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Previous studies on lipid biomarkers preserved in Chinese stalagmites have indicated that ratios of low‐molecular‐weight (LMW) to high‐molecular‐weight (HMW) n‐alkanes, n‐alkan‐2‐ones, n‐alkanols and n‐alkanoic acids can be used as an index of vegetation versus microbial organic matter input to the system and, by extension, a marker of climatic changes, with increases in the proportion of LMW compounds coinciding with colder periods. Here we test whether this hypothesis is equally applicable to a different geographical region (north‐west Scotland), by examining a stalagmite record of the past 200 years, and a wider range of lipid markers. We also test the applicability of other lipid proxies in this context, including the use of n‐alkane ratios, to interpret vegetation changes, and unsaturated alkanoic acid ratios as climatic indicators. The results show that lipid proxies preserved in stalagmites, and especially those related to vegetation, are potentially extremely useful in palaeoenvironmental research. Of particular value is the use of C27/C31 n‐alkane ratios as a proxy for vegetation change, clearly indicating variations between herbaceous and arboreal cover. This proxy has now been successfully applied to samples from diverse environments, and can be considered sufficiently robust to be of use in analysing future stalagmite records. It will be of particular value in areas where reliable pollen records are not available, as is often the case with deeper cave deposits. However, the division between LMW and HMW aliphatic compounds is not a clear‐cut case of microbial versus plant activity, with the changes in LMW compounds relating more closely to those in their HMW analogues than in specific bacterial biomarkers. The use of unsaturated alkanoic acid ratios here gives conflicting results, with the observed variation through time depending on the isomer measured. The discrepancies between the findings of this study and previous work are likely to be due to the varying controls on the lipids (original organic matter input, and compound degradation), which in turn will be affected by whether the main climatic limiting factor on the soil is temperature or precipitation. This suggests that lipid proxies preserved in stalagmites must be interpreted with care, particularly in the case of bacterial compounds which may be derived from within the cave or from the soil. However, many of these issues can be resolved by the use of multi‐proxy studies. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   
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Water levels in cryoconite holes were monitored at high resolution over a 3‐week period on Austre Brøggerbreen (Svalbard). These data were combined with melt and energy balance modelling, providing insights into the evolution of the glacier's near‐surface hydrology and confirming that the hydrology of the near‐surface, porous ice known as the ‘weathering crust’ is dynamic and analogous to a shallow‐perched aquifer. A positive correlation between radiative forcing of melt and drainage efficiency was found within the weathering crust. This likely resulted from diurnal contraction and dilation of interstitial pore spaces driven by variations in radiative and turbulent fluxes in the surface energy balance, occasionally causing ‘sudden drainage events’. A linear decrease in water levels in cryoconite holes was also observed and attributed to cumulative increases in near‐surface ice porosity over the measurement period. The transport of particulate matter and microbes between cryoconite holes through the porous weathering crust is shown to be dependent upon weathering crust hydraulics and particle size. Cryoconite holes therefore yield an indication of the hydrological dynamics of the weathering crust and provide long‐term storage loci for cryoconite at the glacier surface. This study highlights the importance of the weathering crust as a crucial component of the hydrology, ecology and biogeochemistry of the glacier ecosystem and glacierized regions and demonstrates the utility of cryoconite holes as natural piezometers on glacier surfaces. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
14.
The transition from the last glacial and beginning of Bølling–Allerød and Pre‐Boreal periods in particular is marked by rapid increases in atmospheric methane (CH4) concentrations. The CH4 concentrations reached during these intervals, ~650–750 ppb, is twice that at the last glacial maximum and is not exceeded until the onset of industrialization at the end of the Holocene. Periods of rapid sea‐level rise as the Last Glacial Maximum ice sheets retreated and associated with ‘melt‐water pulses’ appear to coincide with the onset of elevated concentrations of CH4, suggestive of a potential causative link. Here we identify and outline a mechanism involving the flooding of the continental shelves that were exposed and vegetated during the glacial sea‐level low stand and that can help account for some of these observations. Specifically, we hypothesize that waterlogging (and later, flooding) of large tracts of forest and savanna in the Tropics and Subtropics during the deglacial transition and early Holocene would have resulted in rapid anaerobic decomposition of standing biomass and emission of methane to the atmosphere. This novel mechanism, akin to the consequences of filling new hydroelectric reservoirs, provides a mechanistic explanation for the apparent synchronicity between rate of sea‐level rise and occurrence of elevated concentrations of ice core CH4. However, shelf flooding and the creation of transient wetlands are unlikely to explain more than ~60 ppb of the increase in atmospheric CH4 during the deglacial transition, requiring additional mechanisms to explain the bulk of the glacial to interglacial increase. Similarly, this mechanism has the potential also to play some role in the rapid changes in atmospheric methane associated with the Dansgaard–Oeschger cycles. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
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Qi  Chongchong  Fourie  Andy  Du  Xuhao  Tang  Xiaolin 《Natural Hazards》2018,92(2):1179-1197
Natural Hazards - The prediction of open stope hangingwall (HW) stability is a crucial task for underground mines. In this paper, a relatively novel technique, the random forest (RF) algorithm, is...  相似文献   
17.
The Matt Wilson structure is a circular 5.5 km-diameter structure in Early Mesoproterozoic or Neoproterozoic rocks of the Victoria Basin, Northern Territory. It lies in regionally horizontal to gently dipping Wondoan Hill and Stubb Formations (Tijunna Group) and Jasper Gorge Sandstone (Auvergne Group). An outer circumferential syncline with dips of 5?–?40° in the limbs surrounds an intermediate zone with faulted sandstone displaying horizontal to low dips, and a central steeply dipping zone about 1.5 km across. Several thrust faults in the outer syncline appear to indicate outward-directed forces. The central zone, marked by steeply dipping to overturned Tijunna Group and possibly Bullita Group sandstone and mudstone, indicates uplift of at least 300 m. The rocks are intensely fractured with some brecciation, and contain numerous planar to subtly undulating surfaces displaying striae which resemble shatter cleavage. Thin-sections of sandstone from the central area show zones of intense microbrecciation and irregular and planar fractures in quartz, but no melt-rocks have been identified. The planar fractures occur in multiple intersecting parallel sets typical of relatively low-level (5?–?10 GPa) shock-pressure effects. Alternative mechanisms, i.e. igneous intrusion, carbonate collapse, diapirism and regional deformation processes, have been discounted. The circular nature, central uplift, faulting, shatter features and planar fractures are all consistent with an impact origin. The Matt Wilson structure is most likely a deeply eroded impact structure in which the more highly shocked rocks of the original crater floor have been removed by erosion. Estimates of the age of the Auvergne and Tijunna Groups range from Early Mesoproterozoic (which we favour) to Late Neoproterozoic. Early Cambrian Antrim Plateau Volcanics near the impact structure show no signs of impact effects, allowing the age of impact to be constrained between Early Mesoproterozoic and Early Cambrian. The presence of widespread soft-sediment deformation features, apparently confined to a single horizon in the Saddle Creek Formation some 700?–?1000 m stratigraphically higher in the Auvergne Group than the rocks at the impact site, and apparently increasing in thickness towards the Matt Wilson structure, lead us to speculate that this probable event horizon is related to the impact event: if correct the impact occurred during deposition of the Saddle Creek Formation.  相似文献   
18.
Future mineral exploration within eastern Australia will be enhanced by resolving the tectonic evolution of the Lachlan Orogen to establish the spatial and temporal terrane distribution of the various mineral deposits. The Lachlan Orogen, from north-eastern Tasmania through to central and eastern New South Wales, is host to a number of major mineral deposit styles—including orogenic gold (e.g. Stawell, Ballarat, Bendigo), volcanic-hosted massive sulphide (e.g. Woodlawn, Currawong), sediment-hosted Cu–Au (e.g. Cobar Basin deposits), porphyry Au–Cu (e.g. Cadia, Parkes, Cowal) and granite-related Sn (e.g. Ardlethan, Beechworth). Each of these mineral deposit styles is a sensitive and diagnostic indicator of the prevalent tectonic environment during their formation. In this review, we briefly summarise the deposit- to large-scale factors that define the diverse metallogenic evolution of the Lachlan Orogen. This overview is intended to “set the scene” for subsequent specialist papers published in this thematic issue on the metallogeny and tectonics of the Lachlan Orogen in south-east Australia.  相似文献   
19.
The dynamic response of tall civil structures due to earthquakes is very important to civil engineers. Structures exposed to earthquakes experience vibrations that are detrimental to their structural components. Structural pounding is an additional problem that occurs when buildings experience earthquake excitation. This phenomena occurs when adjacent structures collide from their out‐of‐phase vibrations. Many energy dissipation devices are presently being used to reduce the system response. Tuned mass dampers (TMD) are commonly used to improve the response of structures. The stiffness and damping properties of the TMD are designed to be a function of the natural frequency of the building to which it is connected. This research involves attaching adjacent structures with a shared tuned mass damper (STMD) to reduce both the structures vibration and probability of pounding. Because the STMD is connected to both buildings, the problem of tuning the STMD stiffness and damping parameters becomes an issue. A design procedure utilizing a performance function is used to obtain the STMD parameters to result in the best overall system response. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   
20.
 The structure of the cristobalite-like polymorph of phosphorus oxynitride PON has been refined using neutron powder diffraction data. It is tetragonal, space group I&4macr;2d, Z=4. The four P–(O,N) distances are equal but the tetrahedron is compressed along c. In AX2 or ABX4 compounds, the tetragonal I&4macr;2d or I&4macr; structure is obtained when the average ratio of the cation to anion radius is below 1.186, whereas the tetragonal P41212 or orthorhombic C2221 structure is obtained at low temperatures for larger ratios. The cell parameters of this PON polymorph have been determined as a function of hydrostatic pressure by in situ angle dispersive X-ray powder diffraction in a diamond-anvil cell. Under truly hydrostatic pressure, a strong anisotropic behavior is observed with the c parameter being nearly incompressible. Very slight anisotropic stress strongly modifies the high-pressure behavior. According to the pressure-temperature conditions of treatment, three phases, cristobalite-, moganite-, and quartz-like, have been obtained by quenching experiments, and the PT phase diagram of PON was derived. The high-pressure behavior of the α-quartz, moganite, and cristobalite-like polymorphs of PON and SiO2 is discussed. Received: 7 August 2000 / Accepted: 21 January 2001  相似文献   
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