphism, caused by the burial of the lava succession and higher heat flow from nearby central volcanoes. Low-grade zeolite facies metamorphism of basaltic lavas in the Hvalfjördur area results in two distinct mineral parageneses that can be correlated to events in the burial and hydrothermal history of the lava pile. Stage Ia represents syn-eruptive near-surface alteration in which celadonite and silica were precipitated along primary pores. During regional burial metamorphism (stage Ib), hydrolysis of olivine and glass led to the formation of mixed-layer chlorite/smectite clays. The chlorite content of stage Ib phyllosilicate vesicle rims increases with increasing burial depth and temperature. Stage II occurred after the burial and is marked by zeolite mineralization caused by higher heat flow from the Laxárvogur and Hvalfjördur central volcanoes. Altogether 11 different zeolites were found in the Hvalfjördur area: analcime, chabazite, epistilbite, heulandite, laumontite, levyne, mesolite, stilbite, stellerite, thomsonite and yugawaralite. In total, three separate depth and temperature-controlled “zeolite zones” occur in the Hvalfjördur area. 相似文献
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In response to the observations of the ultravioler deficiencies shown by all of the outer planets and Titan, models have been proposed to explain the low albedos by absorption by particles in the upper atmospheres of these objects. These particles are generally believed to be photochemically formed from gases in the upper atmospheres, primarily methane and hydrogen. Such processes may also be operative on Titan. The results of some laboratory experiments of the proton irradiation of mixtures of gases including CH4 H2, NH3, etc., have shown that liquid and solid materials are produced that are strong ultraviolet absorbers. However, the material produced from the CH4 + H2 mixture was colorless, indicating that species containing elements other than carbon and hydrogen are necessary for the production of color. Two such elements are nitrogen (as NH3 or N2) and sulfur (as H2S) and colored materials have been produced from such mixtures. None of these materials has spectral properties identical to those shown by the planets. Therefore it is necessary that mixtures (and/or cloud layers) of the photochemical materials be present. 相似文献
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Gabriele M. Berberich Tobias Sattler Dietrich Klimetzek Simon A. Benk Martin B. Berberich Daniela Polag Heinz Friedrich Schöler Elliot Atlas 《Journal of Atmospheric Chemistry》2017,74(2):261-281
We investigated and evaluated the occurrence of fault zone tracer gases (CO2, He, Rn), volatile organohalogens (CH3Cl, CHCl3, CHBr3), alkanes and limonene in soil and nest gases of red wood ants (RWA) in comparison to ambient air, in a seismically active area. In this new approach, we compared RWA-free areas to RWA-areas by combining different investigation and analytical methods. In soil gas, the fault zone tracer gas Rn was surprisingly highly correlated to limonene, suggesting a combination of biotic production of limonene and abiotic degassing of Rn in a seismically active area; moderate correlations were found with trihalomethanes and other halocarbons. In RWA nests a variety of elevated concentrations of haloforms were found, while remaining below the atmospheric background values in RWA-free areas. The evidence of CHCl3 in RWA nests is the first record. Its average concentrations in nests of F. rufa and F. polyctena were up to 3 fold higher than atmospheric background and up to 28–70 fold higher compared to e.g. volcanic emissions being considered as one of its main geogenic sources. Thus, RWA nests could possibly be an additional source for CHCl3 liberation. Consequently, apart from RWA being bioindicators for seismically active degassing faults, they might also be used as bioindicators for CHCl3 formation in forest soils. Although we cannot yet differentiate between a geogenic/abiotic and a biotic formation. RWA nests will have to be reconsidered for halocarbon formation in future quantifications of geochemical cycles at global scale, since they impact organic soil chemistry through biotic and/or abiotic pathways. Therefore, further larger-scale research in different tectonic settings but also in well-known CHCl3 “hot spot” study areas such as the Klosterhede area (Denmark) should focus directly on gas sampling from confirmed active fault systems. Nests of other ant species should be addressed to compare seasonal, diurnal and nocturnal variations of degassing procedures in relation to earth tides, different geologic settings, and tectonic events such as earthquakes and on quantifying the fluxes to the atmosphere. 相似文献
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Transfer patterns in Phase I of the EU Emissions Trading System: a first reality check based on cluster analysis 总被引:1,自引:0,他引:1
In 2005, the world's largest Emissions Trading System (ETS) was introduced in the EU. Economic theory assumes high efficiency of such market-based instruments since companies have the flexibility to trade allowances. However, to date there is a lack of understanding on how companies have participated in the allowance markets. This article uses data on transfers of allowances between 2005 and the end of 2007, published by the EU in the Community Independent Transaction Log (CITL) after a five-year delay. We use cluster analysis to detect patterns in the data and differentiate transfer behaviour. We find that the vast majority of participants (7212 accounts) are rather passive in terms of transfers. Of these, more than half are hardly participating in the market at all, whereas one-third are accounts managed by another account belonging to the parent company. Opposed to that, 143 accounts show more active, but relatively diverse transfer behaviour. We also identify differences in sectoral representations, account types, and primary allocation across the seven clusters. While the passive accounts mostly belong to installations regulated under the EU ETS, the most active accounts are classified as ‘non-regulated account type'. 相似文献
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