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111.
Rahman  Zahid  Rehman  Khaista  Ali  Wajid  Ali  Amir  Burton  Paul  Barkat  Adnan  Ali  Asghar  Qadri  S. M. Talha 《Journal of Seismology》2021,25(6):1461-1481
Journal of Seismology - The Pamir-Hindu Kush region is seismically the most dynamic and active zone that went through many devastating earthquakes. While much research is ongoing to produce seismic...  相似文献   
112.
The Pacific Atmospheric Sulfur Experiment (PASE) is the first sulfur-budget field experiment to feature simultaneous flux measurements of DMS marine emissions and SO2 deposition to the ocean surface. We make use of these data to constrain a 1-D chemical transport model to study the production and loss pathways for DMS and SO2 over the equatorial Pacific. Model results suggest that OH is the main sink for DMS in the boundary layer (BL), and the average DMS-to-SO2 conversion efficiency is ~73%. In an exploratory run involving the addition of 1 pptv of BrO as a second oxidant, a 14% increase in the DMS flux is needed beyond that based on OH oxidation alone. This BrO addition also reduces the DMS-to-SO2 conversion efficiency from 73% to 60%. The possibility of non-DMS sources of marine sulfur influencing the estimated conversion efficiency was explored and found to be unconvincing. For BL conditions, SO2 losses consist of 48% dry deposition, while transport loss to the BuL and aerosol scavenging each account for another 19%. The conversion of SO2 to H2SO4 consumes the final 14%. In the BuL, cloud scavenging removes 85% of the SO2, thus resulting in a decreasing vertical profile for SO2. The average SO2 dry deposition velocity from direct measurements (i.e., 0.36 cm sec−1) is approximately 50% of what is calculated from the 1-D model and the global GEOS-Chem model. This suggests that the current generation of global models may be significantly overestimating SO2 deposition rates over some tropical marine areas. Although the specific mechanism cannot be determined, speculation here is that the dry deposition anomalous results may point to the presence of a micro-surface chemical phenomenon involving partial saturation with either S(IV) and/or S(VI) DMS oxidation products. This could also appear as a pH drop in the ocean’s surface microfilm layer in this region. Finally, we propose that the enhanced SO2 level observed in the lower free troposphere versus that in the upper BuL during PASE is most likely the result of transported DMS/SO2-rich free-tropospheric air parcels from the east of the PASE sampling area, rather than an inadequate representation in the model of local convection.  相似文献   
113.
Tidal inundation is a new technique for remediating coastal acid sulfate soils (CASS). Here, we examine the effects of this technique on the geochemical zonation and cycling of Fe across a tidally inundated CASS toposequence, by investigating toposequence hydrology, in situ porewater geochemistry, solid-phase Fe fractions and Fe mineralogy. Interactions between topography and tides exerted a fundamental hydrological control on the geochemical zonation, redistribution and subsequent mineralogical transformations of Fe within the landscape. Reductive dissolution of Fe(III) minerals, including jarosite (KFe3(SO4)2(OH)6), resulted in elevated concentrations of porewater Fe2+ (> 30 mmol L?1) in former sulfuric horizons in the upper-intertidal zone. Tidal forcing generated oscillating hydraulic gradients, driving upward advection of this Fe2+-enriched porewater along the intertidal slope. Subsequent oxidation of Fe2+ led to substantial accumulation of reactive Fe(III) fractions (up to 8000 μmol g?1) in redox-interfacial, tidal zone sediments. These Fe(III)-precipitates were poorly crystalline and displayed a distinct mineralisation sequence related to tidal zonation. Schwertmannite (Fe8O8(OH)6SO4) was the dominant Fe mineral phase in the upper-intertidal zone at mainly low pH (3–4). This was followed by increasing lepidocrocite (γ-FeOOH) and goethite (α-FeOOH) at circumneutral pH within lower-intertidal and subtidal zones. Relationships were evident between Fe fractions and topography. There was increasing precipitation of Fe-sulfide minerals and non-sulfidic solid-phase Fe(II) in the lower intertidal and subtidal zones. Precipitation of Fe-sulfide minerals was spatially co-incident with decreases in porewater Fe2+. A conceptual model is presented to explain the observed landscape-scale patterns of Fe mineralisation and hydro-geochemical zonation. This study provides valuable insights into the hydro-geochemical processes caused by saline tidal inundation of low lying CASS landscapes, regardless of whether inundation is an intentional strategy or due to sea-level rise.  相似文献   
114.
Lead (Pb) isotopic compositions and concentrations, and barium (Ba) and indium (In) concentrations have been determined at monthly resolution in five Law Dome (coastal Eastern Antarctica) ice core sections dated from ∼1757 AD to ∼1898 AD. ‘Natural’ background Pb concentrations in ∼1757 AD average ∼0.2 pg g−1 and can be attributed to mineral dust and volcanic emissions, with 206Pb/207Pb ratios reaching up to 1.266 ± 0.002. From ∼1887 AD to ∼1898 AD, Pb concentrations reached ∼5 pg g−1 and 206Pb/207Pb ratios decreased to 1.058 ± 0.001 as a result of additional inputs of Pb from anthropogenic sources. Seasonal variability in the late 1880s has been investigated by decoupling volcanic Pb from the total measured Pb concentrations, revealing spring and autumn maxima, and consistent winter minima, in anthropogenic Pb and mineral dust (Ba) concentrations. We link this variability to the annual cycle in the position and strength of the Antarctic Circumpolar Trough and, the Southern Ocean westerly winds to the north of the trough region. During the autumn and spring seasons, these systems increase in strength, transporting more impurity laden air from the Southern Hemisphere continental regions to Eastern Antarctica and Law Dome. As this Pb is isotopically identical to that emitted from south-eastern Australia (Broken Hill, Port Pirie) this implies a relatively direct air trajectory pathway from southern Australia to Law Dome (Eastern Antarctica).  相似文献   
115.
Carbonaceous chondrites contain numerous indigenous organic compounds and could have been an important source of prebiotic compounds required for the origin of life on Earth or elsewhere. Extraterrestrial amino acids have been reported in five of the eight groups of carbonaceous chondrites and are most abundant in CI, CM, and CR chondrites but are also present in the more thermally altered CV and CO chondrites. We report the abundance, distribution, and enantiomeric and isotopic compositions of simple primary amino acids in six metal‐rich CH and CB carbonaceous chondrites that have not previously been investigated for amino acids: Allan Hills (ALH) 85085 (CH3), Pecora Escarpment (PCA) 91467 (CH3), Patuxent Range (PAT) 91546 (CH3), MacAlpine Hills (MAC) 02675 (CBb), Miller Range (MIL) 05082 (CB), and Miller Range (MIL) 07411 (CB). Amino acid abundances and carbon isotopic values were obtained by using both liquid chromatography time‐of‐flight mass spectrometry and fluorescence, and gas chromatography isotope ratio mass spectrometry. The δ13C/12C ratios of multiple amino acids fall outside of the terrestrial range and support their extraterrestrial origin. Extracts of CH chondrites were found to be particularly rich in amino acids (13–16 parts per million, ppm) while CB chondrite extracts had much lower abundances (0.2–2 ppm). The amino acid distributions of the CH and CB chondrites were distinct from the distributions observed in type 2 and 3 CM and CR chondrites and contained elevated levels of β‐, γ‐, and δ‐amino acids compared to the corresponding α‐amino acids, providing evidence that multiple amino acid formation mechanisms were important in CH and CB chondrites.  相似文献   
116.
ABSTRACT

The green city is being elevated to the status of a self-evident good in the theory and practice of urban sustainability. A large literature documents the linked environmental, economic and well-being benefits associated with vegetating urban systems to maximise the ecosystem function. Contemporary urban greening seeks to challenge attempts to expel nature from the city in a quest for order and control. However, by imagining nature as a new mode of urban purification, much effort in the name of the green city inverts and reproduces dualistic understandings of natural and built space. In response, we disrupt the normative dialectics of purity and dirt that sustain this dualism to expose the untidy but fertile ground of the green city. We draw together Ash Amin’s four registers of the Good City – relatedness, rights, repair and re-enchantment – with the artworks of the Australian visual ecologist Aviva Reed. Our work seeks to enrich the practice of more-than-human urbanism through ‘dirt thinking’ by imagining the transformative possibilities in, of and for the dirty green city.  相似文献   
117.
This study examines the abundance of trace elements in surface sediments of a former acid sulfate soil (ASS) wetland subjected to marine tidal inundation. Sediment properties of this highly modified study site are compared with those of an adjacent unmodified, intertidal mangrove forest. Whilst some trace elements (Al, Cd, Mn, Ni and Zn) were clearly depleted due to mobilisation and leaching in the previous oxic-acidic phase, other trace elements (As and Cr) displayed significant enrichment in the tidally inundated ASS. Many trace elements were strongly associated with the reactive Fe and acid volatile sulfide (AVS) fractions, suggesting that trace elements may be adsorbed to abundant reactive Fe phases or sequestered as sulfide minerals. These findings provide an important understanding of the fate and mobility of reactive iron, AVS and trace elements during tidal remediation of a formerly acidified Great Barrier Reef (GBR) catchment.  相似文献   
118.
This paper describes statistical procedures for developing earthquake damage fragility functions. Although fragility curves abound in earthquake engineering and risk assessment literature, the focus has generally been on the methods for obtaining the damage data (i.e., the analysis of structures), and little emphasis is placed on the process for fitting fragility curves to this data. This paper provides a synthesis of the most commonly used methods for fitting fragility curves and highlights some of their significant limitations. More novel methods are described for parametric fragility curve development (generalized linear models and cumulative link models) and non‐parametric curves (generalized additive model and Gaussian kernel smoothing). An extensive discussion of the advantages and disadvantages of each method is provided, as well as examples using both empirical and analytical data. The paper further proposes methods for treating the uncertainty in intensity measure, an issue common with empirical data. Finally, the paper describes approaches for choosing among various fragility models, based on an evaluation of prediction error for a user‐defined loss function. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
119.
Concatenating data from the millimetre regime to the infrared, we have performed spectral energy distribution (SED) modelling for 227 of the 405 millimetre continuum sources of Hill et al. which are thought to contain young massive stars in the earliest stages of their formation. Three main parameters are extracted from the fits: temperature, mass and luminosity. The method employed was the Bayesian inference, which allows a statistically probable range of suitable values for each parameter to be drawn for each individual protostellar candidate. This is the first application of this method to massive star formation.
The cumulative distribution plots of the SED modelled parameters in this work indicate that collectively, the sources without methanol maser and/or radio continuum associations (MM-only cores) display similar characteristics to those of high-mass star formation regions. Attributing significance to the marginal distinctions between the MM-only cores and the high-mass star formation sample, we draw hypotheses regarding the nature of the MM-only cores, including the possibility that the population itself comprises different types of source, and discuss their role in the formation scenarios of massive star formation. In addition, we discuss the usefulness and limitations of SED modelling and its application to the field. From this work, it is clear that within the valid parameter ranges, SEDs utilising current far-infrared data cannot be used to determine the evolution of massive protostars or massive young stellar objects.  相似文献   
120.
We present multimolecular line maps obtained with the Mopra telescope towards the southern giant molecular cloud (GMC) complex G333, associated with the H  ii region RCW 106. We have characterized the GMC by decomposing the 3D data cubes with gaussclumps , and investigated spatial correlations among different molecules with principal component analysis (PCA). We find no correlation between clump size and linewidth, but a strong correlation between emission luminosity and linewidth. PCA classifies molecules into high- and low-density tracers, and reveals that HCO+ and N2H+ are anticorrelated.  相似文献   
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