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结晶岩的水化膨胀研究   总被引:3,自引:0,他引:3  
室温下的应变实验表明 ,低孔隙度的结晶岩如花岗岩、片麻岩、闪长岩和变基性岩 ,水饱和时膨胀 ,干燥时收缩 ,这种效应是可重复的 .用水的吸附和解吸 (在相对湿度下 ) ,也可以观察到膨胀和收缩 .膨胀效应是由于表面力 (VanderWaals吸引、双电层排斥及溶剂化排斥 )引起的 .水饱和体应变约为其孔隙度的 1 /1 0 .用庚烷饱和的体应变比用水饱和的小 .用CaCl2 溶液饱和的应变随着盐克分子浓度的增加而减小 .杨氏模量E、切变模量G、品质因数Q的准静态测量表明 ,随着相对湿度的增加 ,E、G、Q减少 ,吸附水的增加改变了孔隙内表面分子的相互作用力 .大约在岩石孔隙表面吸附达到 3个水分子层时 ,可观察到最强烈的膨胀效应 .  相似文献   
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Xu, X., Kleidon, A., Miller, L., Wang, S., Wang, L. & Dong, G. 2009: Late Quaternary glaciation in the Tianshan and implications for palaeoclimatic change: a review. Boreas, 10.1111/j.1502‐3885.2009.00118.x. ISSN 0300‐9483. The Tianshan mountain range has been extensively and repeatedly glaciated during the late Quaternary. Multiple moraines in this region record the extent and timing of late Quaternary glacier fluctuations. The moraines and their ages are described in three sub‐regions: eastern, central and western Tianshan. Notable glacial advances occurred during marine oxygen isotope stages (MIS) 6, 4, 3, 2, the Neoglacial and the Little Ice Age (LIA) in these sub‐regions. Glaciers in western Tianshan advanced significantly also during MIS 5, but not in eastern and central Tianshan. The local last glacial maximum (llgm) of the three sub‐regions pre‐dated the Last Glacial Maximum (LGM) and occurred during MIS 4 in eastern and central Tianshan, but during MIS 3 in western Tianshan. The spatial and temporal distribution of the glaciers suggests that precipitation (as snow at high altitude) is the main factor controlling glacial advance in the Tianshan. The late Quaternary climate in the Tianshan has been generally cold–dry during glacial times and warm–humid during interglacial times. Between neighbouring glacial times, the climate has had a more arid tendency in eastern and central Tianshan. These palaeoclimatic conditions inferred from glacial landforms indicate important relationships between the mid‐latitude westerly, the Siberian High and the Asian monsoon.  相似文献   
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Authigenic pyrite grains from a section of the Lower Toarcian Posidonia Shale were analysed for their trace‐element contents and sulphur‐isotope compositions. The resulting data are used to evaluate the relationship between depositional conditions and pyrite trace‐element composition. By using factor analysis, trace‐elements in pyrite may be assigned to four groups: (i) heavy metals (including Cu, Ni, Co, Pb, Bi and Tl); (ii) oxyanionic elements (As, Mo and Sb); (iii) elements partitioned in sub‐microscopic sphalerite inclusions (Zn and Cd); and (iv) elements related to organic or silicate impurities (Ga and V). Results indicate that trace‐element contents in pyrite depend on the site and mechanism of pyrite formation, with characteristic features being observed for diagenetic and syngenetic pyrites. Diagenetic pyrite formed within anoxic sediments generally has a high heavy metals content, and the degree of pyritization of these elements increases with increasing oxygen deficiency, similar to the degree of pyritization of reactive Fe. The highest gradient in the increase of the degree of trace element pyritization with bottom‐water oxygenation was found for the elements Ni < Cu < Mo = As < Tl. In contrast, syngenetic pyrite formed within a euxinic water column typically is enriched in As, Mo and Sb, but is low in heavy metals, and the geochemical variation reflects changes in sea water composition.  相似文献   
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