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61.
Abstract Three arrays of current‐meter moorings were deployed under landfast sea ice in southeast Hudson Bay for eight weeks in spring 1986. Spectral analysis shows low‐frequency signals with periods of 3 to 11 days. These signals are interpreted as being due to coastal‐trapped waves propagating cyclonically in Hudson Bay; their theoretical dispersion relations and corresponding modal structures are presented for winter stratification and are compared with observations. At a period of 3 days both the modified external Kelvin wave and higher mode continental shelf waves may be important in describing the observed low‐frequency variability, whereas at a period of 10 days the Kelvin wave appears to be the dominant mode. The generation mechanisms for these coastal trapped waves are also investigated. Two sources have been studied: the longshore atmospheric pressure gradient and the average atmospheric pressure over the ice cover in Hudson Bay. Coherence and phase analyses performed with time series of longshore current and atmospheric forcing data reveal that both the average atmospheric pressure and the longshore atmospheric pressure gradient are important in explaining the observed low‐frequency variability, without indicating which one is the most important. 相似文献
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63.
Michael Anthony Velbel 《Chemical Geology》1989,78(3-4):245-253
Recent studies of alkali-feldspar hydrolysis kinetics have shown that, in the near-neutral pH range, weathering rates in natural systems are up to three orders of magnitude slower than laboratory rates. It has been hypothesized that decelerated rates may result from lower thermodynamic affinities for the hydrolysis reaction in natural systems than in laboratory systems. However, the chemical affinities for the feldspar hydrolysis reaction in two well-constrained natural systems are significantly higher than the threshold value at which affinity would exert detectable influences on the reaction rates. Thus, the hypothesis is rejected, and closer proximity to thermodynamic equilibrium in natural weathering systems does not account for the observed discrepancy between natural and laboratory rates of feldspar hydrolysis. Differences in feldspar weathering rates between natural and laboratory systems are most likely due to a combination of experimental preparation artifacts, loss of reactive surface to the formation of etch pits in naturally weathered feldspars, and inhomogeneous access of reactive fluids to those surfaces. 相似文献
64.
Pyroclastic flow emplacement is strongly influenced by eruption column height. A surface along which kinetic energy is zero theoretically connects the loci of eruption column collapse with all coeval ignimbrite termini. This surface is reconstructed as a two-dimensional energy line for the 1912 Katmai pyroclastic flow in the Valley of Ten Thousand Smokes from mapped flow termini and the runup of the ignimbrite onto obstructions and through passes. Extrapolation of the energy line to the vicinity of the source vent at Novarupta suggests the eruption column which generated the ignimbrite eruption was approximately 425 m high. The 1912 pyroclastic flow travelled about 25 km downvalley. Empirical velocity data calculated from runup elevations and surveyed centrifugal superelevations indicate initial velocities near Novarupta were greater than 79–88 m s–1. The flow progressively decelerated and was travelling only 2–8 m s–1 when it crossed a moraine 16 km downvalley. The constant slope of the energy line away from Novarupta suggests the flow was systematically slowed by internal and basal friction. Using a simple physical model to calculate flow velocities and a constant kinetic friction coefficient (Heim coefficient) of 0.04 derived from the reconstructed energy line, the flow is estimated to have decelerated at an average rate of –0.16 m s–2 and to have taken approximately 9.5 minutes to travel 25 km down the Valley of Ten Thousand Smokes. The shear strength of the flowing ignimbrite at the moraine was approximately 0.5 kPa, and its Bingham viscosity when it crossed the moraine was 3.5 × 103
P. If the flow was Newtonian, its viscosity was 4.2 × 103
P. Reynolds and Froude numbers at the moraine were only 41–62 and 0.84–1.04, respectively, indicating laminar, subcritical flow. 相似文献
65.
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67.
Temperature and humidity flux-variance relations determined by one-dimensional eddy correlation 总被引:3,自引:1,他引:3
Harold L. Weaver 《Boundary-Layer Meteorology》1990,53(1-2):77-91
It may be possible to estimate surface fluxes of scalar quantities from measurement of their variance and mean wind speed. The flux-variance relation for temperature and humidity was investigated over prairie and desert-shrub plant communities. Fluxes were measured by one-dimensional eddy correlation, humidity by fast-response wet-bulb psychrometers and Krypton open-path hygrometers, temperature by fine-wire thermocouples, and mean windspeed by a cup anemometer. The quality of the flux-variance relation proved to be good enough for application to flux measurement. Regressions of flux estimated by the variance technique versus measured flux usually had r
2 values greater than 0.97 for sensible heat flux and greater than 0.88 for water vapor flux. More uniform surfaces tended to yield the same flux-variance relations except when fluxes were small. This exception supported the hypothesis that sparse sources of flux may increase variance downwind. Nonuniform surfaces yielded flux-variance relations that were less predictable, although reasonably accurate once determined. The flux-variance relation for humidity was quite variable over dry surfaces with senescent vegetation. 相似文献
68.
Three Australian brown coals have been separated into humin and humic acid fractions and studied by high resolution solid state 13C NMR spectroscopy and Fourier transform IR spectroscopy. The aromatic rings of the humic acids are highly substituted showing that extensive cross linking must have occurred during formation from wood lignin and tannin. However, the humins contain more aliphatic carbon and hydrogen than the corresponding humic acids. This shows that little cross linking has occurred with other components of the brown coal such as resins, waxes cutin and algal detritus, and cross linking has not rendered the aromatics alkali insoluble. The kinetics of extraction are complex and not simple first order. This is reflected in the chemical composition of the humic acid which is extraction temperature dependent. We also observed that there is a conversion of aromatic carbon to aliphatic carbon and gas during extraction, probably by alkaline oxidation, resulting in ring opening. A range of suitable model compounds have been studied to confirm this finding. Such a mechanism may account for the modification of lignin in oxidising environments such as those occurring in the initial stages of coalification (lignite or brown coal formation) and in soils. 相似文献
69.
The study examines the spatial relationships between sediment yield and 15 independent environmental variables in 54 catchments in South Africa. Rooseboom's (1978) data on the sediment yield from the catchments were standardized for a single time period. Bivariate regression analyses reveal no simple relationships. Multivariate regression analyses conducted for the whole and various sub-areas of South Africa indicate that latitude and longitude are the primary variables affecting spatial variations in sediment yield. This may be as a result of latitude and longitude being surrogate variables reflecting variation in other environmental variables (e. g. geology, vegetation). Within the sub-areas, 43.4% to 97.8% of the variation in sediment yield is explained by the combined variation in a number of different environmental variables. This study highlights a need for the collection and analysis of more sediment yield data, which would allow the analyses to be refined, to predict sediment yields from ungauged catchments in South Africa. 相似文献
70.
Six plastic/rubber materials commonly encountered in marine debris and beach litter were studied under Biscayne Bay (Florida, USA) exposure conditions to determine the effect of fouling on buoyancy. Studies under restricted floating, and restricted submerged exposure conditions suggest that most plastic samples undergo fouling to an extent to cause the sample to be negatively buoyant in sea water. Rapid defouling of the submerged fouled samples was observed. The findings suggest that free-floating plastics at sea may, under certain conditions, undergo fouling-induced sinking followed by resurfacing as floating debris. 相似文献