Carbon isotopic thermometry calibrated by dolomite-calcite solvus temperatures   总被引：1，自引：0，他引：1  

Hideki Wada  Kazuhiro Suzuki 《Geochimica et cosmochimica acta》1983,47(4):697-706

The temperature dependence of carbon isotopic fractionations between calcite and graphite, and between dolomite and graphite are calibrated by the calcite-dolomite solvus geothermometry using marbles collected from the contact metamorphic aureole in the Kasuga area, central Japan. The carbon isotopic fractionations (Δ¹³C_Cc-Gr and Δ¹³C_DoGr) systematically decrease with increasing metamorphic temperature. The concordant relationships between the fractionations and solvus temperatures are approximately linear with T^?2 over the temperature range. 400° to 680°C: Δ¹³C_CcGr (%.) = 5.6 × 10⁶ × T^?2 (K) ? 2.4 Δ¹³C_DoGr (%.) = 5.9 × 10⁶ × T^?2 (K) ? 1.9 These systematic relationships between fractionation and temperature suggest that carbon isotopic equilibria between carbonates and graphite were attained in many cases. The equation for the calcite-graphite system has a slope steeper than Bottinga's (1969) results. It is, however, in good agreement with that of Valley and O'Neil (1981) in the temperature range from 600° to 800°C.Because of the relatively high sensitivity to temperature, these isotopic geothermometers are useful for determining the temperatures in moderate- to high-grade metamorphosed carbonate rocks.  相似文献   

Minerals formed and mineral formation from volcanic ash by weathering   总被引：2，自引：0，他引：2  

Koji Wada 《Chemical Geology》1987,60(1-4):17-28

Weathering of volcanic ash and pumice is unique regarding minerals formed and mineral formation. These minerals include allophane, imogolite, opaline silica and some halloysites, and have distinctive structures and properties. Studies on the surface and subsurface weathering of various volcanic ashes in different settings are reviewed. This review illustrates that relatively rapid weathering of finely comminuted volcanic ash well reflects the effects of climate, vegetation and time, and produces various combinations of weathering products. The moisture regime, the nature and amount of organic matter incorporated, the deposition of volcanic ash as overburden, and the chemical and mineralogical composition of parent ash are important in controlling the mineral formation in weathered volcanic ash.  相似文献   

Transient flexural vibrations of a timoshenko column supported by an elastic half-space     

H. Wada 《地震工程与结构动力学》1984,12(2):169-179

Transient flexural vibrations of an elastic column supported by an elastic half-space are investigated analytically under the condition that an arbitrarily shaped free-field lateral acceleration is given as an input. Applying the Timoshenko theory to the column and making use of Laplace transformations with respect to time and numerical inverse Laplace transformations, the time histories of the column free end acceleration are presented. Numerical results obtained from the Timoshenko theory are compared with those of a previous paper¹ (applying the Bernoulli-Euler theory to the column), and the effects of column slenderness and foundation stiffness on the transient flexural vibrations of the column are clarified.  相似文献   

A Review of Recent Updates of Sea-Level Projections at Global and Regional Scales     

A. B. A. Slangen  F. Adloff  S. Jevrejeva  P. W. Leclercq  B. Marzeion  Y. Wada 《Surveys in Geophysics》2017,38(1):385-406

Sea-level change (SLC) is a much-studied topic in the area of climate research, integrating a range of climate science disciplines, and is expected to impact coastal communities around the world. As a result, this field is rapidly moving, and the knowledge and understanding of processes contributing to SLC is increasing. Here, we discuss noteworthy recent developments in the projection of SLC contributions and in the global mean and regional sea-level projections. For the Greenland Ice Sheet contribution to SLC, earlier estimates have been confirmed in recent research, but part of the source of this contribution has shifted from dynamics to surface melting. New insights into dynamic discharge processes and the onset of marine ice sheet instability increase the projected range for the Antarctic contribution by the end of the century. The contribution from both ice sheets is projected to increase further in the coming centuries to millennia. Recent updates of the global glacier outline database and new global glacier models have led to slightly lower projections for the glacier contribution to SLC (7–17 cm by 2100), but still project the glaciers to be an important contribution. For global mean sea-level projections, the focus has shifted to better estimating the uncertainty distributions of the projection time series, which may not necessarily follow a normal distribution. Instead, recent studies use skewed distributions with longer tails to higher uncertainties. Regional projections have been used to study regional uncertainty distributions, and regional projections are increasingly being applied to specific regions, countries, and coastal areas.  相似文献   

Evaluation of the Global Mean Sea Level Budget between 1993 and 2014     

Don P. Chambers  Anny Cazenave  Nicolas Champollion  Habib Dieng  William Llovel  Rene Forsberg  Karina von Schuckmann  Yoshihide Wada 《Surveys in Geophysics》2017,38(1):309-327

Evaluating global mean sea level (GMSL) in terms of its components—mass and steric—is useful for both quantifying the accuracy of the measurements and understanding the processes that contribute to GMSL rise. In this paper, we review the GMSL budget over two periods—1993 to 2014 and 2005 to 2014—using multiple data sets of both total GMSL and the components (mass and steric). In addition to comparing linear trends, we also compare the level of agreement of the time series. For the longer period (1993–2014), we find closure in terms of the long-term trend but not for year-to-year variations, consistent with other studies. This is due to the lack of sufficient estimates of the amount of natural water mass cycling between the oceans and hydrosphere. For the more recent period (2005–2014), we find closure in both the long-term trend and for month-to-month variations. This is also consistent with previous studies.  相似文献   

26Al–26Mg chronology of high-temperature condensate hibonite in a fine-grained,Ca-Al-rich inclusion from reduced CV chondrite     

Noriyuki Kawasaki  Daiki Yamamoto  Sohei Wada  Changkun Park  Hwayoung Kim  Naoya Sakamoto  Hisayoshi Yurimoto 《Meteoritics & planetary science》2024,59(4):630-639

Al–Mg mineral isochron studies using secondary ion mass spectrometry (SIMS) have revealed the initial ²⁶Al/²⁷Al ratios, (²⁶Al/²⁷Al)₀, for individual Ca-Al-rich inclusions (CAIs) in meteorites. We find that the relative sensitivity factors of ²⁷Al/²⁴Mg ratio for SIMS analysis of hibonite, one of the major constituent minerals of CAIs, exhibit variations based on their chemical compositions. This underscores the critical need for using appropriate hibonite standards to obtain accurate Al−Mg data. We measured the Al−Mg mineral isochron for hibonite in a fine-grained CAI (FGI) from the Northwest Africa 8613 reduced CV chondrite by SIMS using synthesized hibonite standards with ²⁷Al/²⁴Mg of ~30, ~100, and ~400. The obtained mineral isochron of hibonite in the FGI yields (²⁶Al/²⁷Al)₀ of (4.73 ± 0.09) × 10⁻⁵, which is identical to that previously obtained from the mineral isochron of spinel and melilite in the same FGI (Kawasaki et al., 2020). The uncertainties of (²⁶Al/²⁷Al)₀ indicate that the constituent minerals in the FGI formed within ~0.02 Myr in the earliest solar system. The disequilibrium O-isotope distributions of the minerals in the FGI suggest that the O-isotope compositions of the nebular gas from which they condensed underwent a transitional change from ¹⁶O-rich to ¹⁶O-poor within ~0.02 Myr in the earliest solar system. Once formed, the FGI may have been removed from the forming region within ~0.02 Myr and transported to the accretion region of the parent body.  相似文献