Development and Re‐Evaluation of Tourmaline Reference Materials for In Situ Measurement of Boron δ Values by Secondary Ion Mass Spectrometry     

Katharina Marger  Matthieu Harlaux  Andrea Rielli  Lukas P. Baumgartner  Andrea Dini  Barbara L. Dutrow  Anne‐Sophie Bouvier 《Geostandards and Geoanalytical Research》2020,44(3):593-615

Six tourmaline samples were investigated as potential reference materials (RMs) for boron isotope measurement by secondary ion mass spectrometry (SIMS). The tourmaline samples are chemically homogeneous and cover a compositional range of tourmaline supergroup minerals (primarily Fe, Mg and Li end‐members). Additionally, they have homogeneous boron delta values with intermediate precision values during SIMS analyses of less than 0.6‰ (2s). These samples were compared with four established tourmaline RMs, that is, schorl IAEA‐B‐4 and three Harvard tourmalines (schorl HS#112566, dravite HS#108796 and elbaite HS#98144). They were re‐evaluated for their major element and boron delta values using the same measurement procedure as the new tourmaline samples investigated. A discrepancy of about 1.5‰ in δ¹¹B was found between the previously published reference values for established RMs and the values determined in this study. Significant instrumental mass fractionation (IMF) of up to 8‰ in δ¹¹B was observed for schorl–dravite–elbaite solid solutions during SIMS analysis. Using the new reference values determined in this study, the IMF of the ten tourmaline samples can be modelled by a linear combination of the chemical parameters FeO + MnO, SiO₂ and F. The new tourmaline RMs, together with the four established RMs, extend the boron isotope analysis of tourmaline towards the Mg‐ and Al‐rich compositional range. Consequently, the in situ boron isotope ratio of many natural tourmalines can now be determined with an uncertainty of less than 0.8‰ (2s).  相似文献   

How ready is ready? Measuring physical preparedness for severe storms     

Ryan  Barbara  King  Rachel 《Natural Hazards》2020,104(1):171-199

This paper investigates use of inventories, or checklists of activities, as an emergency management tool to motivate preparedness action in individuals. It develops the inventory concept to provide the foundation for a more targeted approach to storm preparation communication and community engagement. It also examines the potential efficacy of alternatives to paper-based checklists, such as web or smartphone applications. Academic and grey literature was reviewed to collect activities for a storm inventory for emergency agencies to measure individual preparedness and for individuals to measure their preparation progress. The resulting master list was refined for application and tested for useability in a pilot study of semi-structured interviews in a storm-susceptible community in Queensland, Australia. Also, clustering items by type of preparedness activity reveal where strengths and weaknesses exist in individual preparedness. For instance, preparation for leaving and safety planning were shown to be the areas of weakest activity in the pilot sample, while preparation of the house for a storm was the strongest area. In addition, behaviour change literature shows potential for effective use of an inventory-based smartphone application in motivating preparation activity. Data collected by a storm preparedness smartphone application could show where a communication or engagement program for targeted communities should be focused. It is supported by health literature that identifies preferences of individuals to make progress on complex tasks in stages, the value of lists to achievement of goals and demonstrated increase in uptake of activities prompted by smartphone applications over web or paper-based diaries.

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Higher-mode force response in multi-story strongback-braced frames     

Barbara G. Simpson Ph.D. 《地震工程与结构动力学》2020,49(14):1406-1427

Strongback-braced frames employ an essentially elastic steel truss, or strongback, that distributes demands more uniformly to delay or prevent story mechanisms. Because inertial forces are no longer limited by the formation of a story mechanism, strongback-braced frames can exhibit large elastic force demands, particularly in the higher modes. This paper characterizes the higher-mode force response of strongback-braced frames. Four-story archetypes were designed using nonlinear dynamic analyses to incorporate higher-mode force demands into the design process. The response of the archetypes was compared with that of reference buckling-restrained braced frames that were allowed to form story mechanisms. The force demands in the strongback were then described using equivalent-static forces to represent the inertial forces induced by the higher modes. Force demands in the strongback arise from a yielding first-mode ‘pivoting’ and elastic higher-mode ‘bending’ response. These higher-mode force demands are elastic, ill-constrained by the strength of the yield mechanism, and depend significantly on the choice of ground motion record used for the analysis. In remaining elastic in the higher modes, the strongback distributes demands more uniformly and mitigates the formation of story mechanisms. Consequently, design and analysis methods for strongback-braced frames need to include estimates for these near-elastic higher-mode force demands.  相似文献   

Using qPCR Assays to Predict Rates of Cometabolism of TCE in Aerobic Groundwater     

John T. Wilson  James C. Mills IV  Barbara H. Wilson  Mark L. Ferrey  David L. Freedman  Dora Taggart 《Ground Water Monitoring & Remediation》2019,39(2):53-63

Monitored natural attenuation (MNA) is commonly used as a remedy for trichloroethene (TCE) in anaerobic groundwater; however, MNA has not been applied to TCE contamination in aerobic groundwater. Under aerobic conditions, bacteria initiate the degradation of many organic substances with oxygenase enzymes. Several of these enzymes are known to degrade TCE through a fortuitous reaction known as cometabolism. There are commercially available qPCR assays that can determine the number of gene copies of these enzymes. If the qPCR assay could be used to predict the first-order rate constant for cometabolism of TCE, the qPCR assay could be used to screen sites to determine whether MNA was a plausible remedy for TCE contamination. This study reevaluated data from water samples that were collected from 19 wells on five sites in Minnesota, New York, and Utah. Data had previously been published on the rate constant for cometabolism of TCE in the water samples as determined by a ¹⁴C-assay and the abundance of gene copies for five enzymes that cometabolize TCE as determined using a qPCR assay. The Michaelis-Menten (Haldane) kinetic parameters for cometabolism of TCE and the abundance of DNA for the five oxygenase enzymes were used to predict the rate constant for cometabolism of TCE. The predicted rate constants were evaluated and validated by comparing them to the rate constants derived from the ¹⁴C-assay. For predicted rate constants greater than 0.003 per year, the predicted rate constants agreed with the measured rate constants within a factor of three. The qPCR assay serves as a convenient screening tool to determine whether MNA is a plausible remedy for an aerobic plume of TCE.  相似文献   

Are real-world shallow landslides reproducible by physically-based models? Four test cases in the Laternser valley,Vorarlberg (Austria)     

Thomas Zieher  Barbara Schneider-Muntau  Martin Mergili 《Landslides》2017,14(6):2009-2023

In contrast to the complex nature of slope failures, physically-based slope stability models rely on simplified representations of landslide geometry. Depending on the modelling approach, landslide geometry is reduced to a slope-parallel layer of infinite length and width (e.g., the infinite slope stability model), a concatenation of rigid bodies (e.g., Janbu’s model), or a 3D representation of the slope failure (e.g., Hovland’s model). In this paper, the applicability of four slope stability models is tested at four shallow landslide sites where information on soil material and landslide geometry is available. Soil samples were collected in the field for conducting respective laboratory tests. Landslide geometry was extracted from pre- and post-event digital terrain models derived from airborne laser scanning. Results for fully saturated conditions suggest that a more complex representation of landslide geometry leads to increasingly stable conditions as predicted by the respective models. Using the maximum landslide depth and the median slope angle of the sliding surfaces, the infinite slope stability model correctly predicts slope failures for all test sites. Applying a 2D model for the slope failures, only two test sites are predicted to fail while the two other remain stable. Based on 3D models, none of the slope failures are predicted correctly. The differing results may be explained by the stabilizing effects of cohesion in shallower parts of the landslides. These parts are better represented in models which include a more detailed landslide geometry. Hence, comparing the results of the applied models, the infinite slope stability model generally yields a lower factor of safety due to the overestimation of landslide depth and volume. This simple approach is considered feasible for computing a regional overview of slope stability. For the local scale, more detailed studies including comprehensive material sampling and testing as well as regolith depth measurements are necessary.  相似文献   

Impact of rock-water interactions and recharge on water resources quality of the Agadir-Essaouira basin,southwestern Morocco     

Al Yacoubi Latifa  Bouchaou Lhoussaine  Jaillard Etienne  Masrour Moussa  Ait Brahim Yassine  El Mouden Ahmed  Schneider Jana  Reichert Barbara 《Arabian Journal of Geosciences》2017,10(7):169

The Agadir-Essaouira area in the occidental High Atlas Mountains of Morocco is characterized by a semi-arid climate. The scarcity and quality of water resources, exacerbated by long drought periods, constitute a major problem for a sustainable development of this region. Groundwater resources of carbonate units within Jurassic and Cretaceous aquifers are requested for drinking and irrigation purposes. In this study, we collected 84 samples from wells, boreholes, springs, and rivers. Hydrochemical and isotopic data were used to examine the mineralization and origin of water, which control groundwater quality. The chemical composition of water seems to be controlled by water-rock interactions, such as dissolution of carbonates (calcite and dolomite), weathering of gypsum, as well as ion exchange processes, which explain the observed variability. Stable isotopes results show that groundwater from the mainly marly Cretaceous aquifer are submitted to an evaporation effect, while samples from the chiefly calcareous Jurassic aquifer indicate a meteoric origin, due to a rapid infiltration of recharge runoff through the karstic outcrops. The low values of δ¹⁸O and δ²H suggest a local recharge from areas with elevations ranging from 400 to 1200 m for the Cretaceous aquifer and from 800 to 1500 m for the Jurassic units.  相似文献   

A Snapshot of the Sun Near Solar Minimum: The Whole Heliosphere Interval     

Barbara J. Thompson  Sarah E. Gibson  Peter C. Schroeder  David F. Webb  Charles N. Arge  Mario M. Bisi  Giuliana de Toma  Barbara A. Emery  Antoinette B. Galvin  Deborah A. Haber  Bernard V. Jackson  Elizabeth A. Jensen  Robert J. Leamon  Jiuhou Lei  Periasamy K. Manoharan  M. Leila Mays  Patrick S. McIntosh  Gordon J. D. Petrie  Simon P. Plunkett  Liying Qian  Peter Riley  Steven T. Suess  Munetoshi Tokumaru  Brian T. Welsch  Thomas N. Woods 《Solar physics》2011,274(1-2):29-56

We present an overview of the data and models collected for the Whole Heliosphere Interval, an international campaign to study the three-dimensional solar?Cheliospheric?Cplanetary connected system near solar minimum. The data and models correspond to solar Carrington Rotation 2068 (20 March??C?16 April 2008) extending from below the solar photosphere, through interplanetary space, and down to Earth??s mesosphere. Nearly 200 people participated in aspects of WHI studies, analyzing and interpreting data from nearly 100 instruments and models in order to elucidate the physics of fundamental heliophysical processes. The solar and inner heliospheric data showed structure consistent with the declining phase of the solar cycle. A closely spaced cluster of low-latitude active regions was responsible for an increased level of magnetic activity, while a highly warped current sheet dominated heliospheric structure. The geospace data revealed an unusually high level of activity, driven primarily by the periodic impingement of high-speed streams. The WHI studies traced the solar activity and structure into the heliosphere and geospace, and provided new insight into the nature of the interconnected heliophysical system near solar minimum.  相似文献   

Limnology of Bird Pond,Ross Island,Antarctica     

Barbara Spurr 《新西兰海洋与淡水研究杂志》2013,47(4):547-562

The physical, chemical and biological properties of Bird Pond, Cape Bird, Ross Island, Antarctica (77° 13’ 10” S, 166° 28’ 30” E), were investigated at weekly intervals for 2 months in the summer of 1970–71. The above properties were also investigated over a 24‐h period. Salinity and temperature tolerance of the rotifer Philodina gregaria were investigated in the laboratory at Cape Bird.

Bird Pond is characterised by a high conductivity and chloride ion concentration, and an alkaline pH. It has a water temperature as high as 15°c in mid summer, with the bottom water temperature often 3°c higher than the surface temperature. Diurnal measurements suggest a vertical movement of phytoplankton during a 24‐h period. P. gregaria survives ionic concentrations up to 250 000 g.m^‐3 Na⁺ + Cl^‐, and water temperatures up to 32°c.  相似文献   

Complexities in hindcasting models--when should we say enough is enough     

Maslia ML  Aral MM  Faye RE  Grayman WM  Suárez-Soto RJ  Sautner JB  Anderson BA  Bove FJ  Ruckart PZ  Moore SM 《Ground water》2012,50(1):10-6; discussion 16-8

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The conservation of small water reservoirs in the Krajeńskie Lakeland (North-West Poland)     

Barbara Waldon 《Limnologica》2012,42(4):320-327

This study comprised an inventory of vascular plants in 450 small water reservoirs (up to 1 ha in size). Most water bodies (76%) in the study area (Krajeńskie Lakeland, NW, Poland) were located in an agricultural landscape, typical of the region. A total of 576 species of vascular plants were recorded. Of these, about 76% were native species, 34 taxa were listed as legally protected in Poland and endangered in the region (Western Pomerania) or in Poland. 201 plant communities were identified, including 128 associations.Depending on the surrounding habitat, the following groups of ponds were identified: (1) mid-forest ponds; (2) mid-wetland ponds; ponds between arable fields, including (3) water basins with wide, well developed ecotone zones and (4) ponds with narrow or disturbed contact zones; and (5) ponds in urban areas. 30 ponds of each type were compared in detail. Differentiation and plant species richness of small water reservoirs was dependent on landscape type. The richest ponds were located within fields but isolated from their surroundings by a natural belt of rushes or trees, whilst mid-forest ponds were the poorest. Valorization was based on the presence of valuable flora (e.g. native, rare, and endangered species) and plant communities. This revealed that mid-forest and mid-wetland ponds were the most natural, while ponds in urban areas were the most strongly transformed.Ponds in the study area (n = 450) were also analysed for anthropogenic impacts. Anthropogenic stressors were observed in 51% of ponds. The most serious threats to the ponds of the Krajeńskie Lakeland were deterioration due to drainage and eutrophication. Over 35% of ponds were connected to a network of drainage ditches, with the highest percentage (57.1%) found in mid-forest ponds type.  相似文献