Growth and potential of the ICES Journal of Marine Science     

Payne  Andrew I.L.; Barranguet  Christiane 《ICES Journal of Marine Science》2005,62(1):1-2

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Modelling the equilibrium speciation of nickel in the Tweed Estuary, UK: Voltammetric determinations and simulations using WHAM     

Andrew Turner  Manuela Martino   《Marine Chemistry》2006,102(3-4):198-207

The complexation of dissolved Ni has been evaluated in a rapidly-flushed, rural estuary (Tweed, UK) by ligand exchange-adsorptive cathodic stripping voltammetry. Results suggest the presence of strongly binding ligands, L, throughout, with average stability constants of about 10¹⁹ and which are saturated by ambient Ni concentrations. Equilibrium speciation calculations incorporating these constants in WHAM, version 6, predict an increase in Ni complexation (as NiL) from about 50% of total dissolved Ni in fresh water to over 90% in sea water. Equivalent calculations using the default-mode fulvic and humic substances (FS and HS, respectively) encoded in the WHAM database predict a reduction in complexation (as NiFS + NiHS) from about 20% in fresh water to less than 1% in sea water. Discrepancies arising from the two approaches are largely attributed to the different analytical detection windows employed. Thus, a better representation of Ni complexation is derived from including both types of complexant in the speciation calculations, resulting in estimates of net complexation in excess of 60% of total dissolved Ni throughout the estuary. The uncertainties and assumptions inherent in all computations illustrate the difficulty in measuring or predicting metal complexation in estuaries.  相似文献   

Petroleum geochemistry of the Kimmeridge Clay of onshore Southern and Eastern England     

Paul F. V. Williams 《Marine and Petroleum Geology》1986,3(4)

The Kimmeridge Clay is considered a major oil source rock for the North Sea hydrocarbon province. The formation is also developed onshore in an organic-rich mudstone facies. This paper examines the possibility of onshore oil generation from the Kimmeridge Clay. Geochemically, onshore basin margin sediments contain rich, potential source horizons with mainly Type l/Type ll oil-prone kerogen, but are immature. Some deeper Cleveland Basin sediments have reached marginal maturity. Burial history reconstruction suggests significant formation palaeoburial depths in central areas of the Cleveland and Wessex Basins. Computed vitrinite isoreflectance contours show the Wealden and Isle of Wight Kimmeridge Clay to be thermally mature. Basin modelling suggests an early Palaeogene onset of oil generation in parts of the Cleveland Basin, while maximum oil generation could have been reached by the formation base in the Isle of Wight area during the late Cretaceous. Although basin subsidence ceased in the Neogene, in the Weald and Isle of Wight, where the formation is still deeply buried, oil generation probably continued for some time during uplift. Thus significant quantities of oil could have been generated. Whether or not this oil is present today however, would depend on the correct timing of suitable migration and trap structures.  相似文献   

North Pacific Synthesis of the Joint Global Ocean Flux Study: Overview     

Toshiro Saino  Alexander Bychkov  Chen-Tung Arthur Chen  Paul J. Harrison 《Journal of Oceanography》2004,60(1):1-4

This special issue is comprised of 13 papers, including this overview, and focuses on the synthesis of the Joint Global Ocean Flux Study (JGOFS) in the North Pacific which took place from 1997 through 2003. The effort was led by the JGOFS North Pacific Synthesis Group, with the aim of quantifying CO₂ drawdown by physical and biological pumps in the North Pacific by identifying and studying the regional, seasonal to inter-annual variations in the key processes, and understanding their regulating mechanisms. Emphasis was placed on the similarities and differences of the biogeochemical regimes in the eastern and western subarctic Pacific. Effort was also made to address the future research directions which arose from the scientific findings during the North Pacific JGOFS process study. A brief overview of the papers from view points of CO₂ drawdown by physical and biological pumps, spatial variability, and temporal variability from seasonal to decadal scales is made, followed by suggestions for the directions of future research. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

The composition and distribution of saturated and aromatic hydrocarbons in nearshore sediments, river sediments, and coastal peat of the Alaskan Beaufort Sea: Implications for detecting anthropogenic hydrocarbon inputs     

Margarete S. Steinhauer  Paul D. Boehm   《Marine environmental research》1992,33(4)

A 3-year program, to determine spatial and temporal trends in sediment concentrations of hydrocarbons and metals from oil and gas exploration and development activities, was conducted in the US Beaufort Sea. Concentrations of saturated and aromatic hydrocarbons in sediments from the Beaufort Sea were elevated in comparison to non-polluted shelf-sediments from other regions of the US coast. Potential natural sources for hydrocarbons that were examined included riverine sediments and coastal peat. Significant quantities of fossil hydrocarbons characterize the surface sediments from the entire region. Sediment inputs from river discharges appear to account for this observation. The use of source-diagnostic ratios has allowed the differentiation of various sources in an area with high naturally-occurring hydrocarbon concentrations where effects due to oil and gas exploration and development activities may be obscured.  相似文献   

Laboratory measurements of uniform longshore currents: Reply to the comments of C.J. Galvin     

Paul J. Visser   《Coastal Engineering》1992,18(3-4)

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Interannual variability in Nordic seas primary production   总被引：1，自引：0，他引：1  

Skogen  Morten D.; Budgell  W. Paul; Rey  Francisco 《ICES Journal of Marine Science》2007,64(5):889-898

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Acoustic and stiffness properties of gillnets as they relate to small cetacean bycatch     

Mooney  T. Aran; Au  Whitlow W. L.; Nachtigall  Paul E.; Trippel  Edward A. 《ICES Journal of Marine Science》2007,64(7):1324-1332

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Simulating trawl herding in flatfish: the role of fish length in behaviour and swimming characteristics   总被引：2，自引：0，他引：2  

Winger  Paul D.; Walsh  Stephen J.; He  Pingguo; Brown  Joseph A. 《ICES Journal of Marine Science》2004,61(7):1179-1185

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Autonomous underwater vehicles: future platforms for fisheries acoustics   总被引：3，自引：1，他引：3  

Fernandes  Paul G; Stevenson  Pete; Brierley  Andrew S; Armstrong  Frederick; Simmonds  E.John 《ICES Journal of Marine Science》2003,60(3):684-691

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