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71.
Three Australian brown coals have been separated into humin and humic acid fractions and studied by high resolution solid state 13C NMR spectroscopy and Fourier transform IR spectroscopy. The aromatic rings of the humic acids are highly substituted showing that extensive cross linking must have occurred during formation from wood lignin and tannin. However, the humins contain more aliphatic carbon and hydrogen than the corresponding humic acids. This shows that little cross linking has occurred with other components of the brown coal such as resins, waxes cutin and algal detritus, and cross linking has not rendered the aromatics alkali insoluble. The kinetics of extraction are complex and not simple first order. This is reflected in the chemical composition of the humic acid which is extraction temperature dependent. We also observed that there is a conversion of aromatic carbon to aliphatic carbon and gas during extraction, probably by alkaline oxidation, resulting in ring opening. A range of suitable model compounds have been studied to confirm this finding. Such a mechanism may account for the modification of lignin in oxidising environments such as those occurring in the initial stages of coalification (lignite or brown coal formation) and in soils. 相似文献
72.
Six plastic/rubber materials commonly encountered in marine debris and beach litter were studied under Biscayne Bay (Florida, USA) exposure conditions to determine the effect of fouling on buoyancy. Studies under restricted floating, and restricted submerged exposure conditions suggest that most plastic samples undergo fouling to an extent to cause the sample to be negatively buoyant in sea water. Rapid defouling of the submerged fouled samples was observed. The findings suggest that free-floating plastics at sea may, under certain conditions, undergo fouling-induced sinking followed by resurfacing as floating debris. 相似文献
73.
A total of 269 tropical storms and hurricanes originated in the North Atlantic basin from 1960–1989. Of these, 76 made landfall on the continental United states. This study divides the 76 tropical storms into their month of formation. Seasonal shifts in the principal areas of tropical cyclone formation over the Atlantic basin have been recognized for many decades. The results of the study suggest that the early and late season tropical cyclones develop in areas which are first affected by the position of the sun, resulting in an increase in water temperatures. These cyclones normally make landfall along the Gulf Coast and usually are of low intensity. Formation areas shift eastward in mid-summer with a slight increase in intensity. By late August and early September, the formation areas have extended to the Cape Verde Islands. These storms tend to strike the east coast of the US and are normally more intense. By the end of the hurricane season, the primary formation area has shifted back to the Gulf of Mexico, with low intensity storms affecting the Gulf Coast. 相似文献
74.
75.
Industrial decentralisation (ID) has been a central component of South Africa's regional strategy for over twenty years. Until recently, though, the programme has evinced little interest amongst industrialists. The fact that ID policy has been premised upon political rather than economic considerations has been thought to lie at the root of this failure. Following recent developments, however, this view is being reassessed. The reorganisation of ID policy in 1982 and the dramatic acceleration in the rate of industrial relocations that this reorganisation appears to have induced, has led theorists to revise their thinking on both the economic and political imperatives underpinning the programme. The purpose of this paper is to review the debates that are now developing concerning ID in South Africa, and to suggest where further research and analysis might be most profitably directed. 相似文献
76.
A multi-span, curved, concrete box-girder bridge has been extensively instrumented by the California Strong Motion Instrumentation Program (CSMIP) in cooperation with the California Department of Transportation (Caltrans). On 28 June 1992, the bridge was shaken by the magnitude 7–5 Landers and magnitude 6–6 Big Bear earthquakes in southern California. The epicentres of these earthquakes were 50 and 29 miles (81 and 46 km) from the bridge, respectively. All 34 strong-motion sensors installed on the bridge recorded the response to these earthquakes and provided an insightful set of data. A striking aspect of the response is the presence of intermittent sharp spikes in nearly all of the acceleration records from sensors at the deck of the bridge. Among these the highest spike was 0.8g for the Landers and 1.0g for the Big Bear earthquake. The peak ground acceleration at the bridge site was only about 0.1g for both these earthquakes. With the aid of visual examination and simple analysis it is deduced that (1) the spikes were caused by forces generated at separation joints by impacts and stretching of the cable restrainers between adjacent bridge segments; (2) the forces of impacts and cable stretching are directly proportional to the size of the spikes and can be estimated by the use of a simple formula; and (3) the spikes travelled from their source to other locations on the bridge with the velocity of a compression wave propagating through concrete. 相似文献
77.
Regional Energy Demand Responses To Climate Change: Methodology And Application To The Commonwealth Of Massachusetts 总被引:1,自引:2,他引:1
Climate is a major determinant of energy demand. Changes in climate may alter energy demand as well as energy demand patterns.
This study investigates the implications of climate change for energy demand under the hypothesis that impacts are scale dependent
due to region-specific climatic variables, infrastructure, socioeconomic, and energy use profiles.
In this analysis we explore regional energy demand responses to climate change by assessing temperature-sensitive energy demand
in the Commonwealth of Massachusetts. The study employs a two-step estimation and modeling procedure. The first step evaluates
the historic temperature sensitivity of residential and commercial demand for electricity and heating fuels, using a degree-day
methodology. We find that when controlling for socioeconomic factors, degree-day variables have significant explanatory power
in describing historic changes in residential and commercial energy demands. In the second step, we assess potential future
energy demand responses to scenarios of climate change. Model results are based on alternative climate scenarios that were
specifically derived for the region on the basis of local climatological data, coupled with regional information from available
global climate models. We find notable changes with respect to overall energy consumption by, and energy mix of the residential
and commercial sectors in the region. On the basis of our findings, we identify several methodological issues relevant to
the development of climate change impact assessments of energy demand. 相似文献
78.
Keith D. Williams Catherine A. Senior Anthony Slingo John F. B. Mitchell 《Climate Dynamics》2005,24(7-8):701-719
Most of the discrepancies in the climate sensitivity of general circulation models (GCMs) are believed to be due to differences in cloud radiative feedback. Analysis of cloud response to climate change in different ‘regimes’ may offer a more detailed understanding of how the cloud response differs between GCMs. In which case, evaluation of simulated cloud regimes against observations in terms of both their cloud properties and frequency of occurrence will assist in assessing confidence in the cloud response to climate change in a particular GCM. In this study, we use a clustering technique on International Satellite Cloud Climatology Project (ISCCP) data and on ISCCP-like diagnostics from two versions of the Hadley Centre GCM to identify cloud regimes over four different geographical regions. The two versions of the model are evaluated against observational data and their cloud response to climate change compared within the cloud regime framework. It is found that cloud clusters produced by the more recent GCM, HadSM4, compare more favourably with observations than HadSM3. In response to climate change, although the net cloud response over particular regions is often different in the two models, in several instances the same basic processes may be seen to be operating. Overall, both changes in the frequency of occurrence of cloud regimes and changes in the properties (optical depth and cloud top height) of the cloud regimes contribute to the cloud response to climate change. 相似文献
79.
80.
Peter Doucette Peggy Agouris Anthony Stefanidis Mohamad Musavi 《ISPRS Journal of Photogrammetry and Remote Sensing》2001,55(5-6)
The extraction of road networks from digital imagery is a fundamental image analysis operation. Common problems encountered in automated road extraction include high sensitivity to typical scene clutter in high-resolution imagery, and inefficiency to meaningfully exploit multispectral imagery (MSI). With a ground sample distance (GSD) of less than 2 m per pixel, roads can be broadly described as elongated regions. We propose an approach of elongated region-based analysis for 2D road extraction from high-resolution imagery, which is suitable for MSI, and is insensitive to conventional edge definition. A self-organising road map (SORM) algorithm is presented, inspired from a specialised variation of Kohonen's self-organising map (SOM) neural network algorithm. A spectrally classified high-resolution image is assumed to be the input for our analysis. Our approach proceeds by performing spatial cluster analysis as a mid-level processing technique. This allows us to improve tolerance to road clutter in high-resolution images, and to minimise the effect on road extraction of common classification errors. This approach is designed in consideration of the emerging trend towards high-resolution multispectral sensors. Preliminary results demonstrate robust road extraction ability due to the non-local approach, when presented with noisy input. 相似文献