大兴安岭呼中钼多金属矿床成矿流体特征及成矿机制          下载免费PDF全文

王升鹏  杨倩倩  齐忠友  陈晨  王童  钱鸿 《贵州地质》2018,35(2):118-124

大兴安岭呼中镇钼多金属矿床产于早白垩世碎裂花岗岩中,矿体形态似层状、脉状或透镜状。成矿阶段分为辉钼矿阶段、铜铅锌阶段、方解石阶段等3个阶段。本矿床中的包裹体主要有气液H_2O包裹体、气相H_2O包裹体、含子矿物H_2O包裹体,CO_2包裹体、CO_2-H_2O包裹体等五大类。辉钼矿阶段均一温度为209.2℃413.4℃,盐度ω(NaCleq)为0.53%16.53%,平均值7.3%,属中低盐度,成矿压力在53.3 68.5 MPa,相应的成矿深度为2 052 2 807 m;铜铅锌阶段为191.5℃351.0℃,盐度ω(NaCleq)为0.88%34.24%,平均值3.96%,属低盐度;方解石阶段207.2℃233.5℃,盐度ω(NaCleq)为3.55%4.18%,平均值3.77%,为低盐度。从辉钼矿阶段到铜铅锌阶段再到方解石阶段,温度及盐度逐渐降低。辉钼矿成矿压力在53.3 72.9 MPa,成矿深度为2 052 2 807 m。成矿过程中发生了CO_2-H_2O不混溶作用,这是导致辉钼矿沉淀的主要机制。矿床类型属中低温浅成热液型矿床。  相似文献   

辽西地区北票组烃源岩生物标志化合物特征的差异性     

吴桐  李永飞  张涛  孙求实  孙守亮  宗文明  郜晓勇 《地质与资源》2018,27(4):371-376

北票组是辽西地区重要的一套煤系地层,被认为是该区油气勘探的重要目的层.坤头营子剖面和卧龙剖面是该区较为有代表性的北票组地层剖面,对于研究北票组的沉积环境、有机质来源等具有重要意义.采用气相色谱-质谱（GC-MS）等技术对2个剖面的烃源岩样品进行了分析测试,结果显示两组样品表现出不同的地球化学特征.坤头营子剖面的烃源岩样品抽提物正构烷烃的质量色谱图均为单峰态,主峰碳数以C₁₉为主,姥鲛烷/植烷比值（Pr/Ph）在3.0~4.0之间;甾烷系列中以C₂₉甾烷为优势,C₂₃三环萜烷含量相对较低,伽马蜡烷指数低（平均0.08）.取自卧龙剖面的样品质量色谱图大部分呈现双峰态,Pr/Ph值低;甾烷系列中C₂₇占优势,萜烷系列中C₂₃三环萜烷含量高,具有较高的伽马蜡烷含量（平均0.23）,且各项生标成熟度参数均已达到异构平衡化阶段.结合样品的全岩分析显微组分分析结果,认为两者主要差异可能是剖面附近的侵入岩造成,北票组烃源岩有机质具有陆源高等植物和低等水生生物双重来源,以陆源高等植物为主.  相似文献   

大兴安岭南部地区林西组油气勘探前景探讨     

吴桐  周铁锁 《地质与资源》2018,27(5):438-444

基于露头资料,利用有机地球化学分析技术,通过研究大兴安岭南部林西组地层及烃源岩发育特征,探讨有利勘探方向.结果表明：大兴安岭南部地区上二叠统林西组广泛发育,其沉积环境主体为三角洲-湖相沉积;林西组暗色泥岩有机质含量以中等为主,有机质类型为Ⅱ₂~Ⅲ型,有机质热演化达到高熟-过熟阶段.该区开展油气勘探应远离侵入岩发育区,在有中生界覆盖地区,保存条件及盖层条件更为有利.  相似文献   

CO<Subscript>2</Subscript>-assisted removal of nutrients from municipal wastewater by microalgae <Emphasis Type="Italic">Chlorella vulgaris</Emphasis> and <Emphasis Type="Italic">Scenedesmus obliquus</Emphasis>     

R. Chaudhary  Y. W. Tong  A. K. Dikshit 《International Journal of Environmental Science and Technology》2018,15(10):2183-2192

Axenic culture of microalgae Chlorella vulgaris ATCC^® 13482 and Scenedesmus obliquus FACHB 417 was used for phycoremediation of primary municipal wastewater. The main aim of this study was to measure the effects of normal air and CO₂-augmented air on the removal efficacy of nutrients (ammonia N and phosphate P) from municipal wastewater by the two microalgae. Batch experiments were carried out in cylindrical glass bottles of 1 L working volume at 25 °C and cool fluorescent light of 6500 lux maintaining 14/10 h of light/dark cycle with normal air supplied at 0.2 L min^?1 per liter of the liquid for both algal strains for the experimental period. In the next set of experiments, the treatment process was enhanced by using 1, 2 and 5% CO₂/air (vol./vol.) supply into microalgal cultures. The enrichment of inlet air with CO₂ was found to be beneficial. The maximum removal of 76.3 and 76% COD, 94.2 and 92.6% ammonia, and 94.8 and 93.1% phosphate after a period of 10 days was reported for C. vulgaris and S. obliquus, respectively, with 5% CO₂/air supply. Comparing the two microalgae, maximum removal rates of ammonia and phosphate by C. vulgaris were 4.12 and 1.75 mg L^?1 day^?1, respectively, at 5% CO₂/air supply. From kinetic study data, it was found that the specific rates of phosphate utilization (q _phsophate) by C. vulgaris and S. obliquus at 5% CO₂/air supply were 1.98 and 2.11 day^?1, respectively. Scale-up estimation of a reactor removing phosphate (the criteria pollutant) from 50 MLD wastewater influent was also done.  相似文献   

内蒙古丰镇市泉子沟斑岩钼矿床成岩成矿年代学及其地质意义   总被引：1，自引：0，他引：1  

张明玉  李铁刚  陈公正  吴晓光  赵正  黄凡  吴昊  王国瑞  许立权  张彤 《矿床地质》2018,37(2):339-354

泉子沟斑岩钼矿床位于内蒙古丰镇市,地处华北克拉通北缘内蒙古台隆凉城断隆内。矿区出露一套燕山期花岗质杂岩体——红娘山杂岩体,主要由中粗粒花岗岩、似斑状花岗岩和石英斑岩组成,钼矿体主要赋存于似斑状花岗岩中。文章在详细的野外地质调查基础上,对泉子沟矿床的成岩成矿时代进行了详细研究,并探讨了地质意义。5件辉钼矿样品的Re-Os模式年龄介于(158.8±2.2)Ma~(161.5±2.2)Ma之间,其加权平均值为(159.8±1.0)Ma(MSWD=0.92),等时线年龄为(161.7±3.1)Ma(MSWD=1.40)。红娘山杂岩体LA-ICP-MS锆石U-Pb年龄分别为:中粗粒花岗岩结晶年龄为(173±1)Ma(MSWD=0.88),似斑状花岗岩侵位年龄为(162±1)Ma(MSWD=0.40),石英斑岩结晶年龄为(160±2)Ma(MSWD=1.90)。辉钼矿Re-Os和锆石U-Pb定年结果表明,泉子沟钼矿床形成于晚侏罗世早期,成矿与似斑状花岗岩关系密切。泉子沟钼矿床的辉钼矿w(Re)介于16.49×10~(-6)~32.87×10~(-6),暗示成矿物质主要来自下地壳。  相似文献   

内蒙古兴和县曹四夭超大型斑岩钼铅锌金成矿系统年代学及其地质意义     

范海洋  李铁刚  武文恒  张明玉  黄凡  赵正  张彤  许立权  李香资  权知心 《矿床地质》2018,37(2):355-370

曹四夭斑岩钼矿床位于内蒙古兴和县,是华北克拉通北缘最大的钼矿床。该矿床中部发育斑岩型钼矿体,外围和上部产出热液脉型铅锌金矿体。文章选取1件与斑岩钼矿化共生的绢云母样品进行了40Ar-39Ar定年,获得40Ar-39Ar坪年龄为(144.4±1.2)Ma,相应的39Ar/36Ar-40Ar/39Ar等时线年龄为(146.4±2.2)Ma(MSWD=0.31),将等时线年龄认作绢云母的Ar封闭年龄,表明曹四夭斑岩钼矿化发生在约146 Ma前。选取14件脉型铅锌矿石中的闪锌矿、黄铁矿和磁黄铁矿样品开展了Rb-Sr定年,获得4件闪锌矿的Rb-Sr等时线年龄为(145.1±3.0)Ma(MSWD=0.63);5件黄铁矿的Rb-Sr等时线年龄为(145.2±1.3)Ma(MSWD=0.53);4件闪锌矿、5件黄铁矿和1件磁黄铁矿的Rb-Sr等时线年龄为(145.3±1.0)Ma(MSWD=0.43)。硫化物Rb-Sr定年结果表明曹四夭矿床脉型铅锌矿化形成于约145 Ma前。本次绢云母40Ar-39Ar和硫化物Rb-Sr定年结果表明,曹四夭矿床斑岩型钼矿化和脉型铅锌金矿化为同期产物,两者均形成于晚侏罗世末期,属于同一个斑岩成矿系统。曹四夭矿床硫化物的w(Rb)和w(Sr)分别为0.1867×10~(-6)~1.305×10~(-6)和0.3175×10~(-6)~6.935×10~(-6),Sr同位素初始比值(87Sr/86Sr)i介于0.709 919~0.711 951之间,平均值0.710 952,结合前人获得的辉钼矿Re含量,认为曹四夭矿床的成矿物质主要来源于地壳。  相似文献   

东昆仑五龙沟金矿田控矿构造带的变形条件——来自EBSD组构的启示   总被引：1，自引：0，他引：1  

陈柏林  张昊  陈建林  王永  王铜  韩玉  张延林 《地球学报》2018,39(1):1-13

五龙沟金矿田是东昆仑地区最重要的金矿集中区之一,金矿田主要控矿构造为偏脆性断裂破碎带,在三条控矿构造带中仅在萤石沟—红旗沟构造带邻近北侧的局部出露韧性变形带。本文作者运用电子背散射衍射技术(EBSD)技术方法,对东昆仑五龙沟金矿田萤石沟—红旗沟构造带变形岩石的组构分析显示,花岗质糜棱岩韧性变形强烈,大部分样品石英变形机制是以中温I级柱面(1010)1120滑移为主,变形式样比较单一;少量样品为中高温II级柱面(101—0)0001滑移和中低温底面(0001)112—0滑移。从岩石组构特点结合宏观构造分析,五龙沟金矿田萤石沟—红旗沟构造带及其邻近北侧经历了中-中深层次、中-中高温条件(15~25 km,t=350~550°C,P=0.40~0.60 Gpa)的韧性变形,局部叠加中浅层次、中低温条件(10~15 km,t=250~350°C,P=0.25~0.40 Gpa)的韧脆性变形;而岩金沟和三道梁—苦水泉构造带为低温低压条件的脆性破碎带。结合变形花岗闪长岩年代学资料,确定构造变形时代为早中生代。  相似文献   

Dynamic land use change simulation using cellular automata with spatially nonstationary transition rules   总被引：2，自引：0，他引：2  

Yongjiu Feng  Xiaohua Tong 《地理信息系统科学与遥感》2018,55(5):678-698

The dynamic relationships between land use change and its driving forces vary spatially and can be identified by geographically weighted regression (GWR). We present a novel cellular automata (GWR-CA) model that incorporates GWR-derived spatially varying relationships to simulate land use change. Our GWR-CA model is characterized by spatially nonstationary transition rules that fully address local interactions in land use change. More importantly, each driving factor in our GWR model contains effects that both promote and resist land use change. We applied GWR-CA to simulate rapid land use change in Suzhou City on the Yangtze River Delta from 2000 to 2015. The GWR coefficients were visualized to highlight their spatial patterns and local variation, which are closely associated with their effects on land use change. The transition rules indicate low land conversion potential in the city’s center and outer suburbs, but higher land conversion potential in the inner near suburbs along the belt expressway. Residual statistics show that GWR fits the input data better than logistic regression (LR). Compared with an LR-based CA model, GWR-CA improves overall accuracy by 4.1% and captures 5.5% more urban growth, suggesting that GWR-CA may be superior in modeling land use change. Our results demonstrate that the GWR-CA model is effective in capturing spatially varying land transition rules to produce more realistic results, and is suitable for simulating land use change and urban expansion in rapidly urbanizing regions.  相似文献   

滇西北石鼓杂岩中花岗质片麻岩年代学、地球化学特征及地质意义     

罗改  张彤  贾小川  杨学俊  肖典  谭晓莲 《地质学报》2021,95(11):3335-3351

青藏高原东南缘滇西北前寒武纪石鼓变质杂岩中新识别出一套花岗质片麻岩.采用LA-ICP-MS方法进行锆石U-Pb年代学分析,获得206Pb/238 U加权平均年龄分别为790±11 Ma(MSWD=2.1,n=10)和814±15 Ma(MSWD=5.7,n=9),显示其形成于新元古代早期.地球化学特征显示,岩石具有高硅(SiO2=66.05％～77.16％)、高 K2O/Na2O(0.90～9.26,均值2.57)特征,MgO=0.35％～3.60％,TFeO=1.02％～4.86％,P2O5=0.03％～0.17％.铝饱和指数A/CNK为1.08～2.51,矿物组合中出现石榴子石和白云母等富铝矿物,CIPW标准矿物中刚玉分子平均含量为4.72％,显示为强过铝质花岗岩.球粒陨石标准化稀土配分显示轻稀土元素富集,(La/Yb)N=1.79～12.34,具明显的Eu负异常(δEu=0.21～0.67).原始地幔标准化蛛网图显示,岩石富集Rb、U,明显亏损Ba、Ta、Nb、Sr、P、Ti元素.综合分析认为,花岗质片麻岩原岩主要为低成熟度、黏土贫乏的砂质岩在高温条件下部分熔融的产物,形成于后碰撞构造环境,是Rodinia超大陆汇聚事件在滇西北石鼓地区的响应.  相似文献   

鄂西建始地区五峰-龙马溪组黑色页岩生物地层特征          下载免费PDF全文

周志  姜振学  李世臻  徐桂红  王胜建  郭天旭  童川川 《地球科学》2021,46(2):432-443

鄂西建始地区五峰组-龙马溪组黑色页岩发育,尚未建立古生物地层序列.基于建地1井及湘鄂渝地区23个穿越奥陶系和志留系钻井、剖面资料,研究建始地区五峰组-龙马溪组黑色页岩笔石序列,分析湘鄂水下高地演化模式及其对页岩气成藏影响.建地1井从奥陶系Dicellograptus complexus（WF2）带至志留系Stimulograptus sedgwickii（LM8）带,共包含8个笔石带,缺失了Perculpto gr. perculptus（LM1）、Akidograptus ascensus（LM2）和Parakido gr.acuminatus（LM3）三个笔石带,表明建始地区在赫南特期至鲁丹早期处在湘鄂水下高地范围内.受控于全球海平面变化和广西运动双重作用,湘鄂水下高地整体呈现出自凯迪期至鲁丹早期不断隆升、影响范围逐渐扩大,鲁丹中晚期再逐渐回缩的演化模式;在其范围内普遍缺失WF3-LM4部分笔石带富有机质页岩,导致页岩气藏抗构造破坏能力差,勘探风险较大.   相似文献