Diagenetic Ge-Si fractionation in continental margin environments: further evidence for a nonopal Ge sink     

James McManus  Douglas E. Hammond  Gary P. Klinkhammer 《Geochimica et cosmochimica acta》2003,67(23):4545-4557

We present data for dissolved germanic and silicic acids from several settings: sediment pore water profiles collected from the Peru-Chile continental margin, fluxes measured with in situ benthic flux chambers and shipboard whole-core incubations, and water column profiles from the California continental margin. Collectively, these data show that Ge and Si are fractionated in these continental margin sedimentary environments during diagenesis with ∼50% of the Ge released by opal dissolution being sequestered within the sediments. The areal extent of this diagenetic fractionation covers station depths from ∼100 m to >1000 m. Sediments from these sites typically have high pore water Fe²⁺ present in the upper ∼2 cm. At sites with low Fe²⁺ concentrations in the upper pore waters, the Ge:Si benthic regeneration ratio indicates little or no fractionation during diatom dissolution. Consistent with the sedimentary fractionation, water column dissolved Ge:Si ratios along the continental margin are on average lower (0.66 μmol/mol) than the global average ratio (0.72 μmol/mol, Mortlock and Froelich, 1996). This lower “average” ratio is driven by two distinct ΔGe:ΔSi data trends having similar slopes but different intercepts. Data from the upper ∼150 m has a Ge:Si slope of 0.74 ± 0.04 μmol/mol (2σ) and an intercept of 0.5 ± 0.4; whereas below ∼550 m the slope is 0.70 ± 0.06 μmol/mol, but the intercept is −5.0 ± 8.0. Assuming that the sediments sampled here are representative of all reducing marine environments, an assumption requiring further testing, our calculations indicate that sequestration of Ge into a nonopal phase throughout the global ocean in the depth range 0.2-1 km is sufficient to balance the Ge budget. Thus, we tentatively conclude that sequestering of Ge in reducing continental margin sediments is the “missing” Ge sink.  相似文献   

Chemical characterization of high molecular weight dissolved organic matter in fresh and marine waters   总被引：1，自引：0，他引：1  

Daniel J. Repeta  Tracy M. QuanLihini I. Aluwihare  AmyMarie Accardi 《Geochimica et cosmochimica acta》2002,66(6):955-962

The high molecular weight fraction of dissolved organic matter in a suite of lakes, rivers, seawater, and marine sediment interstitial water samples was collected by ultrafiltration and characterized by molecular level and spectroscopic techniques. Proton nuclear magnetic resonance spectra of all samples show a high degree of similarity, with major contributions from carbohydrates, bound acetate, and lipids. Molecular level analyses of neutral sugars show seven monosaccharides, rhamnose, fucose, arabinose, xylose, mannose, glucose, and galactose, to be abundant, and to occur in comparable relative amounts in each sample. Previous studies have emphasized the distinctive composition of dissolved humic substances in fresh and marine waters, and have attributed these differences to sources and transformations of organic matter unique to each environment. In contrast we find a large fraction of freshwater high molecular weight dissolved organic matter (HMWDOM; > 1kD) to be indistinguishable from marine HMWDOM in bulk and molecular-level chemical properties. Aquatic HMWDOM is similar in chemical composition to biologically derived acylated heteropolysaccharides isolated from marine algal cultures, suggesting a biological source for some fraction of persistent HMWDOM. High molecular weight DOC contributes 51 ± 26% of the total DOC, and monosaccharides 18 ± 8% of the total HMWDOC in our freshwater samples. These contributions are on average higher and more variable, but not significantly different than for surface seawater (30% and 16% respectively). Biogeochemical processes that produce, accumulate, and recycle DOM may therefore share important similarities and be broadly comparable across a range of environmental settings.  相似文献   

A comparison between subaerial and submarine eruptions at Kilauea Volcano, Hawaii: implications for the thermal viability of lateral feeder dikes     

Elisabeth A. Parfitt  Tracy K. P. Gregg  Deborah K. Smith 《Journal of Volcanology and Geothermal Research》2002,113(1-2)

Eruption styles on the subaerial East Rift Zone (ERZ) of Kilauea volcano are reviewed and a classification scheme for the different types of eruption is proposed. The various eruption types are produced by differing thermal and driving pressure behaviour in the feeder dikes. Existing evidence is reviewed and new evidence presented of the types and volumes of eruptions on the Puna Ridge, which is the submarine extension of the ERZ. Eruptions on the Puna Ridge fall into the same five classes as, and are of comparable volume to, those on the subaerial ERZ. Evidence is presented which suggests that feeder dikes for Puna Ridge eruptions are more thermally viable than those feeding subaerial eruptions, and this difference causes long-lived, large-volume eruptions to be more common on the Puna Ridge than on the subaerial ERZ. This systematic variation in thermal viability may be due to increased dike width for Puna Ridge dikes or increased pressure gradients driving magma flow. Lateral dike emplacement is common to many basaltic systems including on other Hawaiian volcanoes, in Iceland and at mid-ocean ridges. The systematic trend inferred for the ERZ of Kilauea implies that in the other systems large-volume eruptions may also be more common at great distances than they are close to the magma centre.  相似文献   

The Horizontal Reactive Media Treatment Well (HRX Well®) for Passive In‐Situ Remediation          下载免费PDF全文

Craig E. Divine  Tracy Roth  Michelle Crimi  Abrahm C. DiMarco  Matt Spurlin  Jeff Gillow  Gastón Leone 《Ground Water Monitoring & Remediation》2018,38(1):56-65

A new in‐situ remediation concept termed a Horizontal Reactive Media Treatment Well (HRX Well®) is presented that utilizes horizontal wells filled with reactive media to passively treat contaminated groundwater in‐situ. The approach involves the use of large‐diameter directionally drilled horizontal wells filled with granular reactive media generally installed parallel to the direction of groundwater flow. The design leverages natural “flow‐focusing” behavior induced by the high in‐well hydraulic conductivity of the reactive media relative to the aquifer hydraulic conductivity to passively capture and treat proportionally large volumes of groundwater within the well. Clean groundwater then exits the horizontal well along its downgradient sections. Many different types of solid granular reactive media are already available (e.g., zero valent iron, activated carbon, ion exchange resins, zeolite, apatite, chitin); therefore, this concept could be used to address a wide range of contaminants. Three‐dimensional flow and transport simulations were completed to assess the general hydraulic performance, capture zones, residence times, effects of aquifer heterogeneity, and treatment effectiveness of the concept. The results demonstrate that capture and treatment widths of up to tens of feet can be achieved for many aquifer settings, and that reductions in downgradient concentrations and contaminant mass flux are nearly immediate. For a representative example, the predicted treatment zone width for the HRX Well is approximately 27 to 44 feet, and contaminant concentrations immediately downgradient of the HRX Well decreased an order of magnitude within 10 days. A series of laboratory‐scale physical tests (i.e., tank tests) were completed that further demonstrate the concept and confirm model prediction performance. For example, the breakthrough time, peak concentration and total mass recovery of methylene blue (reactive tracer) was about 2, 35, and 20 times (respectively) less than chloride (conservative tracer) at the outlet of the tank‐scale HRX Well.  相似文献   

Phosphorites,glass ramps and carbonate factories: The evolution of an epicontinental sea and a late Palaeozoic upwelling system (Phosphoria Rock Complex)     

Edward J. Matheson  Tracy D. Frank 《Sedimentology》2020,67(6):3003-3041

The Permian Phosphoria Rock Complex of the western USA contains an enigmatic assemblage of bioelemental rocks (i.e. phosphorites and cherts) that accumulated in a depositional system with no modern analogue. This study utilizes detailed sedimentological, stratigraphic and petrographic examination to evaluate the genetic relations of phosphorites, spiculitic chert and carbonates of the Ervay cycle (depositional sequence) and propose a unified oceanographic model for their deposition. The Ervay cycle contains three marine and one terrestrial facies association, each of which composes the bulk of a single lithostratigraphic unit. The marine facies associations include: (i) granular phosphorites (Retort Member); (ii) spiculitic cherty dolostones (Tosi Member); and (iii) marine to peritidal carbonates (Ervay Member). Red beds and intercalated gypsum (Goose Egg Formation) accumulated in the vast desert adjacent to the sea. The three marine members are chronostratigraphically distinct, successive and conformably stacked. They are not coeval facies belts. They reflect the progressive evolution of the epicontinental sea from the location of: (i) authigenic phosphogenesis (lowstand to transgression); to (ii) a glass ramp with biosiliceous (sponge) deposition (transgression); to (iii) a carbonate ramp (regression). This succession of switching biochemical sediment factories records the evolution of sea-level, nutrient supply, upwelling, oxygenation and dissolved Si. Intense upwelling, potentially coupled with aeolian input, led to sedimentary condensation and phosphogenesis. Decreased upwelling intensity during transgression increased oxygenation sufficiently for a siliceous sponge benthos. Sponges were favoured over biocalcifiers due to elevated dissolved silica and a low carbonate saturation state. The cessation of sponge dominance and transition to a carbonate ramp occurred due to decreasing upwelling intensity, Si drawdown and an increased carbonate saturation state. These results provide insight into the role of Si loading in faunal turnover on glass ramps and highlight how differences in dissolved Si utilizers in pre-Cretaceous versus post-Cretaceous upwelling systems influence the resultant deposits.  相似文献   

Bottom water circulation in Cascadia Basin     

Susan L. Hautala  H. Paul Johnson  Douglas E. Hammond 《Deep Sea Research Part I: Oceanographic Research Papers》2009,56(10):1688-1707

A combination of beta spiral and minimum length inverse methods, along with a compilation of historical and recent high-resolution CTD data, are used to produce a quantitative estimate of the subthermocline circulation in Cascadia Basin. Flow in the North Pacific Deep Water, from 900-1900 m, is characterized by a basin-scale anticyclonic gyre. Below 2000 m, two water masses are present within the basin interior, distinguished by different potential temperature-salinity lines. These water masses, referred to as Cascadia Basin Bottom Water (CBBW) and Cascadia Basin Deep Water (CBDW), are separated by a transition zone at about 2400 m depth. Below the depth where it freely communicates with the broader North Pacific, Cascadia Basin is renewed by northward flow through deep gaps in the Blanco Fracture Zone that feeds the lower limb of a vertical circulation cell within the CBBW. Lower CBBW gradually warms and returns to the south at lighter density. Isopycnal layer renewal times, based on combined lateral and diapycnal advective fluxes, increase upwards from the bottom. The densest layer, existing in the southeast quadrant of the basin below 2850 m, has an advective flushing time of 0.6 years. The total volume flushing time for the entire CBBW is 2.4 years, corresponding to an average water parcel residence time of 4.7 years. Geothermal heating at the Cascadia Basin seafloor produces a characteristic bottom-intensified temperature anomaly and plays an important role in the conversion of cold bottom water to lighter density within the CBBW. Although covering only about 0.05% of the global seafloor, the combined effects of bottom heat flux and diapycnal mixing within Cascadia Basin provide about 2-3% of the total required global input to the upward branch of the global thermohaline circulation.  相似文献   

"The Bush is No More": Insights on Institutional Change and Natural Resource Availability in Rural South Africa     

Kirkland T  Hunter LM  Twine W 《社会与自然资源》2007,20(4):337-350

The past decade has brought substantial transition to South Africa. The introduction of democracy in 1994 has yielded important political and socioeconomic transformations affecting millions of people. Here, we explore the impact of institutional and structural changes on the availability and management of fuelwood, a key natural resource in rural South Africa. As in other developing regions, many households depend on natural resources for both sustenance and energy needs. Drawing on qualitative data from 32 interviews, our objective is to describe, from the perspective of the respondents, (1) resource scarcity, (2) the underlying causes of resource scarcity, (3) the role of traditional authority in managing resources, and (4) strategies used by community members in the face of resource scarcity. The results have important implications for the well-being of both social and natural systems in many transitional, rural developing societies.  相似文献   

Lightning activity related to satellite and radar observations of a mesoscale convective system over Texas on 7–8 April 2002     

Nikolai Dotzek  Robert M. Rabin  Lawrence D. Carey  Donald R. MacGorman  Tracy L. McCormick  Nicholas W. Demetriades  Martin J. Murphy  Ronald L. Holle 《Atmospheric Research》2005,76(1-4):127

A multi-sensor study of the leading-line, trailing-stratiform (LLTS) mesoscale convective system (MCS) that developed over Texas in the afternoon of 7 April 2002 is presented. The analysis relies mainly on operationally available data sources such as GOES East satellite imagery, WSR-88D radar data and NLDN cloud-to-ground flash data. In addition, total lightning information in three dimensions from the LDAR II network in the Dallas–Ft. Worth region is used.GOES East satellite imagery revealed several ring-like cloud top structures with a diameter of about 100 km during MCS formation. The Throckmorton tornadic supercell, which had formed just ahead of the developing linear MCS, was characterized by a high CG+ percentage below a V-shaped cloud top overshoot north of the tornado swath. There were indications of the presence of a tilted electrical dipole in this storm. Also this supercell had low average CG− first stroke currents and flash multiplicities. Interestingly, especially the average CG+ flash multiplicity in the Throckmorton storm showed oscillations with an estimated period of about 15 min.Later on, in the mature LLTS MCS, the radar versus lightning activity comparison revealed two dominant discharge regions at the back of the convective leading edge and a gentle descent of the upper intracloud lightning region into the trailing stratiform region, apparently coupled to hydrometeor sedimentation. There was evidence for an inverted dipole in the stratiform region of the LLTS MCS, and CG+ flashes from the stratiform region had high first return stroke peak currents.  相似文献   

Geostatistical analysis of the effects of stage and roughness on reach-scale spatial patterns of velocity and turbulence intensity     

Carl J. Legleiter  Tracy L. Phelps  Ellen E. Wohl 《Geomorphology》2007,83(3-4):322-345

  相似文献   

Deglacial meltwater drainage and glaciodynamics: inferences from Laurentide eskers, Canada     

Dr. Tracy A. Brennand   《Geomorphology》2000,32(3-4)

This paper evaluates current knowledge of Laurentide eskers in Canada in the light of developments in glacier hydrology and glacial sedimentology. Questions regarding the morpho-sedimentary relations of eskers, the synchroneity and operation of R-channel systems, the role of supraglacial meltwater input and proglacial water bodies, the controls on esker pattern, and the glaciodynamic condition of the ice sheet at the time of esker formation are discussed. A morphologic classification of eskers is proposed. Five types of eskers are identified and investigated. Type I eskers likely formed in extensive, synchronous, dendritic R-channel networks under regionally stagnant ice that terminated in standing water. Type II eskers likely formed in short, subaqueously terminating R-channels or reentrants close to an ice front or grounding line that may have actively retreated during esker sedimentation. Type III eskers plausibly formed in short R-channels that drained either to interior lakes in, or tunnel channels under, regionally stagnant ice. Type IV eskers may have formed as time-transgressive segments in short, subaerially terminating R-channels (or reentrants) that developed close to the ice margin as the ice front underwent stagnation-zone retreat or downwasted and backwasted regionally (stagnant ice); however, formation in synchronous R-channels cannot be discounted on the basis of reported observations. Type V eskers may have formed in H-channels that terminated subaerially. The spatial distribution of these esker types is discussed. The factors that determined Laurentide R-channel pattern and operation were likely a complex combination of (i) supraglacial meltwater discharge, (ii) the number and location of sink holes, (iii) the ice surface slope, thickness and velocity, and (iv) the permeability, topography and rigidity of the bed. These factors cause and respond to changes in ice dynamics and thermal regime over the glacial cycle.  相似文献