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581.
The lithic units of polymict breccia 14321 (Big Bertha) have been grouped according to composition, texture, degree of metamorphism, and additional criteria based on a systematic study of the interrelationships of all clast-matrix pairs. From this information it has been possible to reconstruct the assembly and metamorphic history of this breccia. The earliest formed fragmental component of 14321 (microbreccia-1) is dominated by KREEP-rich norite, extruded and subsequently brecciated and lithified in an ejecta blanket at approximately 1000°C in the general region of Mare Imbrium after the Serenitatis impact but prior to the Imbrium impact. This early microbreccia component and lesser amounts of mare-type basalt, microgranite, rhyolite glass, anorthosite and olivine microbreccia were assembled at the Apollo 14 site as part of the Fra Mauro ejecta blanket from the Imbrium impact. The resulting microbreccia-3 incorporates all the lithic types above and accretionary lapilli structures (microbreccia-2) in a dark matrix annealed at approximately 700°C. A later impact on the Fra Mauro excavated and mutually abraded microbreccia-3 and a local, 14321-type, basalt which were assembled into polymict breccia 14321. Final placement of 14321 at its sampling location was accomplished during the minor Cone Crater impact event.  相似文献   
582.
Flow splitting in the Rhine valley has been observed with a transportable wind lidar (TWL) during a shallow-foehn event in the framework of the Mesoscale Alpine Programme (MAP). The Doppler lidar recorded in detail flow splitting, foehn wind gusts, and flow reversal. Such structures have not previously been observed with comparable detail by conventional in-situinstruments. In addition to the TWL, boundary-layer processes have been documented by means of rawinsondes and surface stations. This paper presents an analysis of the processes giving birth to flow splitting between the Seez and Rhine valleys during Intensive Observation Period (IOP) 5 (1–3 October 1999) by combining the collected data with hydraulic theory. The study shows thatthe splitting of the channelled flow is associated with (1) the existence of a stagnation point at the intersection of the Seez and Rhine valleys, and (2) the deflection of the flow by the lateral sidewalls of the valleys.  相似文献   
583.
Résumé L'évolution géodynamique hercynienne des Pyrénées se caractérise par une importante activité magmatique à l'origine de corps plutomques de taille, de composition et de niveaux de mise en place différents. A partir de ces caractéristiques nous avons pu établir une typologie qui nous a permis de distinguer deux types principaux de massifs: 1) les massifs de composition homogène, acides (massifs de type HA) ou basiques (massifs de type HB), localisés dans les grands ensembles métamorphiques régionaux et 2) les massifs de composition hétérogène, formés par l'association de roches basiques et de roches acides dont la répartition spatiale a permis de distinguer les massifs de type CA (roches acides au coeur du massif), les massifs de type CB (roches basiques au coer du massif) et les massifs de type CR (récurrences de lentilles de roches basiques dans un massif zoné de type CA ou CB), mis en place dans le Paléozoïque supérieur généralement loin des grands ensembles métamorphiques. Tous ces massifs se sont mis en place diapiriquement au cours du métamorphisme régional et de la déformation hercynienne majeure.
One of the main characteristics of the Hercynian geodynamic evolution of the Pyrenees is an intense magmatic activity producing large plutonic bodies. They have different sizes, various compositions and distinct emplacement levels. From these characteristics, a typology for these massifs is defined. Two main types of massifs have been recognized: 1) massifs with an homogenous composition founded in large regional metamorphic areas, and 2) massifs with an heterogenous composition of acid and basic rocks, whose spatial disposition permits the recognition of three sub-types: a) the CA type where acid rocks are at the core of the massif; b) the CB type where basic rocks are at the core of the massif, and c) the CR type where numerous basic xenoliths are scattered within either a CA or a CB type massif. These heterogenous massifs generally occur within Upper Paleozoic rocks and usually far away from regional metamorphic areas. All of these massifs were emplaced diapirically during the regional metamorphism and the main Hercynian deformation.

Zusammenfassung Ein wichtiges charakteristisches Merkmal der geodynamischen Entwicklung der Pyrenäen während der herzynischen Phase ist eine hohe magmatische Aktivität, auf die Plutone größerer Ausdehnung zurückgeführt werden. Größe, Mineralogie und Erstarrungstiefe der Plutone variieren. Anhand dieser Charakteristika können die Intrusivkörper in zwei Hauptgruppen differenziert werden. Die erste Gruppe (1) sind Plutone homogener Zusammensetzung in regionalmetamorph überprägten Gebieten. Die zweite sind heterogen zusammengesetzte Plutone (2) saurer und basischer Magmatite, deren räumliche Anordnung eine Untergliederung in drei Untergruppen ermöglicht:a) Bei dem CA-Typ befinden sich saure Gesteine im Kern; bei b), dem CB-Typ, liegen basische Gesteine im Kern vor und bei c), einem CR genannten Typ, sind zahlreiche basische Xenolithe entweder in dem CA-oder dem CB-Typ verstreut vorhanden. Diese heterogenen Plutone findet man allein in spätpaläozoischen Gesteinen und in der Regel weit entfernt von Gebieten, die metamorph beeinflußt wurden. Sämtliche Plutone haben eine Diapir-ähnliche Form und intrudierten zeitgleich mit der Regionalmetamorphose und der Hauptphase der herzynischen Deformation.

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584.
585.
Distribution coefficients have been experimentally determined for the partitioning of nickel, cobalt and manganese between calcium-rich clinopyroxenes and coexisting silicate liquids. Temperatures ranged from 1110–1360°C and oxygen fugacities in the furnaces were controlled by gas mixtures at one atmosphere total pressure. Bulk compositions used include synthetic compositions in the system albite-anorthite-diopside and a natural basalt. Charges were doped with a few percent transition metal oxides and analyzed by electron microprobe. Measured clinopyroxene/liquid distribution coefficients range from 1.5–14 for Ni, 0.5–2.0 for Co and 0.3–1.2 for Mn. Diopside/liquid distribution coefficients for nickel are shown to be independent of Ni content over a range of from 3 ppm to 3 wt.% Ni in the liquid and to increase with decreasing temperature. From analyses of pyroxenes grown from experimental charges differing only in the amounts of transition metals present, nickel and cobalt are shown to occupy the M1 site of diopside while manganese occupies both M1 and M2.Ordinary weight ratio distribution coefficients are strongly dependent on liquid composition as well as temperature. For example, experiments on synthetic Ab-An-Di compositions give clinopyroxene/liquid distribution coefficients higher by about a factor of five than those from experiments at the same temperature on a natural basalt. For Ni and Co, which occupy only the M1 site of clinopyroxene, an equilibrium constant can be defined in terms of activities of components in the liquid and solid phases. Activities of components in the solid are approximated by their mole fractions. An activity/concentration model based on the viscosity model of BOTTINGA and WEILL (1972) is used for the liquid. This model approximates the activity of silica as its mole fraction among the network-forming components SiO2, TiO2, KAlO2, NaAlO2 and Ca0.5AlO2.Activities of network modifiers such as CaO are approximated as their mole fractions among the network-modifying components CaO, MgO, FeO, FeO1.5, etc. When these estimated activities are used in the expression for the equilibrium constant, the effects of compositional differences on trace element distribution coefficients can be understood and the results of experiments on synthetic and natural compositions reconciled.  相似文献   
586.
Measurements of the density of deep pelagic bioluminescent zooplankton (BL) were made with the Intensified Silicon Intensifier Target (ISIT) profiler in the Ligurian, Tyrrhenian, Adriatic, Ionian Seas and the Strait of Sicily from ~300 m to near seafloor. Mean BL densities ranged from 2.61 m?3 at 500–1000 m depth in the Adriatic Sea to 0.01 m?3 at 4000–5000 m depth in the E Ionian Sea. We investigated drivers of spatial variation of deep pelagic BL density. Linear regression was applied between surface chlorophyll a (Chl a) concentration and underlying BL density. Chl a values were determined from satellite derived 100 km radius composites (six 10-day means per ISIT deployment, over preceding 60 days). At 500–1000 m depth we found a significant positive relationship between mean BL density and mean Chl a in the period prior to 0–10 days (at 1% level) and prior to 10–40 days (at 5% level). Beyond 40 days no relationship between BL density and Chl a was found at this depth. At depths 1000–1500 m BL density values were low and no significant relationship with Chl a was detected. Generalised additive modelling (GAM) was used to assess the influence of benthic hotspots (seamount; cold water coral mound; mud volcano) on overlying BL density. A reduction in BL density was found downstream of the Palinuro seamount from 300 to 600 m. No effect on BL density in the overlying water column was detected from the presence of cold water corals. Higher BL densities were detected over the W Madonna dello Ionio mud volcano than at other sites sampled in the NW Ionian Sea. We find surface Chl a to be a good predictor of BL density in the mesopelagic zone; below this depth we hypothesise that processes affecting the efficiency of particle export to deep water may exert greater influence on BL density.  相似文献   
587.
588.
The identification of metal provenance is often based on chemical and Pb isotope analyses of materials from the operating chain, mainly ores and metallic artefacts. Such analyses, however, have their limits. Some studies are unable to trace metallic artefacts or ingots to their ore sources, even in well-constrained archaeological contexts. Possible reasons for this difficulty are to be found among a variety of limiting factors: (i) problems of ore signatures, (ii) mixing of different ores (alloys), (iii) the use of additives during the metallurgical process, (iv) metal recycling and (v) possible Pb isotopic fractionation during metal production. This paper focuses on the issue of Pb isotope fractionation during smelting to address the issue of metal provenance. Through an experimental reconstruction of argentiferous Pb production in the medieval period, an attempt was made to better understand and interpret the Pb isotopic composition of ore smelting products. It is shown that the measured differences (outside the total external uncertainties of 0.005 (2*sd) for 206Pb/204Pb ratios) in Pb signatures measured between ores, slag and smoke are not due to Pb mass fractionation processes, but to (1) ore heterogeneity (Δ206Pb/204Pbslag-ores = 0.066) and (2) the use of additives during the metallurgical process (Δ206Pb/204Pbslag-ores = 0.083). Even if these differences are due to causes (1) and/or (2), smoke from the ore reduction appears to reflect the ore mining area without a significant disturbance of its Pb signature for all the isotopic ratios (Δ206Pb/204Pbsmokes-ores = 0.026). Thus, because the isotopic heterogeneity of the mining district and additives is averaged in slags, slag appears as the most relevant product to identify ancient metal provenance. Whereas aiming at identifying a given mine seems beyond the possibilities provided by the method, searching for the mining district through analysis of the smelting workshop materials should provide a more appropriate approach in cases where no archaeological evidence of ancient mining is available. Furthermore, smoke Pb isotopic composition does not seem to be significantly affected by the metallurgical process. Paleopollution recorded in peat deposits could help to detect ancient mining production and workshops. Integrated collaboration between mining archaeologists and geochemists appears crucial to achieve this goal.  相似文献   
589.
The study of the creation and evolution of the excavation disturbed zone (EDZ) in argillaceous rocks is a major issue for the safety of nuclear wastes underground repositories. In this context, the argillaceous Tournemire site has provided a unique opportunity to study the evolution of the EDZ with time thanks to the existence of three openings of different ages. A thorough characterization of the EDZ has been conducted by different means such as visual observation, analysis of samples extracted from drilled boreholes, EDZ permeability measurements, etc. On the basis of these measurements, a conceptual model of the EDZ initiation and propagation at the Tournemire site has been proposed. In order to validate this model, numerical simulations of increasing complexity have been carried out. In a first attempt, the response of the rock mass to the excavation phase, followed by seasonal cyclic variations of temperature and relative humidity inside the opening, has been simulated by means of a purely mechanical analysis, using a simple elastic material model. The EDZ has been estimated by post-processing the calculated stress states, using a Mohr–Coulomb failure criterion. The results obtained show that no EDZ could be predicted unless adopting a low cohesion value for the rock mass. Moreover, the deferred nature of the EDZ formation in Tournemire could not be reproduced. These limitations have then been suppressed by using a coupled viscoplastic-damaging mechanical model, the parameters of which have been identified from different laboratory experiments. With this model, a time evolution of the EDZ could be predicted, but the EDZ pattern could not match the one observed in situ. Finally, in view of the importance of the hydraulic couplings, unsaturated hydro-mechanical calculations have been carried out to investigate the effect of the numerous seasonal variations cycles and the resulting shrinkage.  相似文献   
590.
Groundwater flow modelling in the central zone of Hanoi, Vietnam   总被引:3,自引:2,他引:1  
On the basis of a review of the Quaternary sedimentary architecture in the area of Hanoi city (Vietnam), a numerical, deterministic and three-dimensional groundwater flow model has been built for a simulation between 1995 and 2004. The sedimentary architecture has been constructed on the basis of the data from 32 drillings covering the entire Quaternary sequence (but with little sedimentological detail), as well as hydrographical and hydrogeological data. Both steady- and transient-state conditions were tested. Results calculated by the model seem to indicate that the conceptual hypotheses adopted are reasonable for the modelled domain and period. The simulation allows for calculation of the regional groundwater flow trends. It is also used for assessing the relative importance of the various recharge sources of the shallow aquifer system in Hanoi, and for estimating the interactions between groundwater and the Red River.  相似文献   
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