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21.
A methodology for planning an optimized river water temperature monitoring network is presented. The methodology is based on sampling of the physio-climatic variability of the region to be monitored. Physio-climatic metrics are selected to describe the study region, based on principal component analysis. The sites to be monitored are then identified based on a k-means clustering in the multidimensional space defined by the selected metrics. The methodology is validated on an existing dense water temperature network in Haute-Savoie, France. Different configurations of more or less dense network scenarios are evaluated by assessing their ability to estimate water temperature indices at ungauged locations. An optimized network containing 83 sites is found to provide satisfactory estimations for seven ecologically and biologically meaningful thermal indices defined to characterize brown trout thermal habitat. 相似文献
22.
Can observational selection effects, tied with the existence of strong lines, explain the observed log (1 + z) periodicity of the quasar's histogram, as sometimes claimed? A first approach shows that one must distinguish radio from optical quasars. In the former case spectroscopic selection due to strong lines is investigated from the study of homogeneous samples. Then, the role played by pairs of strong lines in the redshift's determination is evaluated and it shows that teh spectroscopic selection cannot explain the observed periodicity of the radio quasar's histogram. The study of the complete sample confirms this conslusion. 相似文献
23.
G. Bayon K.W. Burton G. Soulet N. Vigier B. Dennielou J. Etoubleau E. Ponzevera C.R. German R.W. Nesbitt 《Earth and Planetary Science Letters》2009,277(3-4):318-326
The combined use of Lu–Hf and Sm–Nd isotope systems potentially offers a unique perspective for investigating continental erosion, but little is known about whether, and to what extent, the Hf–Nd isotope composition of sediments is related to silicate weathering intensity. In this study, Hf and Nd elemental and isotope data are reported for marine muds, leached Fe-oxide fractions and zircon-rich turbidite sands collected off the Congo River mouth, and from other parts of the SE Atlantic Ocean. All studied samples from the Congo fan (muds, Fe-hydroxides, sands) exhibit indistinguishable Nd isotopic composition (εNd ~ ? 16), indicating that Fe-hydroxides leached from these sediments correspond to continental oxides precipitated within the Congo basin. In marked contrast, Hf isotope compositions for the same samples exhibit significant variations. Leached Fe-hydroxide fractions are characterized by εHf values (from ? 1.1 to + 1.3) far more radiogenic than associated sediments (from ? 7.1 to ? 12.0) and turbidite sands (from ? 27.2 to ? 31.6). εHf values for Congo fan sediments correlate very well with Al/K (i.e. a well-known index for the intensity of chemical weathering in Central Africa). Taken together, these results indicate that (1) silicate weathering on continents leads to erosion products having very distinctive Hf isotope signatures, and (2) a direct relationship exists between εHf of secondary clay minerals and chemical weathering intensity.These results combined with data from the literature have global implications for understanding the Hf–Nd isotope variability in marine precipitates and sediments. Leached Fe-hydroxides from Congo fan sediments plot remarkably well on an extension of the ‘seawater array’ (i.e. the correlation defined by deep-sea Fe–Mn precipitates), providing additional support to the suggestion that the ocean Hf budget is dominated by continental inputs. Fine-grained sediments define a diffuse trend, between that for igneous rocks and the ‘seawater array’, which we refer to as the ‘zircon-free sediment array’ (εHf = 0.91 εNd + 3.10). Finally, we show that the Hf–Nd arrays for seawater, unweathered igneous rocks, zircon-free and zircon-bearing sediments (εHf = 1.80 εNd + 2.35) can all be reconciled, using Monte Carlo simulations, with a simple weathering model of the continental crust. 相似文献
24.
We report Li isotopic compositions, for river waters and suspended sediments, of about 40 rivers sampled within the Mackenzie River Basin in northwestern Canada. The aim of this study is to characterize the behaviour of Li and its isotopes during weathering at the scale of a large mixed lithology basin. The Mackenzie River waters display systematically heavier Li isotopic compositions relative to source rocks and suspended sediments. The range in δ7Li is larger in dissolved load (from +9.3‰ to +29.0‰) compared to suspended sediments (from −1.7‰ to +3.2‰), which are not significantly different from δ7Li values in bedrocks. Our study shows that dissolved Li is essentially derived from the weathering of silicates and that its isotopic composition in the dissolved load is inversely correlated with its relative mobility when compared to Na. The highest enrichment of 7Li in the dissolved load is reported when Li is not or poorly incorporated in secondary phases after its release into solution by mineral dissolution. This counterintuitive observation is interpreted by the mixing of water types derived from two different weathering regimes producing different Li isotopic compositions within the Mackenzie River Basin. The incipient weathering regime characterizing the Rocky Mountains and the Shield areas produces 7Li enrichment in the fluid phase that is most simply explained by the precipitation of oxyhydroxide phases fractionating Li isotopes. The second weathering regime is found in the lowland area and produces the lower δ7Li waters (but still enriched in 7Li compared to bedrocks) and the most Li-depleted waters (compared to Na). Fractionation factors suggest that the incorporation of Li in clay minerals is the mechanism that explains the isotopic composition of the lowland rivers. The correlation of boron and lithium concentrations found in the dissolved load of the Mackenzie Rivers suggests that precipitation of clay minerals is favoured by the relatively high residence time of water in groundwater. In the Shield and Rocky Mountains, Li isotopes suggest that clay minerals are not forming and that secondary minerals with stronger affinity for 7Li appear.Although the weathering mechanisms operating in the Mackenzie Basin need to be characterized more precisely, the Li isotope data reported here clearly show the control of Li isotopes by the weathering intensity. The spatial diversity of weathering regimes, resulting from a complex combination of factors such as topography, geology, climate and hydrology explains, in fine, the spatial distribution of Li isotopic ratios in the large drainage basin of the Mackenzie River. There is no simple relationship between Li isotopic composition and chemical denudation fluxes in the Mackenzie River Basin. 相似文献
25.
The paper contains a reply to TREDER'S (1977) argument that the existence of a third scalar mode of photons contradicts the laws of heat radiation. 相似文献