Monazite U-Pb dating of staurolite grade metamorphism in pelitic schists   总被引：1，自引：1，他引：0  

Harold A. Smith  Barbara Barreiro 《Contributions to Mineralogy and Petrology》1990,105(5):602-615

A study of the occurrence of and relations between rare-earth element (REE) minerals in pelitic schists indicates that monazite forms at or near the P and T of the staurolite isograd. Samples at staurolite grade from the Silurian Perry Mountain Formation in the Rumford quadrangle of Maine yield monazite in sufficient quantities to permit accurate dating of the metamorphic events forming the monazites. The bulk chemistry of the metapelites, as seen in the major element abundances and REE patterns, does not vary significantly across the study area. Thus the appearance and disappearance of REE phases is assumed to reflect changes in metamorphic grade. In a sample from the biotite zone, scanning electron microscope and microprobe studies show allanite and monazite intimately associated on a 10 m scale. The texture suggest that metastable detrital monazite breaks down, distributing its REE components to allanite. From samples below staurolite grade in which monazite is not present, our observations suggest that REEs are partitioned into allanite. At or near the staurolite isograd monazite forms as a metamorphic mineral, initiating its role as a geochronometer. Garnet-biotite geothermometry on samples at this grade from this and other studies places constraints on the minimum temperature necessary to form monazite: 525° C±25°C at 3.1±0.25 kbar. A total of 15 separates from nine schist samples ranging up to sillimanite grade have been dated. Each date is remarkably concordant, even though petrologic and textural studies by previous workers have shown that the rocks in the area have been affected by at least three metamorphic episodes. Calculations indicate insignificant Th disequilibrium in these monazites. The conditions associated with the metamorphic events suggest that monazite remains closed to lead loss provided that subsequent metamorphisms are at or below sillimanite grade. Two distinct metamorphic events are resolved, one at around 400 Ma and one at about 370 Ma. The latter was due to thermal effects of a nearby pluton that yields concordant monazite ages of 363 Ma. This work suggests that in addition to dating plutonism and high-grade metamorphism, monazite should be viewed as a reliable geochronometer for moderate metamorphism of pelitic schists.  相似文献   

Seismic waves | E.F. Savarenskii, 1975. (I.P.S.T. translation) Wiley,Chichester, 281 pp., £13.75     

Warwick D. Smith 《Earth》1976,12(4):424

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Coronal changes associated with a disappearing filament     

N. R. Sheeley Jr.  J. D. Bohlin  G. E. Brueckner  J. D. Purcell  V. E. Scherrer  R. Tousey  J. B. Smith Jr.  D. M. Speich  E. Tandberg-Hanssen  R. M. Wilson  A. C. De Loach  R. B. Hoover  J. P. Mc Guire 《Solar physics》1975,45(2):377-392

This paper describes Skylab/ATM observations of the events associated with a disappearing filament near the center of the solar disk on January 18, 1974. As the filament disappeared, the nearby coronal plasma was heated to a temperature in excess of 6 × 10⁶K. A change in the pattern of coronal emission occurred during the 11/3 hr period that the soft X-ray flux was increasing. This change seemed to consist of the formation and apparent expansion of a loop-like coronal structure which remained visible until its passage around the west limb several days later. The time history of the X-ray and microwave radio flux displayed the well-known gradual-rise-and-fall (GRF) signature, suggesting that this January 18 event may have properties characteristic of a wide class of X-ray and radio events.In pursuit of this idea, we examined other spatially-resolved Skylab/ATM observations of long-duration X-ray events to see what characteristics they may have in common. Nineteen similar long-lived SOLRAD X-ray events having either the GRF or post-burst radio classification occurred during the nine-month Skylab mission. Sixteen of these occurred during HAO/ATM coronagraph observations, and 7 of these 16 events occurred during observations with both the NRL/ATM slitless spectrograph and the MSFC-A/ATM X-ray telescope. The tabulation of these events suggests that all long-lived SOLRAD X-ray bursts involve transients in the outer corona and that at least two-thirds of the bursts involve either the eruption or major activation of a prominence. Also, these observations indicate that long-lived SOLARD events are characterized by the appearance of new loops of emission in the lower corona during the declining phase of the X-ray emission. However, sometimes these loops disappear after the X-ray event (like the post-flare loops associated with a sporadic coronal condensation), and sometimes the loops remain indefinitely (like the emission from a permanent coronal condensation).Visiting Scientist, Kitt Peak National Observatory, Tucson, Ariz. 85726, U.S.A. operated by the Association of Universities for Research in Astronomy, Inc., under contract with the National Science Foundation.Presently located at NASA/MSFC, Space Sciences Laboratory, Marshall Space Flight Center, Ala. 35812, U. S.A.  相似文献   

Acid leaching of ash and coal: Time dependence and trace element occurrences     

Mehtap Paul  Meryem Seferinoğlu  Gul Asiye Ayçık  Åke Sandström  Michael L. Smith  Jan Paul 《International Journal of Mineral Processing》2006

The leaching of coal and coal/asphaltite/wood-ashes in sulfuric acid (pH 1.0, 25 °C, S/L, 1:10) was studied as a function of time; acid consumption and extracted metal concentrations are presented. Whole coals consumed acid rapidly during the first few minutes, followed by slow acid consumption. Wood-, lignite-, and asphaltite-ashes consumed acid in two stages, the rapid phase extending < 30 min and the slow phase extended up to 10 days. The rapid phase was dominated by the dissolution of Ca, K and Mg ions for wood-ash, by Ca, Al and Mg ions for lignite-ash and Ca and Mg ions for asphaltite-ash. The sulfur concentration in solution and the concentrations of Ca, Fe, K, Mg, Na, P, Al and Mn in the aqueous phase verified the neutralizing capacity of the untreated ashes as well as the formation of insoluble sulfates in the residues. The slow phase kinetics differed for different fuels and exhibited leaching of several abundant elements—Fe, Al, K, Na and Mn. Trace elements (Ba, Cd, Co, Cr, Cu, Mo, Ni, Pb, Th, U, V, Zn) sometimes required up to 32 h for maximal extraction from ashes. Suggestions are presented regarding the chemical nature of trace elements in the untreated coals and ashes and suitable residence times for economical industrial processes. We think it possible to combine bacteriological oxidation of sulfidic concentrates of acid leaching from ash of various qualities or even whole coals.  相似文献   

Effects of enhanced zinc and copper in drinking water on spatial memory and fear conditioning     

L.D. Chrosniak  L.N. Smith  C.G. McDonald  B.F. Jones  J.M. Flinn 《Journal of Geochemical Exploration》2006,88(1-3):91

Ingestion of enhanced zinc can cause memory impairments and copper deficiencies. This study examined the effect of zinc supplementation, with and without copper, on two types of memory. Rats raised pre- and post-natally on 10 mg/kg ZnCO₃ or ZnSO₄ in the drinking water were tested in a fear-conditioning experiment at 11 months of age. Both zinc groups showed a maladaptive retention of fearful memories compared to controls raised on tap water. Rats raised on 10 mg/kg ZnCO₃, 10 mg/kg ZnCO₃ + 0.25 mg/kg CuCl₂, or tap water, were tested for spatial memory ability at 3 months of age. Significant improvements in performance were found in the ZnCO₃ + CuCl₂ group compared to the ZnCO₃ group, suggesting that some of the cognitive deficits associated with zinc supplementation may be remediated by addition of copper.  相似文献   

Classifying coastal waters: Current necessity and historical perspective     

J. C. Kurtz  N. D. Detenbeck  V. D. Engle  K. Ho  L. M. Smith  S. J. Jordan  D. Campbell 《Estuaries and Coasts》2006,29(1):107-123

Coastal ecosystems are ecologically and commercially valuable, productive habitats that are experiencing escalating compromises of their structural and functional integrity. The Clean Water Act (USC 1972) requires identification of impaired water bodies and determination of the causes of impairment. Classification simplifies these determinations, because estuaries within a class are more likely to respond similarly to particular stressors. We reviewed existing classification systems for their applicability to grouping coastal marine and Great Lakes water bodies based on their responses to aquatic stressors, including nutrients, toxic substances, suspended sediments, habitat alteration, and combinations of stressors. Classification research historically addressed terrestrial and freshwater habitats rather than coastal habitats. Few efforts focused on stressor response, although many well-researched classification frameworks provide information pertinent to stressor response. Early coastal classifications relied on physical and hydrological properties, including geomorphology, general circulation patterns, and salinity. More recent classifications sort ecosystems into a few broad types and may integrate physical and biological factors. Among current efforts are those designed for conservation of sensitive habitats based on ecological processes that support patterns of biological diversity. Physical factors, including freshwater inflow, residence time, and flushing rates, affect sensitivity to stressors. Biological factors, such as primary production, grazing rates, and mineral cycling, also need to be considered in classification. We evaluate each existing classification system with respect to objectives, defining factors, extent of spatial and temporal applicability, existing sources of data, and relevance to aquatic stressors. We also consider classification methods in a generic sense and discuss their strengths and weaknesses for our purposes. Although few existing classifications are based on responses to stressors, may well-researched paradigms provide important information for improving our capabilities for classification, as an investigative and predictive management tool.  相似文献   

The SHAND quaternary system for evaluating the supersilicic or subsilicic crystal-chemistry of eclogite minerals, and potential new UHPM pyroxene and garnet end-members     

D. C. Smith 《Mineralogy and Petrology》2006,88(1-2):87-122

Summary The stoichiometry of pyroxenes {^viiiX^{2+ vi}Y^{2+ iv}Z⁴⁺ ₂ O₆} and garnets {^xiiX²⁺ ₃ ^viY³⁺ ₂ ^ivZ⁴⁺ ₃ O₁₂} is re-evaluated by a theoretical crystal-chemical approach that takes into account natural phenomena that do not fit with conventional anhydrous stoichiometric mineralogy: the existence in eclogites of microinclusions of other minerals that may have been exsolved from previous supersilicic or subsilicic UHPM pyroxene or garnet. Different definitions of supersilicic and subsilicic are discussed and the one based on the ability to exsolve SiO₂ and leave behind a stoichiometric pyroxene or garnet is recommended for general adoption. The SHAND system (S = Si et al.; H = H; A = Al et al.; N = Na et al.; D = divalents) for projecting multivariate chemical space involving 23 cations and 104 selected natural or potential mineral species on to two essential diagrams (SAND and SHND) is described in full for the first time. Numerous possible chemical exchanges are considered and justified with respect to known mineral phenomena such as cation vacancies, octahedral silicon or protonation. Several new potential end-members are presented, in particular “supersilipyx”, “supersiligar” and “subsiligar”. It is suggested that small quantities of these end-members can be incorporated into UHPM solid-solutions and lead to various exsolution phenomena during eclogite exhumation.  相似文献   

Shape and distribution analysis of Merensky Reef potholing, Northam Platinum Mine, western Bushveld Complex: implications for pothole formation and growth     

Damian S. Smith  Ian J. Basson 《Mineralium Deposita》2006,41(3):281-295

Syn-magmatic removal of the cumulate pile during the formation of the Bushveld Complex resulted in “potholes”. Erosion progressed downward in the cumulate pile, resulting in a series of steep, transgressive contacts between locally conformable potholed reefs in the regional pothole sub-facies of the Swartklip Facies in the western limb of the Bushveld Complex. The deepest of these potholes, “third-order” or “FWP2” potholing, occurs where the base of the Merensky Cyclic Unit transgresses the Upper Pseudo-Reef Chromitite marker horizon. The base of a FWP2 pothole on Northam Platinum Mine consists of an unconformable stringer Merensky Chromitite overlain by a medium-grained, poikilitic orthopyroxenite and underlain by either a pegmatitic harzburgite or the medium-grained Lower Pseudo-Reef Anorthosite. Detailed shape and distribution analysis of FWP2 potholes reveals underlying patterns in their shape and distribution which, in turn, suggest a structural control. The ratio between pothole short vs long axes is 0.624 (N=1,385), although the ratio increases from 0.48 to 0.61 in the long axis range 10 to 60 m, then decreases from 0.61 to 0.57 from 61 to 100 m, increasing again from 0.57 to 0.61 from 101 to 400 m, suggesting that there is not a simple relationship between pothole shape and size. Shape (circularity, eccentricity, and dendricity) analysis of a subset of 638 potholes indicates that potholes with long axes <100 m have an elliptical, average normalized shape, elongate on a 120–150° orientation. Potholes with long axis lengths >100 m have an average normalized shape that is bilobate and elongate on a 120° orientation. The average aspect ratio (short axis length divided by long axis length) of potholes is highest for potholes with long axis lengths >100 m and lowest for potholes with long axis lengths between 35 and 60 m. The most common long axis orientation for potholes with long axis lengths <100 m is 150° but 120° for long axis lengths >100 m. Fractal analysis indicates that the distribution of pothole centers is controlled neither by a single nor several interacting fractal dimensions. Autocorrelation (Fry) analysis of the distribution of pothole centers shows recurring pothole distribution trends at 038, 070, and 110° for potholes over the full range of long axis lengths, while the trends of 008 and 152° occur in potholes with long axes lengths between 60 and 100 m. Chi-squared (X ²) analysis of the locations of pothole centers suggests that the distribution of small potholes is highly non-uniform but becomes exponentially more uniform with increasing pothole size. The model which best fits the observed shape and distribution analysis is a combination of protracted independent growth and “nearest neighbor” merging along specific orientations. For instance, the clustered distribution of original pothole centers resulted in merged potholes with long axes lengths of up to 60 m, exhibiting short vs long axes ratios of 0.61, preferred orientations of 150°, and alignment along 010 and 150° trends. Further independent growth allowed for merging of similar-sized (and smaller) neighboring potholes, generating potholes with long axes of up to 100 m in length, a preferred long axis orientation of 150°, and alignment along 010, 040, 075, and 150°. Subsequent preferential merging occurred along a 120° trend, thereby preserving a bilobate form. This implies that while pothole initiation and enlargement may be driven by a “top-down” (i.e., possibly thermomechanical) process, an underlying linear or structural catalyst/control is revealed in changes in pothole shape during enlargement and, furthermore, in the preferred trends along which potholes merged over a considerable period, possibly concomitant with adjustment of major structures in the footwall to the Bushveld Complex and pulses into the magma chamber.  相似文献   

Surface temperature differences between minerals in crystalline rocks: Implications for granular disaggregation of granites through thermal fatigue   总被引：4，自引：0，他引：4  

Miguel Gmez-Heras  Bernard J. Smith  Rafael Fort 《Geomorphology》2006,78(3-4):236-249

Thermal expansion differences between minerals within rocks under insolation have previously been assumed to drive breakdown by means of granular disaggregation. However, there have been no definitive demonstrations of the efficacy of this weathering mechanism. Different surface temperatures between minerals should magnify thermal expansion differences, and thus subject adjacent minerals to repeated stresses that might cause breakdown through fatigue failure. This work confirms the existence of surface temperature differences between minerals in granitic rocks under simulated short-term temperature fluctuations so as to discriminate their potential for initiating granular disaggregation. The influence of colour, as a surrogate for albedo, and crystal size, as a function of thermal mass are specifically identified because of their ease of quantification. Four rock types with a range of these properties were examined, and subjected to repeated short-term temperature cycles by radiative heating and cooling under laboratory conditions. Results show that while albedo is the main control for overall and individual maximum temperatures, crystal size is the main factor controlling higher temperature differences between minerals. Thus, stones with large differences of mineral sizes can undergo magnified stresses due to thermal expansion differences.  相似文献   

Relative importance of the Hercynian and post-Jurassic tectonic phases in the Saharan platform: a palaeomagnetic study of Jurassic sills in the Reggane Basin (Algeria)   总被引：2，自引：0，他引：2  

B. Smith  M. E. M. Derder  B. Henry  B. Bayou  A. K. Yelles  H. Djellit  M. Amenna  M. Garces  E. Beamud  J. P. Callot  R. Eschard  A. Chambers  T. Aifa  R. Ait Ouali  H. Gandriche 《Geophysical Journal International》2006,167(1):380-396

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