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W. F. McDonough H. -G. Stosch N. G. Ware 《Contributions to Mineralogy and Petrology》1992,110(2-3):321-328
The concentrations of titanium and rare earth elements (REE) in olivines, orthopyroxenes, clinopyroxenes and spinels from four anhydrous, spinel-bearing peridotite xenoliths have been determined. The distribution of titanium (used as an analogue for the high field strength elements: HFSE) relative to the REE between clinopyroxenes and orthopyroxenes varies as a function of the whole rock composition and modal mineralogy. The distribution coefficients for titanium and the REE in these peridotites do not reflect mineral-melt equilibria. It is believed that subsolidus distribution coefficients for HFSE relative to REE vary with temperature. Ratios of various incompatible elements (e.g., Ti/Eu, Zr/Sm, Hf/Sm and P/Nd) in peridotite minerals differ from those in most primary basalts. However, the abundance ratios of incompatible elements in the bulk peridotite are comparable to those found in modern basalts. Given this and the differing contribution of melt from each phase during melting, near constant ratios of such incompatible elements in primary and primitive basalts and komatiites reflect the buffering of the melt by its residue. These ratios are fixed in the magma during the initial stages of melting because of similar and low distribution coefficients between melt and bulk residue for these element pairs. Differences in the relative abundances of titanium and REE in clinopyroxenes and orthopyroxenes demonstrate that mantle normalized abundance patterns for clinopyroxene are not equivalent to those of the whole rock. Therefore, claims of a widespread HFSE-depleted reservoir in the upper mantle base solely on the relative abundances of incompatible elements in peridotitic clinopyroxenes are invalid. 相似文献
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D. H. Green A. D. Edgar P. Beasley E. Kiss N. G. Ware 《Contributions to Mineralogy and Petrology》1974,48(1):33-43
Chemical analyses of over seventy lavas or dykes containing spinel lherzolite inclusions of high pressure mineralogy, show that most host magmas are of alkali olivine basalt or basanite composition with relatively rare olivine nephelinites, and olivine melilitites. The 100 Mg/Mg+Fe++ ratios of host magmas display a strong maximum at about Mg70 consistent with partial melting of source peridotite with olivine of Fo88–90. In contrast to these primary magmas, there occur some host magmas with 100 Mg/Mg+Fe++<60 and with chemical compositions resembling those of classical hawaiite, mugearite, and nepheline benmoreite magmas. It is inferred that these magmas have been produced by crystal fractionation, within the upper mantle, of parental basanites or alkali olivine basalts. The presence of kaersutitic hornblende xenocrysts accompanying the lherzolite inclusions, and the nature of the chemical variation between associated basanites and nepheline benmoreites suggests that crystal fractionation has been dominated by kaersutitic hornblende, together with olivine and, in some cases, probably clinopyroxene. The mantle-derived nepheline benmoreite magmas also show similarities to some plutonic nepheline syenites. 相似文献
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Jonathan Corcoran Gary Higgs Chris Brunsdon Andrew Ware 《The Professional geographer》2007,59(4):521-536
This article reports on the results from a spatiotemporal analysis of disaggregate fire incident data. The innovative analysis presented here focuses on the exploration of spatial and temporal patterns for four principal fire incident categories: property, vehicle, secondary fires, and malicious false alarms. This research extends previous work on spatial exploration of spatiotemporal patterns by demonstrating the benefits of comaps and kernel density estimation in examining temporal and spatiotemporal dynamics in calls for services. Results indicate that fire incidents are not static in either time or space and that spatiotemporal variation is related to incident type. The application of these techniques has the potential to inform policy decisions both from a reactive, resource‐allocation perspective and from a more proactive perspective, such as through spatial targeting of preventive measures. 相似文献
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Allen K. Kennedy Jörn-Frederik Wotzlaw James L. Crowley Mark Schmitz Urs Schaltegger Benjamin Wade Laure Martin Cristina Talavera Bryant Ware Thi Hao Bui 《Geostandards and Geoanalytical Research》2023,47(2):373-402
Twelve apatite samples have been tested as secondary ion mass spectrometry (SIMS) reference materials. Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) analysis shows that the SLAP, NUAN and GR40 apatite gems are internally homogeneous, with most trace element mass fractions having 2 standard deviations (2s) ≤ 2.0%. BR2, BR5, OL2, AFG2 and AFB1, which have U > 63 μg g-1, 206Pb/204Pb > 283, and homogeneous SIMS U-Pb data, have respective isotope dilution thermal ionisation mass spectrometry (ID-TIMS) ages of 2053.83 ± 0.21 Ma, 2040.34 ± 0.09 Ma, 868.87 ± 0.25 Ma, 478.71 ± 0.22 Ma and 473.25 ± 0.09 Ma. Minor U-Pb heterogeneity exists and accurate SIMS results require correction with the 3D Concordia-constrained common Pb composition. Among the studied samples, AFG2 and BR5 are the most homogeneous U-Pb reference materials. The SIMS sulfur isotopic compositions of eight of the apatites shows they are homogeneous, with 2s for both 103δ34S and 103δ33S < 0.55‰. One apatite, BR96, has Δ33S = -0.36 ± 0.2‰. The apatite samples have ID-TIMS 87Sr/86Sr between 0.704214 ± 0.000030 and 0.723134 ± 0.000035. 相似文献
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David B. Kidner J. Mark Ware rew J. Sparkes & Christopher B. Jones 《Transactions in GIS》2000,4(4):361-378
It is often assumed that real land surfaces demonstrate the statistically self-affine scaling behaviour of fractional Brownian surfaces. Tests of this assumption against empirical data, however, show many deviations. Estimates of fractal properties vary between methods and over different scale ranges. So far, this empirical evidence has come from the analysis of variograms for DEMs representing areas up to tens of kilometres in diameter. Here we report results obtained by using variograms to analyse land surface DEMs at the continental scale, with a grid resolution of 30 arc seconds. Results reveal variogram curvature and breaks of slope, but also linear sections over distance lags of hundreds of kilometres. The estimated mean fractal dimension calculated from these sections is 2.66, substantially higher for all continents at these broad scales (around 200 km) than values calculated at the erosional landscape scale (around 200 m). Thus the land surface is not self-affine, and it is not clear that it follows any simple multifractal model. At the longest wavelengths, patterns found in the variograms appear to be related to broad tectonic features of the Earth's surface. For the reader to assess their quality and generality, estimates of fractal dimension should always be accompanied by statements of the scale range covered and the goodness of fit to a log-linear relationship. 相似文献
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Janne Liebmann Bryant Ware Michael I.H. Hartnady Christopher L. Kirkland Nicholas E. Timms Noreen J. Evans 《Geostandards and Geoanalytical Research》2023,47(3):637-655
Lead isotopes are a powerful and versatile tool to elucidate fundamental geological problems related to the formation and evolution of continental crust. K-feldspar is a popular target for Pb isotope measurement as it is prevalent in many rock types and tends to capture the initial Pb isotope composition of its parental magma. We present data for a new Pb isotope reference material: Albany K-feldspar; as well as updated data for Shap K-feldspar. Results of Pb double-spike TIMS for Albany K-feldspar are 206Pb/204Pb = 16.7872 ± 0.0062, 207Pb/204Pb = 15.5640 ± 0.0056, and 208Pb/204Pb = 36.6600 ± 0.0168 (2s). TIMS measurement results for Shap K-feldspar indicate two isotopically distinct Pb populations. LA-MC-ICP-MS, with a spatial resolution as high as 15 μm, indicates a homogeneous Pb isotopic composition in Albany K-feldspar. In accord with previous studies, our results show that scatter in the measured Pb isotope ratios, related to the low natural isotopic abundance of 204Pb, along with the effect of isobaric 204Hg-204Pb interference, increases at lower count rates. However, the mean Pb isotope ratios measured via LA-MC-ICP-MS using a range of spot sizes are in excellent agreement with TIMS results thus highlighting the feasibility of Pb isotope determination via LA-MC-ICP-MS to access geological information preserved in small crystals, including mineral inclusions. 相似文献
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