The beach placer iron deposit of Portman Bay,Murcia, SE Spain: the result of 33 years of tailings disposal (1957–1990) to the Mediterranean seaside     

José Ignacio Manteca  José Ángel López García  Roberto Oyarzun  Carlos Carmona 《Mineralium Deposita》2014,49(6):777-783

Between 1957 and 1990, the Peñarroya Mining and Metallurgical Company (SMMPE) disposed about 60 million tonnes of tailings materials directly to the Mediterranean Sea. A substantial part of it (12.5 Mt) was dragged back by the sea currents progressively infilling the Portman Bay (Murcia, SE Spain), thus making the shoreline advance between 500 and 600 m seaward. The Roberto froth flotation plant processed mineral from manto-type deposits belonging to the Sierra de Cartagena-La Unión lead-zinc district. One of the mineral assemblages present in these deposits comprises greenalite, magnetite, sulfides, carbonates, and silica. Despite that magnetite recovery was undertaken by SMMPE between 1959 and 1967, we estimate that magnetite contained in the tailings hosts a substantial resource that could be as large as 2.3 Mt of iron ore. The ore contains magnetite ± hematite ± siderite. Tidal waves and sea currents led to gravimetric classification of the tailings material, with concentration of the dense iron oxides in the sandy fractions, eventually forming a coastal placer iron deposit. A major problem for magnetic separation is the intimate intergrowth between magnetite, hematite, and siderite. Besides, the sands contain large concentrations of Pb (0.27 %), Zn (0.72 %), and As (559 ppm).  相似文献   

Role of rhizosphere and soil properties for the phytomanagement of a salt marsh polluted by mining wastes     

H. M. Conesa  A. María-Cervantes  J. Álvarez-Rogel  M. N. González-Alcaraz 《International Journal of Environmental Science and Technology》2014,11(5):1353-1364

The goal of this study was to evaluate the soil properties and their modifications within the rhizosphere of spontaneous vegetation as key factors to assess the phytomanagement of a salt marsh polluted by mining wastes. A field survey was performed based on a plot sampling design. The results provided by the analyses of rhizospheric soil (pH, electrical conductivity (EC), organic carbon, total nitrogen, etc.) and metal(loid)s’ phytoavailability (assessed by EDTA) were discussed and related to plant metal uptake. The averages of pH and EC values of the bulk soil and rhizospheric samples were in the range of neutral to slightly alkaline (pH 7–8) to saline (>2 dS m^?1), respectively. Heavy metal and As concentrations (e.g. ~600 mg kg^?1 As, ~50 mg kg^?1 Cd, ~11,000 mg kg^?1 Pb) were higher in the rhizosphere for both total and EDTA-extractable fraction. Phragmites australis uptaked the highest concentrations in roots (e.g. ~66 mg kg^?1 As, ~1,770 mg kg^?1 Zn) but not in shoots, for which most of plant species showed low values for Zn (<300 mg kg^?1) but not for Cd (>0.5 mg kg^?1) or Pb (~20–40 mg kg^?1). Vegetation distribution in the studied salt marsh looked to be more affected by salinity than by metal pollution. The free availability of water for plants and the incoming nutrient-enriched effluents which flow through the salt marsh may have hindered the metal(loid)s’ phytotoxicity. The phytomanagement of these polluted areas employing the spontaneous vegetation is a good option in order to improve the ecological indicators and to prevent the transport of pollutants to nearby areas.  相似文献   

Metals and metalloids in primary gold mining districts of Western Bolivia: anthropogenic and natural sources     

Ángel Faz  Raúl Zornoza  M. Ángeles Muñoz  José A. Acosta 《Environmental Earth Sciences》2014,71(12):5027-5036

Topsoil and subsoil samples located adjacent and distant from the mining operations sites were collected. Most total metals showed no significant differences between topsoil and subsoil or proximity, suggesting that they derive from endogenous parent material. There was an increment in Hg in topsoils adjacent to the mining operation sites, indicating a deposition of Hg from the amalgamation areas. Higher values of total, extractable and soluble As were observed adjacent to the mining operation sites, probably related to the presence of residues, rich in arsenopyrite. Organic matter and clay contents control the concentrations of EDTA-extractable Cd and Zn, while soil acidity was associated with the behaviour of As, Hg and Cu. In contrast the concentration of EDTA-extractable Pb was directly affected by its total concentration. In general, soluble metals were highly independent, without significant correlations with any soil physical and chemical properties.  相似文献   

Metal accumulation by plant species growing on a mine contaminated site in Mexico     

Ofelia Morton-Bermea  Juan Miguel Gómez-Bernal  María Aurora Armienta  Rufino Lozano  Elizabeth Hernández-Álvarez  Francisco Romero  Javier Castro-Larragoitia 《Environmental Earth Sciences》2014,71(12):5207-5213

The present work aims to assess the efficiency of heavy metal accumulation of native species growing in contaminated soils in the mining district of Taxco, Mexico. Soil and tailing sampling was conducted in three study sites: La Concha, El Fraile, and a control site. The study localities present diverse metal concentrations with significant differences in their proportion in the geochemical fractions. Results show that species Cupressus lindleyi and Juniperus deppeana accumulate Zn and Mn in anomalous concentrations at La Concha, where Zn is present in soluble fractions. Manganese, despite not being present mostly in the soluble fraction in soils and tailings, seems to have been increased in the soluble fraction after the plant growth. In contrast, samples of the same species taken at El Fraile and in the control site, where Zn and Mn are mainly contained in the residual fraction, do not show an anomalous enrichment. Other analyzed species growing under the same contamination conditions in La Concha (Jacaranda mimosifolia and Psidium guajava) do not show anomalous concentrations. These facts confirm the Zn and Mn accumulation capacity of C. lindleyi and Ju. deppeana, which depends on their accumulation ability and on the concentration of these elements in the soluble fraction.  相似文献   

Effects of coastal orientation and depth on the distribution of subtidal benthic assemblages     

Gustavo M. Martins  Rita F. Patarra  Nuno V. Álvaro  Afonso C. L. Prestes  Ana I. Neto 《Marine Ecology》2013,34(3):289-297

A better understanding of biological systems can only be gained if we understand what processes are important and how they operate to determine the distribution of organisms. Coastal orientation and depth can influence environmental conditions, including the degree of water motion and availability of light, which in turn may influence the horizontal and vertical patterns of organism distribution. Here, we used a mixed‐model design to examine the effects of coastal orientation and depth on the structure of benthic assemblages by comparing the abundance and distribution of macroalgae and invertebrates in shallow and deep waters on the opposing coasts of São Miguel. Generally, coastal orientation had little influence on the distribution of most taxa. In contrast, significant differences were generally associated with depth, although patterns were spatially variable at the scale of locations. This study suggests that depth, and processes operating at the scale of location, but not at the scale of the coast, have an important influence on these assemblages, and that failure to recognise such a scale of variability may hamper our ability to better understand the processes that structure these communities.  相似文献   

Characterization of solid bitumens originating from thermal chemical alteration and thermochemical sulfate reduction   总被引：1，自引：0，他引：1  

Simon R. Kelemen  Peter J. Kwiatek  Mobae Afeworki  William A. Lamberti  Hans G. Machel  Trudy Bolin 《Geochimica et cosmochimica acta》2010,74(18):5305-4687

Solid bitumen can arise from several reservoir processes acting on migrated petroleum. Insoluble solid organic residues can form by oxidative processes associated with thermochemical sulfate reduction (TSR) as well as by thermal chemical alteration (TCA) of petroleum. TCA may follow non-thermal processes, such as biodegradation and asphaltene precipitation, that produce viscous fluids enriched in polar compounds that are then altered into solid bitumens. It is difficult to distinguish solid bitumen formed by TCA from TSR since both processes occur under relatively high temperatures. The focus of the present work is to characterize solid bitumen samples associated with TSR- or TCA-processes using a combination of solid-state X-ray Photoelectron Spectroscopy (XPS), Sulfur X-ray Absorption Near Edge Structure Spectroscopy (S-XANES), and ¹³C NMR. Naturally occurring solid bitumens from three locations, Nisku Formation, Brazeau River area (TSR-related); La Barge Field, Madison Formation (TSR-related); and, the Alaskan North Slope, Brooks Range (TCA-related), are compared to solid bitumens generated in laboratory simulations of TSR and TCA.The chemical nature of solid bitumens with respect to organic nitrogen and sulfur can be understood in terms of (1) the nature of hydrocarbon precursor molecules, (2) the mode of sulfur incorporation, and (3) their concentration during thermal stress. TSR-solid bitumen is highly aromatic, sulfur-rich, and nitrogen-poor. These heteroatom distributions are attributed to the ability of TSR to incorporate copious amounts of inorganic sulfur (S/C atomic ratio >0.035) into aromatic structures and to initial low levels of nitrogen in the unaltered petroleum. In contrast, TCA-solid bitumen is derived from polar materials that are initially rich in sulfur and nitrogen. Aromaticity and nitrogen increase as thermal stress cleaves aliphatic moieties and condensation reactions take place. TCA-bitumens from the Brooks Range have <75% aromatic carbon. TCA-bitumens exposed to greater thermal stress can have a higher aromaticity, like that observed in TSR-bitumens. Organic sulfur in TCA-organic solids remains relatively constant with increasing maturation (S/C atomic ratio <0.035) due to offsetting preservation and H₂S elimination reactions. Although S-XANES and ¹³C NMR provide information needed to understand changes in structure and reactivity that occur in the formation of petroleum solids, in some cases XPS analysis is sufficient to determine whether a solid bitumen is formed by TCA or TSR.  相似文献   

Continuity and facies heterogeneities of shallow carbonate ramp cycles (Sinemurian,Lower Jurassic,North‐east Spain)     

BEATRIZ BÁDENAS  MARC AURELL  DAN BOSENCE 《Sedimentology》2010,57(4):1021-1048

The lateral continuity and facies heterogeneities of metre‐scale cycles in a greenhouse Lower Jurassic (Sinemurian) carbonate ramp from the northern Iberian Basin (Spain) was evaluated from extensive field analysis carried out on a well‐exposed 12 km long outcrop. Eleven high‐frequency continuous cycles and their bounding surfaces are traceable laterally through the entire outcrop. However, three of these cycles are found to split laterally into discontinuous cycles of more limited distribution (up to 3 to 5 km of lateral extent). The continuous and discontinuous cycles have a similar field expression in one‐dimensional logs. As a consequence, the number of cycles that can be differentiated is variable along the logged sections (i.e. from 11 to 16). Cycles have variable facies heterogeneities and sedimentary trends depending on the environment of formation: shallowing‐upward and symmetrical cycles occur in protected lagoon–tidal flat areas and in the open‐marine, high‐energy domain. These cycles show significant facies heterogeneities, which were controlled mainly by lateral migration of a mosaic of facies over an irregular topography. Deepening‐upward and aggradational cycles are generated in low‐energy, sub wave‐base, open‐marine areas. Facies are laterally homogeneous, reflecting low potential for carbonate accumulation and inability to fill the created accommodation space in this low‐relief and relatively deep area. Cycle boundaries are generated by stages of rapid accommodation gain, involving the flooding of the carbonate ramp; they are more likely to originate from regional tectonic pulses (related to the extensional tectonics operating in the northern Iberian Basin) rather than greenhouse low‐amplitude eustacy. Discontinuous cycles tend to occur in thickened areas and are interpreted as originating from the infill of wedge‐shaped accommodation space resulting from differential subsidence (i.e. local tectonic pulses). In conclusion, where thickness variations occur in extensional settings lateral continuity of cycles should not be expected. In less well‐exposed, or in one‐dimensional sections and in wells, it would not be possible to distinguish continuous from discontinuous cycles, or to understand such two‐dimensional heterogeneities. Identification of unique cycle‐forming mechanisms or attempting cyclostratigraphic long‐distance correlation of cycles is unrealistic without a detailed analysis of the architecture of cycles in laterally continuous outcrops.  相似文献