Evidence for the loss of snow-deposited MSA to the interstitial gaseous phase in central Antarctic firn     

R. J. DELMAS  P. WAGNON  K. GOTO-AZUMA  K. KAMIYAMA  O. WATANABE 《Tellus. Series B, Chemical and physical meteorology》2003,55(1):71-79

We have examined several MSA (methanesulfonic acid) records from the upper 200 m of the Antarctic ice sheet and in particular the new Dome F profile. At all the four sites studied, concentration profiles exhibit similar patterns as a function of depth. They suggest that snow metamorphism and solid phase migration are responsible for a marked release of gaseous MSA to interstitial firn air as well as probably to the free atmosphere, in particular at extremely low accumulation sites. Snow acidity can also modify MSA concentration. It is proposed that, below the upper few metres where the communication with the free atmosphere is possible, gaseous MSA may remain in the firn layers and be entrapped later in air bubbles at pore close-off, i.e. when firn is transformed into ice. Chemical measurements on the firn core do not take into account the MSA released to the gaseous phase, but this fraction is measurable in ice samples. In spite of these alterations occurring in the firn layers, relative changes of the atmospheric MSA concentration in the past are probably still there deep within the Antarctic ice sheet. However, for glacial periods, different processes have to be considered in relation to modified aerosol properties.  相似文献   

Tephrochronology and tephrostratigraphy of two Pleistocene continental fossiliferous successions from central Italy     

F. Marcolini  G. Bigazzi  F. P. Bonadonna  E. Centamore  R. Cioni  G. Zanchetta 《第四纪科学杂志》2003,18(6):545-556

The stratigraphical context of two Middle Pleistocene fossiliferous palaeosols from Central Italy (Abruzzo and Tuscany) have been studied. Small mammals and molluscs occur in both palaeosols, which are covered by tephra layers that were analysed using an interdisciplinary approach. Application of fission‐track dating to apatites separated from the Case Picconetto tephra (Pescara, Abruzzo), yielded an age of 0.48 ± 0.04 Ma, indistinguishable from those previously determined for the Campani Quarry (Lower Valdarno, Tuscany) (0.46 ± 0.05 Ma and 0.48 ± 0.05 Ma). Geochemical and petrographic investigations indicate that these tephra originated from different volcanoes, the Alban Hills Volcanic Complex and the Vico Volcano (Latium) respectively. Small mammal and mollusc assemblages indicate different palaeoclimatic and palaeoenvironmental conditions for the Case Picconetto and Campani Quarry palaeosols. Warm and humid conditions can be inferred for the Campani Quarry site, whereas open and cold conditions can be inferred for Case Picconetto. On the basis of faunal data, fission‐track dates and attribution of tephra to specific volcanic eruptions, we suggest a correlation of these faunas with marine oxygen isotope stage 14 (Case Picconetto) and with marine oxygen isotope stage 11 (Campani Quarry), respectively. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Reliability assessment of granular filters in embankment dams     

Roberto Mínguez  Fernando Delgado  Ignacio Escuder  Manuel G. de Membrillera 《国际地质力学数值与分析法杂志》2006,30(10):1019-1037

Empirical criteria have been used successfully to design filters of most embankment large dam projects throughout the world. However, these empirical rules are only applicable to a particular range of soils tested in laboratory and do not take into account the variability of the base material and filter particle sizes. In addition, it is widely accepted that the safety of fill dams is mainly dependent on the reliability of their filter performance. The work herein presented consists in a new general method for assessing the probability of fulfilling any empirical filter design criteria accounting for base and filter heterogeneity by means of first‐order reliability methods (FORM), so that reliability indexes and probabilities of fulfilling any particular criteria are obtained. This method will allow engineers to estimate the safety of existing filters in terms of probability of fulfilling their design criteria and might also be used as a decision tool on sampling needs and material size tolerances during construction. In addition, sensitivity analysis makes possible to analyse how reliabilities are influenced by different sources of input data. Finally, in case of a portfolio risk assessment, this method will allow engineers to compare the safety of several existing dams in order to prioritize safety investments and it is expected to be a very useful tool to evaluate probabilities of failure due to internal erosion. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

Amino acid analyses of Antarctic CM2 meteorites using liquid chromatography‐time of flight‐mass spectrometry     

Daniel P. Glavin  Jason P. Dworkin  Andrew Aubrey  Oliver Botta  James H. Doty  Zita Martins  Jeffrey L. Bada 《Meteoritics & planetary science》2006,41(6):889-902

Abstract— Amino acid analyses of the Antarctic CM2 chondrites Allan Hills (ALH) 83100 and Lewis Cliff (LEW) 90500 using liquid chromatography‐time of flight‐mass spectrometry (LC‐ToF‐MS) coupled with UV fluorescence detection revealed that these carbonaceous meteorites contain a suite of indigenous amino acids not present in Antarctic ice. Several amino acids were detected in ALH 83100, including glycine, alanine, β‐alanine, γ‐amino‐n‐butyric acid (γ‐ABA), and α‐aminoisobutyric acid (AIB) with concentrations ranging from 250 to 340 parts per billion (ppb). In contrast to ALH 83100, the CM2 meteorites LEW 90500 and Murchison had a much higher total abundance of these amino acids (440–3200 ppb). In addition, ALH 83100 was found to have lower abundances of the α‐dialkyl amino acids AIB and isovaline than LEW 90500 and Murchison. There are three possible explanations for the depleted amino acid content in ALH 83100: 1) amino acid leaching from ALH 83100 during exposure to Antarctic ice meltwater, 2) a higher degree of aqueous alteration on the ALH 83100 parent body, or 3) ALH 83100 originated on a chemically distinct parent body from the other two CM2 meteorites. The high relative abundance of ?‐amino‐n‐caproic acid (EACA) in the ALH 83100 meteorite as well as the Antarctic ice indicates that Nylon‐6 contamination from the Antarctic sample storage bags may have occurred during collection.  相似文献   

Opening angles, Lorentz factors and confinement of X-ray binary jets     

J. C. A. Miller-Jones  R. P. Fender  E. Nakar 《Monthly notices of the Royal Astronomical Society》2006,367(4):1432-1440

We present a collation of the available data on the opening angles of jets in X-ray binaries, which in most cases are small (≲10°). Under the assumption of no confinement, we calculate the Lorentz factors required to produce such small opening angles via the transverse relativistic Doppler effect. The derived Lorentz factors, which are in most cases lower limits, are found to be large, with a mean >10, comparable to those estimated for active galactic nuclei (AGN) and much higher than the commonly assumed values for X-ray binaries of 2–5. Jet power constraints do not, in most cases, rule out such high Lorentz factors. The upper limits on the opening angles show no evidence for smaller Lorentz factors in the steady jets of Cygnus X-1 and GRS 1915+105. In those sources in which deceleration has been observed (notably  XTE J1550−564  and Cygnus X-3), some confinement of the jets must be occurring, and we briefly discuss possible confinement mechanisms. It is however possible that all the jets could be confined, in which case the requirement for high bulk Lorentz factors can be relaxed.  相似文献   

The 2dF QSO Redshift Survey – XII. The spectroscopic catalogue and luminosity function     

S. M. Croom  R. J. Smith  B. J. Boyle  T. Shanks  L. Miller  P. J. Outram  N. S. Loaring 《Monthly notices of the Royal Astronomical Society》2004,349(4):1397-1418

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The impact of broad mid-infrared emission bands on extragalactic surveys – a case study: the unidentified 22-μm feature     

Chris P. Pearson  K.-W. Chan  T. Onaka 《Monthly notices of the Royal Astronomical Society》2004,350(2):473-484

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High-resolution observations of a complete sample of 27 FR II radio galaxies and quasars with 0.3 < z < 0.6     

G. M. Gilbert  J. M. Riley  M. J. Hardcastle  J. H. Croston  G. G. Pooley  P. Alexander 《Monthly notices of the Royal Astronomical Society》2004,351(3):845-890

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Radiation exposure and Mission Strategies for Interplanetary Manned Missions (REMSIM)   总被引：1，自引：0，他引：1  

C. Cougnet  N. B. Crosby  S. Eckersley  C. Foullon  V. Guarnieri  S. Guatelli  D. Heynderickx  A. Holmes-Siedle  C. Lobascio  S. Masiello  P. Nieminen  G. Parisi  P. Parodi  M. A. Perino  M. G. Pia  R. Rampini  P. Spillantini  V. Tamburini  E. Tracino 《Earth, Moon, and Planets》2004,94(3-4):279-285

Cosmic radiation is an important problem for human interplanetary missions. The “Radiation Exposure and Mission Strategies for Interplanetary Manned Missions–REMSIM” study is summarised here. They are related to current strategies and countermeasures to ensure the protection of astronauts from radiation during interplanetary missions, with specific reference to: radiation environment and its variability; radiation effects on the crew; transfer trajectories and associated fluences; vehicle and surface habitat concepts; passive and active shielding concepts; space weather monitoring and warning systems.  相似文献   

Chemical alteration of tephra in the depositional environment: theoretical stability modelling     

A. M. Pollard  S. P. E. Blockley  K. R. Ward 《第四纪科学杂志》2003,18(5):385-394

The study of the chemical stability of vitreous material in aqueous media is well‐established. There has to date been little consideration of the implications of variations in the chemical durability of tephra in Quaternary tephrochronology. Chemical alteration can take the form of cationic leaching from the matrix, or complete destruction of the silica network, either of which could constrain the ability to chemically identify distal tephra. Here we apply established models of vitreous durability to the published chemical analyses of a large number of Icelandic tephras in order to predict their relative durabilities under equivalent conditions. This suggests that some important tephras have relatively poor chemical stability, and that rhyolitic tephras are, in general, more stable than basaltic. We conclude that tephras should be expected to show predictable differential chemical stability in the post‐depositional environment. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献