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41.
42.
An on‐line solid phase extraction method for the preconcentration and determination of Cu(II) by flame atomic absorption spectrometry has been described. The procedure is based on the retention of Cu(II) ions at pH 6.0 on a minicolumn packed with Amberlite XAD‐1180 resin impregnated with chrome azurol S. After preconcentration, Cu(II) ions adsorbed on the impregnated resin were eluted by 1 mol L?1 HNO3 solution. Several parameters, such as pH, type of eluent, flow rates of sample and eluent solutions, amount of resin were evaluated. At optimized conditions, for 3.5 min of preconcentration time, the system achieved a detection limit of 1.0 µg L?1, and a relative standard deviation of 1.2% at 0.2 µg mL?1 copper. An enrichment factor of 56‐fold was obtained with respect to the copper determination. The proposed method was successfully validated by the analysis of standard reference material (TMDA 54.4 lake water) and recovery studies. The method was applied to the preconcentration of Cu(II) in natural water samples.  相似文献   
43.
Turkish regional geoid models have been developed by employing a reference earth gravitational model, surface gravity observations and digital terrain models. The gravimetric geoid models provide a ready transformation from ellipsoidal heights to the orthometric heights through the use of GPS/leveling geoid heights determined through the national geodetic networks. The recent gravimetric models for Turkish territory were computed depending on OSU91 (TG-91) and EGM96 (TG-03) earth gravitational models. The release of the Earth Gravitational Model 2008 (EGM08), the collection of new surface gravity observations, the advanced satellite altimetry-derived gravity over the sea, and the availability of the high resolution digital terrain model have encouraged us to compute a new geoid model for Turkey. We used the Remove-Restore procedure based on EGM08 and applied Residual Terrain Model (RTM) reduction of the surface gravity data. Fast Fourier Transformation (FFT) was then used to obtain the residual quasigeoid from the reduced gravity. We restored the individual contributions of EGM08 and RTM to the whole quasi-geoid height (TQG-09). Since the Helmert orthometric height system is adopted in Turkey, the quasi-geoid model (TQG-09) was then converted to the geoid model (TG-09) by making use of Bouguer gravity anomalies and digital terrain model. After all we combined a gravimetric geoid model with GPS/leveling geoid heights in order to obtain a hybrid geoid model (THG-09) (or a transformation surface) to be used in GPS applications. The RMS of the post-fit residuals after the combination was found to be ± 0.95 cm, which represents the internal precision of the final combination. And finally, we tested the hybrid geoid model with GPS/leveling data, which were not used in the combination, to assess the external accuracy. Results show that the external accuracy of the THG-09 model is ± 8.4 cm, a precision previously not achieved in Turkey until this study.  相似文献   
44.
Antakya city is at risk because of strong earthquakes occurring in the area, and different soil conditions that can produce variation of the ground motion amplification. Microzonation of cities provides a basis for site-specific hazard analysis in urban settlements. In particular, seismic microzonation can be provided by means of detailed seismic assessment of the area, including earthquake recordings and geological studies. In this paper, we propose a preliminary microzonation map for the city of Antakya, based on the variation of the dominant periods and shear velocities of the sediments covering the area. The periods are retrieved from microtremor measurements conducted at 69 sites, using the horizontal-to-vertical spectral ratio technique. The results of microtremor analysis were compared with data obtained from refraction microtremor (ReMi) measurements at four profiles crossing the studied area. According to the classification of dominant periods, Antakya city can be divided into five zones, probably prone to different levels of seismic hazard. The shorter natural periods are in inner Antakya and both the sides of Asi River (i.e., northern and southern parts). The eastern and western parts of Antakya have maximum dominant periods. The V s 30 values were calculated by using the ReMi method along the profiles. Antakya city has V s 30 values in the range of category C of the national earthquake hazard reduction programme site classification.  相似文献   
45.
In 2011, Japan was hit by a tsunami that was generated by the greatest earthquake in its history. The first tsunami warning was announced 3 min after the earthquake, as is normal, but failed to estimate the actual tsunami height. Most of the structural countermeasures were not designed for the huge tsunami that was generated by the magnitude M = 9.0 earthquake; as a result, many were destroyed and did not stop the tsunami. These structures included breakwaters, seawalls, water gates, and control forests. In this paper we discuss the performance of these countermeasures, and the mechanisms by which they were damaged; we also discuss damage to residential houses, commercial and public buildings, and evacuation buildings. Some topics regarding tsunami awareness and mitigation are discussed. The failures of structural defenses are a reminder that structural (hard) measures alone were not sufficient to protect people and buildings from a major disaster such as this. These defenses might be able to reduce the impact but should be designed so that they can survive even if the tsunami flows over them. Coastal residents should also understand the function and limit of the hard measures. For this purpose, non-structural (soft) measures, for example experience and awareness, are very important for promoting rapid evacuation in the event of a tsunami. An adequate communication system for tsunami warning messages and more evacuation shelters with evacuation routes in good condition might support a safe evacuation process. The combination of both hard and soft measures is very important for reducing the loss caused by a major tsunami. This tsunami has taught us that natural disasters can occur repeatedly and that their scale is sometimes larger than expected.  相似文献   
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47.
Results obtained from beachrock lying on the north coast of the antique city of Parion in Çanakkale province, NW Turkey, are presented based on field data, petrographic analyses, cement fabrics, and radiocarbon dating. Extending to 20?m offshore at a depth of ?2?m, the studied 50-cm thick beachrock is poorly sorted lithic sandstone. Both exposed and submerged parts are characterized by sequentially precipitated marine phreatic and vadose cements composed of micrite encrustations with micro-organism borings, pseudopeloidal aggregates of high-Mg calcites with scalenohedral habits and meniscus bridges. Radiocarbon ages point to a deposition during the classical period when the sea level was below (between ?1 and ?1.5?m) that of the present. The beachrock witnesses a granule- and pebble-dominated wide beach prior to cementation, suggesting that Parion’s fortification walls were behind the coastline during this lowstand and raises questions concerning the existence of a harbor north of the city.  相似文献   
48.
Timber constructions have been widely suggested to be seismically resistant based on post-disaster reconnaissance studies. This observation has, however, remained to a large extent anecdotal due to the lack of experimental work supporting it, especially for certain timber architectural forms, including traditional timber frame “h?m??” structures. To fill this gap, the authors carried out an extensive full-scale testing scheme using frames of various geometrical configurations, tested under reverse-cyclic lateral loading with/without infill (brick and adobe) or cladding (ba?dadi and ?amdolma) (Aktas et al. in Earthq Spectra 30(4):1711–1732, 2014a, b). The tests concluded that h?m?? frames had high energy dissipation capabilities due mostly to nailed connections. Infill/cladding significantly helped improve stiffness and lateral load strength of the frames, and timber type did not seem to make a remarkable impact on the overall behaviour. The current paper, on the other hand, uses test data to calculate capacity/demand ratios based on capacity spectrum method and Eurocode 8 to elaborate more on the performance of “h?m??” structures under seismic loading. The obtained results are discussed to draw important conclusions with regards to how frame geometry and infill/cladding techniques affect the overall performance.  相似文献   
49.
Increase in saturation in natural clayey slopes along coastal zones as a result of tsunamis or storm surges may cause flow slides or failures. One of the common treatments is to increase the overall stability by soil replacement and/or re-compaction, which is often difficult to implement, expensive, and, most importantly, damages the natural vegetation. In this paper, remedial effectiveness of a relatively economical and environmentally friendly method involving insertion of geotextile strips with drainage capability into natural clayey slopes is evaluated through a series of centrifuge tests. The test results demonstrate the effectiveness of the employed technique to increase the stability of slopes and their drainage capability as well as to reduce the deformations under surcharge loadings.  相似文献   
50.
The effectiveness of coagulation (at pH values of 6, 7.5, and 9), flocculation (at pH 9), and coagulation plus flocculation (at pH 9) on turbidity removal from natural stone (travertine) processing wastewaters (NSPW) were examined by applying classical sedimentation tests. FeCl3·6 H2O, AlCl3, and Al2(SO4)3·16 H2O were used as coagulants and a polyacrylamide based anionic polymer was used as the flocculant. In this way, it was found that the coagulation method alone was not sufficient to purify NSPW, whereas flocculation and coagulation plus flocculation methods provided superior purification. Among the coagulants used, AlCl3 gave the best result in terms of turbidity removal by coagulation from NSPW at pH 6 and 9, whereas the turbidity removal performances of the three coagulants were almost identical at pH 7.5. In addition, relatively low pH (i. e., pH 6) improved the purification performance of all coagulants. During coagulation of NSPW at pH 6, a charge neutralization mechanism played a decisive role in turbidity removal. However, in neutral (pH 7.5) and slightly basic (pH 9) media, a sweep coagulation mechanism was predominant. For flocculation of NSPW, the basic mechanism comprised of polymer bridging.  相似文献   
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