Provenance of Oligocene synorogenic sediments of the Ligurian Alps (NW Italy): inferences on belt age and cooling history     

Chiara?Barbieri  Barbara?Carrapa  Andrea?Di GiulioEmail author  Jan?Wijbrans  Glen?R.?Murrell 《International Journal of Earth Sciences》2003,92(5):758-778

Mineral chemistry, ⁴⁰Ar/³⁹Ar geochronology on white micas and Apatite Fission Track Thermochronology (AFTT), are applied here to study the provenance of the synorogenic Molare Formation (lowermost unit of the Tertiary Piedmont Basin clastic sequence). The Molare Formation was deposited during transgression onto the Ligurian Alps nappe stack in the Early Oligocene. Depositional facies show that clastic distribution remained transversal, with local sources located just landward from the coastline. Phengite mineral chemistry together with ⁴⁰Ar/³⁹Ar data clearly shows two distinctive source areas, each one mirroring the composition of the basement directly beneath the clastic sequence. Amphibole mineral chemistry allows second order provenance distinctions within each sector, reflecting heterogeneous metamorphic evolution of the bedrock complexes. Integrated ⁴⁰Ar/³⁹Ar dating and AFTT suggest that, following a fast cooling/exhumation episode of the Ligurian Alps during the Oligocene, very little net uplift has since occurred. This is due to a period of general subsidence from the Oligocene–Late Miocene followed by comparable uplift from Late Miocene–Pliocene to the present. In general our data provide an image of the Ligurian Alps during the Oligocene, which is very similar to the present-day one.This revised version was published online in September 2003.  相似文献   

Ecological condition of US Mid-Atlantic estuaries, 1997-1998     

Kiddon JA  Paul JF  Buffum HW  Strobel CS  Hale SS  Cobb D  Brown BS 《Marine pollution bulletin》2003,46(10):1224-1244

The Mid-Atlantic Integrated Assessment (MAIA-Estuaries) evaluated ecological conditions in US Mid-Atlantic estuaries during the summers of 1997 and 1998. Over 800 probability-based stations were monitored in four main estuarine systems--Chesapeake Bay, the Delaware Estuary, Maryland and Virginian coastal bays, and the Albemarle-Pamlico Estuarine System. Twelve smaller estuaries within the four main systems were also assessed to establish variance at the local scale. A subset of the MAIA-Estuaries data is used here to estimate the extent of eutrophication, sediment contamination, and benthic degradation in mid-Atlantic estuaries. An Environmental Report Card and Index of Environmental Integrity summarize conditions in individual estuaries, the four estuarine systems, and the entire MAIA region. Roughly 20-50% of the region showed signs of eutrophication (high nutrients, excessive production of organic matter, poor water clarity, or depleted dissolved oxygen), 30% had contaminated sediments, and 37% had degraded benthic communities. Compared with the Environmental Monitoring and Assessment Program (EMAP)-Virginian Province study in 1990-1993, larger fractions of Chesapeake Bay (17%) and Delaware River (32%) had increased metals or organics in sediments.  相似文献   

Aquatic Sciences – Research Across Boundaries is an online first journal!     

Barbara Sulzberger 《Aquatic Sciences - Research Across Boundaries》2005,67(1):i-i

  相似文献   

Time constraints for Mesoproterozoic upper amphibolite facies metamorphism in NW Namibia: a multi-isotopic approach     

Barbara Seth  Richard A. Armstrong  Annett Büttner  Igor M. Villa   《Earth and Planetary Science Letters》2005,230(3-4):355-378

This study presents the chronological evolution of the upper amphibolite facies Orue Unit in NW Namibia. Metasedimentary and meta-igneous rocks of the Orue Unit were investigated using the Pb–Pb stepwise leaching technique on garnet and rutile, U–Pb multi-grain analysis on rutile, Sm–Nd–Lu–Hf leaching technique on garnet, SHRIMP analysis on zircon and Ar–Ar dating on amphibole. Each of these techniques pertains to different processes that occurred before, during, or after the metamorphic peak. Our age data can be integrated with petrological constraints to provide a more complete understanding of the metamorphic cycle. Our pre-peak metamorphic zircon ages, peak metamorphic garnet ages and peak to late peak metamorphic amphibole ³⁹Ar–⁴⁰Ar ages bracket the upper amphibolite facies metamorphic event including hydration or dehydration processes into a time span of only ca. 20 Ma. The age data obtained by peak metamorphic mineral analyses cluster around 1340–1320 Ma. Based on age data and field observation, we interpret the upper amphibolite facies metamorphism as a large-scale regional mid-crustal event. Spot analyses of inherited zircon cores obtained by SHRIMP reflect the sedimentary origin of the respective rocks of the Orue Unit and derivation from Palaeoproterozoic protoliths. The metamorphic rocks south of the anorthositic Kunene Intrusive Complex (KIC) have previously been ascribed to the Palaeoproterozoic Epupa Complex at the SW margin of the Congo craton and were thus thought to be older than the Mesoproterozoic KIC. Our data show that the high-grade metamorphic overprint took place 30–50 Ma after emplacement of the KIC. Rutile growth ages of 1248 Ma in one sample reflect fluid activity which seems to be a local phenomenon since there is no other evidence of geological activity throughout the Orue Unit at that time. The rutile ages predate the emplacement of satellite intrusions in that area by 30 Ma and there is no causal relation between these two events.  相似文献   

Benthic diatoms of an Alpine stream/lake network in Switzerland   总被引：1，自引：0，他引：1  

Christopher T. Robinson  Barbara Kawecka 《Aquatic Sciences - Research Across Boundaries》2005,67(4):492-506

We compared the benthic diatom composition of lakes, and lake inlet and outlet streams in a high elevation catchment (∼2600 m a.s.l.) in the Swiss Alps. The catchment consisted of a southern basin mostly fed by glacial-melt water and a northern basin fed by snowmelt and groundwater. Streams in both basins flowed through a series of small lakes before converging into a lake with a primary outlet channel. The south basin had on average 4°C cooler water temperatures and 2× higher nitrate-N levels (up to 300 μg/L) than the north basin. In contrast, the north basin had higher levels (2–4×) of particulate-P, particulate-N, and particulate organic matter than the south basin. A total of 109 and 143 diatom species was identified in lakes and streams, respectively, with a similar number of species found in each basin. Aulacoseira alpigena and Achnanthidium minutissimum were common benthic algae in north basin lakes, whereas Achnanthes subatomoides, Achnanthes marginulata, Pinnularia microstauron, and Psammothidium helveticum were most common in south basin lakes. One disconnected lake in the north basin had an assemblage dominated by Tabellaria flocculosa (66%) and Eunotia tenella (14%). Principal components analysis showed a clear separation between the north and south basins in lotic diatoms. Of the 10 most common species, streams in the south basin had greater abundances of Psammothidium helveticum, Achnanthes helvetica var. minor, Achnanthes marginulata, Achnanthes subatomoides, and Diatoma mesodon than the north basin, whereas north basin streams had higher abundances of Achnanthidium minutissimum, Aulacoseira alpigena, and Luticola goeppertiana. Lake outlet assemblages were similar to respective downstream lake inlet assemblages, and assemblages changed in composition along each basins longitudinal flow path. However, Aulacoseira alpigena had higher average abundances in north basin outlets than inlets, and Achnanthidium minutissimum, Psammothidium helveticum, and Achnanthes helvetica var. minor had higher average abundances in south basin outlets than inlets. In contrast, Diatoma mesodon, Fragilaria capucina, and Gomphonema parvulum had higher average abundances in south basin inlets than outlets. The spatial patterns in species composition reflected the hierarchical interaction of landscape features (geology, hydrology) on longitudinal gradients (lake position) in the stream/lake network.  相似文献   

Wal-Mart and Aldi: Two Retail Giants in Germany     

Ulrike Gerhard  Barbara Hahn 《GeoJournal》2005,62(1):15-26

Wal-Mart entered the German market at the end of 1997 but is still running at a loss in its 92 stores. This article tests the hypothesis that there are two main reasons for Wal-Mart’s problems in Germany. First of all, Wal-Mart is competing against very strong and well established deep discounters, especially Aldi. Secondly, there is the difference between the so-called Wal-Mart culture and German customer values. So far, Wal-Mart has not managed to close this gap or create a positive image in Germany. The first part of the article describes the differences between the two retail companies Wal-Mart and Aldi, whereas the second part focuses on the consumer perspective. Four hundred people were interviewed on the phone about their shopping behaviour in the city of Würzburg (northern Bavaria, 140,000 inhabitants). This survey is part of an international study also undertaken in Canada, Great Britain and China.  相似文献   

Calcium isotope fractionation in calcite and aragonite   总被引：1，自引：0，他引：1  

Nikolaus Gussone  Florian Böhm  Martin Dietzel  Barbara M.A. Teichert  Gert Wörheide 《Geochimica et cosmochimica acta》2005,69(18):4485-4494

Calcium isotope fractionation was measured on skeletal aragonite and calcite from different marine biota and on inorganic calcite. Precipitation temperatures ranged from 0 to 28°C. Calcium isotope fractionation shows a temperature dependence in accordance with previous observations: 1000 · ln(α_cc) = −1.4 + 0.021 · T (°C) for calcite and 1000 · ln(α_ar) = −1.9 + 0.017 · T (°C) for aragonite. Within uncertainty the temperature slopes are identical for the two polymorphs. However, at all temperatures calcium isotopes are more fractionated in aragonite than in calcite. The offset in δ^44/40Ca is about 0.6‰. The underlying mechanism for this offset may be related to the different coordination numbers and bond strengths of the calcium ions in calcite and aragonite crystals, or to different Ca reaction behavior at the solid-liquid interface. Recently, the observed temperature dependence of the Ca isotope fractionation was explained quantitatively by the temperature control on precipitation rates of calcium carbonates in an experimental setting (Lemarchand et al., 2004). We show that this mechanism can in principle also be applied to CaCO₃ precipitation in natural environments in normal marine settings. Following this model, Ca isotope fractionation in marine Ca carbonates is primarily controlled by precipitation rates. On the other hand the larger Ca isotope fractionation of aragonite compared to calcite can not be explained by different precipitation rates. The rate control model of Ca isotope fractionation predicts a strong dependence of the Ca isotopic composition of carbonates on ambient CO₃²⁻ concentration. While this model is in general accordance with our observations in marine carbonates, cultured specimens of the planktic foraminifer Orbulina universa show no dependence of Ca-isotope fractionation on the ambient CO₃²⁻ concentration. The latter observation implies that the carbonate chemistry in the calcifying vesicles of the foraminifer is independent from the ambient carbonate ion concentration of the surrounding water.  相似文献   

Late Glacial and Holocene Palaeoenvironmental Changes in the Rostov-Yaroslavl’ Area, West Central Russia     

Barbara Wohlfarth  Pavel Tarasov  Ole Bennike  Terri Lacourse  Dmitry Subetto  Peter Torssander  Fedor Romanenko 《Journal of Paleolimnology》2006,35(3):543-569

Three lake sediment sequences (lakes Nero, Chashnitsy, Zaozer’e) from the Rostov-Jaroslavl’ region north of Moscow were studied to provide information on palaeoclimatic and palaeoenvironmental changes during the past 15,000 cal yr. The multi-proxy study (i.e., pollen, macrofossils, mineral magnetic measurements, total carbon, nitrogen and sulphur) is chronologically constrained by AMS ¹⁴C measurements. Lake Nero provided the longest sedimentary record back to ca. 15,000 cal yr BP, while sediment accumulation began around ca. 11,000 cal yr BP in the two other lakes, possibly due to melting of permafrost. Limnic plant macrofossil remains suggest increased lake productivity and higher mean summer temperatures after 14,500 cal yr BP. While the late glacial vegetation was dominated by Betula and Salix shrubs and various herbs, it appears that Betula sect. Albae became established as early as 14,000 cal yr BP. Major hydrological changes in the region led to distinctly lower lake levels, starting 13,000 cal yr BP in Lake Nero and ca. 9000 cal yr BP in lakes Chashnitsy and Zaozer’e, which are situated at higher elevations. These changes resulted in sedimentary hiatuses in all three lakes that lasted 3500–4500 cal yr. Mixed broad-leaved – coniferous forests were widespread in the area between 8200 and 6100 cal yr BP and developed into dense, species-rich forests between 6100 and 2500 cal yr BP, during what was likely the warmest interval of the studied sequences. Agricultural activity is documented since 500 cal yr BP, but probably began earlier, since Rostov was a major capital by 862 A.D. This apparent gap may be caused by additional sedimentary hiatuses around 2500 and 500 cal yr BP.  相似文献   

A three-dimensional radially anisotropic model of shear velocity in the whole mantle   总被引：4，自引：0，他引：4  

Mark Panning  Barbara Romanowicz 《Geophysical Journal International》2006,167(1):361-379

We present a 3-D radially anisotropic S velocity model of the whole mantle (SAW642AN), obtained using a large three component surface and body waveform data set and an iterative inversion for structure and source parameters based on Non-linear Asymptotic Coupling Theory (NACT). The model is parametrized in level 4 spherical splines, which have a spacing of ∼ 8°. The model shows a link between mantle flow and anisotropy in a variety of depth ranges. In the uppermost mantle, we confirm observations of regions with   V_SH > V_SV   starting at ∼80 km under oceanic regions and ∼200 km under stable continental lithosphere, suggesting horizontal flow beneath the lithosphere. We also observe a   V_SV > V_SH   signature at ∼150–300 km depth beneath major ridge systems with amplitude correlated with spreading rate for fast-spreading segments. In the transition zone (400–700 km depth), regions of subducted slab material are associated with   V_SV > V_SH   , while the ridge signal decreases. While the mid-mantle has lower amplitude anisotropy (<1 per cent), we also confirm the observation of radially symmetric   V_SH > V_SV   in the lowermost 300 km, which appears to be a robust conclusion, despite an error in our previous paper which has been corrected here. The 3-D deviations from this signature are associated with the large-scale low-velocity superplumes under the central Pacific and Africa, suggesting that   V_SH > V_SV   is generated in the predominant horizontal flow of a mechanical boundary layer, with a change in signature related to transition to upwelling at the superplumes.  相似文献   

Sulphate Sources in the Sava and Ljubljanica Rivers, Slovenia, Inferred from Sulphur and Oxygen Isotope Compositions     

Barbara Vokal-Nemec  Janina Szaran  Andrzej Trembaczowski  Stanislaw Halas  Tadej Dolenec  Sonja Lojen 《Aquatic Geochemistry》2006,12(3):199-220

Measurements were made of sulphur and oxygen isotope ratios of sulphate in some Slovenian rivers, lakes and tap waters. δ³⁴S ranged from −0.2 to + 13.3‰, δ¹⁸O ranged from +4.9 to + 13.6‰, and the sulphate content varied from 0.8 to 41.4 mg/L. Rivers flowing from the Julian Alps contain a very low amount of sulphate that is leached from a thin horizon of soil by rain. As confirmed by their low δ¹⁸O values, these sulphates do not enter the rivers directly in rain, but arise from biochemical cycling in the soil. The low δ³⁴S of this sulphate indicates that it originates from the oxidation of sedimentary sulphides. The evolution of sulphates along the river course was investigated for the Sava and Ljubljanica rivers. The variations observed in sulphate from the waters studied result from variations in the contribution of sulphates of different origin. Downstream the Sava River sulphate is depleted in the heavy isotopes of both sulphur and oxygen, with δ-values gradually tending toward the δ-values of groundwater sulphates in the watershed. In contrast, the δ-values of sulphate in the Ljubljanica River are almost constant and similar to those of sulphate in local groundwater. Introduction of water from Italian and Slovenian mines was recorded in the Soča River, where the lowest δ³⁴S value of sulphate sulphur (−0.2‰) was observed. In addition, the influence of sulphate from the oxidation of sedimentary sulphides was recorded in the Sotla River. No evidence was found for introduction of sulphate from factories.  相似文献