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Ejecta at North Ray crater (Apollo 16) sampled a unique section of the lunar highlands not accessible at most other landing sites and provide important constraints on the composition of late accreted materials. New data on multiple aliquots of four fragmental matrix breccias and a fragment‐laden melt breccia from this site display a variety of highly siderophile element patterns which may represent the signatures of volatile element‐depleted carbonaceous chondrite‐like material, primitive achondrite, differentiated metal, and an impactor component that cannot be related to known meteoritic material. The latter component is prevalent in these rocks besides characterized by depletions in Re and Os compared to Ir, Ru and Pt, chondritic Re/Os, and a gradual depletion of Pd and Au. The observed characteristics are more consistent with fractionations by nebular processes, like incomplete condensation or evaporation, than with lunar crustal processes, like partial melting or volatilization. The impactor signature preserved in these breccias may stem from primitive meteorites with a refractory element composition moderately different from known chondrites. The presence of distinct impactor components within the North Ray crater breccias together with observed correlations of characteristic element ratios (e.g., Re/Os, Ru/Pt, Pd/Ir) in different impact lithologies of four Apollo landing sites constrains physical mixing processes ranging from the scale of gram‐sized samples to the area covered by the Apollo missions.  相似文献   
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The composition of ice‐rafted debris (IRD) within a sediment core from the European continental slope (core OMEX‐2K; 49° 5′ N, 13° 26′ W) has been examined using environmental magnetic analyses. The data demonstrate compositional variability of the IRD within Heinrich layers 2 (H2) and 1 (H1) and these differences are most readily explained by changes in the contribution of different IRD sources to the core site. Some IRD within the main Heinrich layers show magnetic signatures that are similar to IRD derived from the Laurentide ice sheet found in cores from within the main North Atlantic IRD‐belt. In contrast, other IRD‐rich layers, both prior to and within the main Heinrich layers, demonstrate different magnetic behaviour, suggesting a contribution from a non‐Laurentide sourced IRD, most likely derived from ice streams discharging from northeast Atlantic ice sheets such as the British and Fennoscandian ice sheets. These data are consistent with published compositional data from the same core and, given the rapid, highly sensitive and non‐destructive nature of the method, suggest that environmental magnetic analysis has considerable potential for characterising IRD materials within Heinrich layers for the purposes of defining provenance. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   
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In the Basle region of Switzerland we demonstrate that rockfall blocks can be dated accurately using the radiocarbon method. Soil beneath rockfall blocks containing organic macro‐remains was sampled at four cliff sites in the Tabular Jura south‐east of Basle. A lightweight drilling rig drills a 101‐mm‐diameter hole through rockfall blocks up to 6 m in height. A downhole sampler is used to recover soil samples from below the blocks. Eighteen radiocarbon dates on charcoal, wood, needles of conifers and organic macro‐remains from 11 blocks gave dates between 970 and 440 bp . Calibrated ages range between ad 1210 and ad 1450. These results, along with field observations and historical research, suggest that a large number of blocks toppled as rockfalls within a short time interval in the epicentral area of the ad 1356 Basle earthquake.  相似文献   
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The kinetics of (Mg, Fe)SiO3 pyroxene layer growth within silicate thin films with total thickness <1 μm was studied experimentally at 0.1 MPa total pressure, controlled fO2 and temperatures from 1,000 to 1,300°C. The starting samples were produced by pulsed laser deposition. Layer thickness before and after the experiments and layer composition as well as microstructures, grain size and shape of the interfaces were determined by Rutherford back scattering and transmission electron microscopy assisted by focused ion beam milling. Due to the miniaturization of the starting samples and the use of high resolution analytical methods the experimentally accessible temperature range for rim growth experiments was extended by about 300°C towards lower temperatures. The thickness of the layers at a given temperature increases proprotional to the square root of time, indicating a diffusion-controlled growth mechanism. The temperature dependence of rim growth yields an apparent activation energy of 426 ± 34 kJ/mol. The small grain size in the orthopyroxene rims implies a significant contribution of grain boundary diffusion to the bulk diffusion properties of the polycrystalline rims. Based on microstructural observations diffusion scenarios are discussed for which the SiO2 component behaves immobile relative to the MgO component. Volume diffusion data for Mg in orthopyroxene from the literature indicate that the measured diffusivity is probably controlled by the mobility of oxygen. The observed reaction rates are consistent with earlier results from dry high-temperature experiments on orthopyroxene rim growth. Compared to high pressure experiments at 1,000°C and low water fugacities, reaction rates are 3–4 orders of magnitude smaller. This observation is taken as direct evidence for a strong effect of small amounts of water on diffusion in silicate polycrystals. In particular SiO2 changes from an immobile component at dry conditions to an extremely mobile component even at very low water fugacities.  相似文献   
139.
The position of the Raman methane (CH4) symmetric stretching band (ν1) over the range 1-650 bar and 0.3-22 °C has been determined using a high-pressure optical cell mounted on a Raman microprobe. Two neon emission lines that closely bracket the CH4 band were collected simultaneously with each CH4 spectrum. The peak position was determined after least squares fitting using a summed Gaussian-Lorentzian method, resulting in a precision of ≈±0.02 cm−1 in peak position determination. The CH4ν1 band position shifts to lower wave number with increasing pressure. At a given pressure, the band shifts to lower wave number with decreasing temperature, and the magnitude of the temperature shift increases with increasing pressure. The relationship between the Raman CH4ν1 band position and temperature and pressure determined here may be used to estimate the internal pressure in natural or synthetic CH4-bearing fluid inclusions. This information, in turn, may be used to determine the density of pure CH4 fluid inclusions and the salinity of CH4-bearing aqueous inclusions.  相似文献   
140.
In acoustic tomographic system capable of performing in situ two-dimensional (2D) acoustic imaging of shallow water sediments is described. This system is capable of resolving inhomogeneities greater than 10 cm and differentiating sound-speed variations greater than 2%, A tomographic inversion is performed in a 2D vertical slice of about 1 m 2 (1 m×1 m) using three identical probes, with each consisting of 70 evenly distributed transducers. In normal deployments, two of the probes are oriented vertically and are separated by about 1 meter, and the third is positioned horizontally right above the two vertical probes. The additional horizontal probe greatly improves the horizontal resolution of the system compared to conventional crosshole tomographic setups. Numerical simulations are performed to evaluate the influences of arrival time detection error and transducer position error on the performance of the tomography system. For an arrival time of 500 ns (standard deviation) and a position error of 4 mm (standard deviation), sound-speed anomalies of greater than 0.8% can be correctly predicted near the upper portion (close to the horizontal probe) and are resolvable near the lower portion. A controlled laboratory experiment was conducted to evaluate the performance of the system. The location of a polyurethane block (Conap EN22) used as a known target is correctly predicted while the inverted sound speed is about 9% lower than that from its actual value. Field data taken from a saturated muddy site are presented and analyzed. The inverted mean sound speed and attenuation are about 1480 ms-1 and 20 dBm-1, respectively  相似文献   
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