On the Temperature and Humidity Dissimilarity in the Marine Surface Layer     

Xiaoli Guo Larsén  Mark Kelly  Anna Maria Sempreviva 《Boundary-Layer Meteorology》2014,151(2):273-291

The dissimilarity of temperature and humidity transfer in the marine surface layer (MSL) is investigated through the relative transport efficiency and correlation coefficient of these two scalars. We examine their variability and relationship with mean values, as well as spectral characteristics. It is shown that the dissimilarity between these two scalars in the MSL is a function of stability, the boundary-layer depth, and flow steadiness. In general the temperature and humidity are less correlated in shallow marine boundary layers compared to deep marine boundary layers, due to the stronger impact of the boundary-layer scale in breaking the “same source, same sink” assumption for scalar similarity. This is supported by the combination of our spectral analysis of scalar fluxes and corresponding measured and modelled boundary-layer depth. This assumption is also broken in near-neutral conditions, when there is an efficient latent heat transfer but negligible sensible heat transfer. Our data suggest that parametrization of humidity fluxes via similarity theory could still be reliable when the correlation coefficient $>$ 0.5, and in near-neutral conditions the humidity flux can be estimated without use of the sensible heat flux.  相似文献   

A reassessment of the soil sink for atmospheric carbon tetrachloride based upon static flux chamber measurements     

James D. Happell  Yudania Mendoza  Kelly Goodwin 《Journal of Atmospheric Chemistry》2014,71(2):113-123

Static flux chamber measurements of CCl₄ uptake by soils in boreal, subtropical and tropical forests have been used to reassess the sink strength for this ozone depleting chemical. Happell and Roche (Geophys. Res. Lett. 30(2), 1088–1091, 2003) used flux estimates from soil concentration gradients to calculate a partial CCl₄ atmospheric lifetime (τ_soil) of 90 years. More recently, it is has been assumed that a better estimate of τ_soil is 195 years (Montzka et al. 2011). In the work here, the rate of CCl₄ uptake was calculated from 453 flux chamber measurements using an exponential fit to the chamber CCl₄ concentration change with time. This analysis indicated that the flux rate estimate in Happell and Roche (Geophys. Res. Lett. 30(2) 1088–1091, 2003) was overestimated by 2.75, yielding a new estimate of τ_soil for CCl₄ of 245 years. Significant correlations of CCl₄ uptake to temperature, soil moisture, or time of year were not observed. This work provides additional evidence that CCl₄ uptake by soils is a common process and needs to be considered when developing an atmospheric budget for this compound.  相似文献   

Do S-type granites commonly sample infracrustal sources? New results from an integrated O, U–Pb and Hf isotope study of zircon     

Sarah K. Appleby  Martin R. Gillespie  Colin M. Graham  Richard W. Hinton  Grahame J. H. Oliver  Nigel M. Kelly 《Contributions to Mineralogy and Petrology》2010,160(1):115-132

In contrast to I-type granites, which commonly comprise infracrustal and supracrustal sources, S-type granites typically incorporate predominantly supracrustal sources. The initial aim of this study was to identify the sources of three Scottish Caledonian (~460 Ma) S-type granites (Kemnay, Cove and Nigg Bay) by conducting oxygen, U–Pb and Hf isotope analyses in zircon in order to characterise one potential end-member magma involved in the genesis of the voluminous late Caledonian (~430–400 Ma) I-type granites. Field, whole-rock geochemical and isotopic data are consistent with the generation of the S-type granites by melting their Dalradian Supergroup country rocks. While Hf isotope compositions of magmatic zircon, U–Pb data of inherited zircons, and high mean zircon δ¹⁸O values of 9.0 ± 2.7‰ (2SD) and 9.8 ± 2.0‰ for the Kemnay and Cove granites support this model, the Nigg Bay Granite contains zircons with much lower δ¹⁸O values (6.8 ± 2.1‰), similar to those found in Scottish I-type granites. This suggests that the Nigg Bay Granite contains low-δ¹⁸O material representing either altered supracrustal material, or more likely, an infracrustal source component with mantle-like δ¹⁸O. Mixing trends in plots of δ¹⁸O vs. εHf for S-type granite zircons indicate involvement of at least two sources in all three granites. This pilot study of Scottish Caledonian S-type granites demonstrates that, while field and whole-rock geochemical data are consistent with local melting of only supracrustal sources, the oxygen isotopic record stored in zircon reveals a much more complex petrogenetic evolution involving two or more magma sources.  相似文献   

Using Stable Isotope Mixing in a Great Lakes Coastal Tributary to Determine Food Web Linkages in Young Fishes     

Joel C. Hoffman  Gregory S. Peterson  Anne M. Cotter  John R. Kelly 《Estuaries and Coasts》2010,33(6):1391-1405

We characterized stable isotope mixing along a river-Great Lake transition zone in the St. Louis River, an important fish nursery in western Lake Superior, and used it to identify food web linkages supporting young fish production. We observed a broad, spatial pattern in the carbon stable isotope ratio (δ¹³C); downriver enrichment in particulate organic carbon and aquatic vegetation δ¹³C, as well as pelagic, benthic and littoral invertebrate δ¹³C, reflected isotope mixing along the river-lake transition zone. Fishes with similarly enriched δ¹³C were used to identify benthopelagic and littoral trophic pathways. River and Lake Superior organic matter (OM) sources contributed to both pathways. Differences between the δ¹³C in fishes and invertebrate prey revealed that fish production was supported at multiple spatial scales. The result was that the food web specific to any location along the transition zone incorporated multiple OM sources from across the watershed.  相似文献   

Impacts of Oyster Reef Restoration on Primary Productivity and Nutrient Dynamics in Tidal Creeks of the North Central Gulf of Mexico     

Rochelle Plutchak  Kelly Major  Just Cebrian  C. Drew Foster  Mary-Elizabeth C. Miller  Andrea Anton  Kate L. Sheehan  Kenneth L. HeckJr.  Sean P. Powers 《Estuaries and Coasts》2010,33(6):1355-1364

The ability of oysters to remove large quantities of particulates from the water column, thereby potentially improving water quality, has been cited as one of the reasons for oyster reef restoration. However, this ability has not yet been effectively demonstrated in the field. As part of the Alabama Oyster Reef Restoration Project, this study was designed to assess impacts of restored eastern oyster (Crassostrea virginica) reefs on primary production, nutrient dynamics, and water quality in shallow tidal creeks. Using a Before–After-Control–Impact (BACI) design, we monitored tidal creeks around Dauphin Island, AL, for changes induced by the introduction of oyster reefs. Reef placement resulted in increased ammonium (NH₄⁺) in two of the three experimental creeks. Interestingly, oyster reefs did not seem to reduce water column particulates or have an impact on phytoplankton or microphytobenthic biomass or productivity. We do not believe that our data discount the importance and/or usefulness of oysters in modifying the water column. Rather, we acknowledge that it is difficult to detect these impacts/environmental services in this type of system (i.e., a tidal creek system), because they seem to be very localized and short-lived (i.e., not ecologically relevant on a creek-wide scale). This study highlights the need to consider location and habitat in planning oyster restoration projects. Also, it demonstrates that the types, magnitudes, and spatial extent of changes in ecosystem services that should be expected after reef restoration might need to be re-evaluated.  相似文献   

Using chloride and other ions to trace sewage and road salt in the Illinois Waterway     

Walton R. Kelly  Samuel V. Panno  Keith C. Hackley  Hue-Hwa Hwang  Adam T. Martinsek  Momcilo Markus 《Applied Geochemistry》2010

Chloride concentrations in waterways of northern USA are increasing at alarming rates and road salt is commonly assumed to be the cause. However, there are additional sources of Cl⁻ in metropolitan areas, such as treated wastewater (TWW) and water conditioning salts, which may be contributing to Cl⁻ loads entering surface waters. In this study, the potential sources of Cl⁻ and Cl⁻ loads in the Illinois River Basin from the Chicago area to the Illinois River’s confluence with the Mississippi River were investigated using halide data in stream samples and published Cl⁻ and river discharge data. The investigation showed that road salt runoff and TWW from the Chicago region dominate Cl⁻ loads in the Illinois Waterway, defined as the navigable sections of the Illinois River and two major tributaries in the Chicago region. Treated wastewater discharges at a relatively constant rate throughout the year and is the primary source of Cl⁻ and other elements such as F⁻ and B. Chloride loads are highest in the winter and early spring as a result of road salt runoff which can increase Cl⁻ concentrations by up to several hundred mg/L. Chloride concentrations decrease downstream in the Illinois Waterway due to dilution, but are always elevated relative to tributaries downriver from Chicago. The TWW component is especially noticeable downstream under low discharge conditions during summer and early autumn when surface drainage is at a minimum and agricultural drain tiles are not flowing.  相似文献