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61.
62.
Lagrangian trajectory methods are often applied as deterministic transport models, where transport is due strictly to advection without taking into account stochastic elements of particle dispersion, which raises questions about validity of the model results. The present work investigates the impact of horizontal eddy diffusivity for a case study of coastal pollution in the Gulf of Finland, where the pollutants are assumed to originate from a major fairway and are transported to the coast by surface currents. Lagrangian trajectories are calculated using the TRACMASS model from velocity fields calculated by the Rossby Centre circulation model for 1982 to 2001. Three cases are investigated: (1) trajectory calculation without eddy diffusivity, (2) stochastic modelling of eddy diffusivity with a constant diffusion coefficient and (3) stochastic modelling of eddy diffusivity with a time- and space-variable diffusion coefficient. It is found that the eddy diffusivity effect increases the spreading rate of initially closely packed trajectories and the number of trajectories that eventually reach the coast. The pattern of most frequently hit coastal sections, the probability of hit to each such section and the time the pollution spends offshore are virtually invariant with respect to inclusion of eddy diffusivity.  相似文献   
63.
A photographic Fabry-Perot interferometer was used to measure the breadth and wavelength of the Fexiv spectral line at 5303 Å in the solar corona, during the eclipse of 7 March, 1970, in Mexico. The observations were consistent with a possible large-scale vortex structure in a bright streamer, in which cooler gases revolved about a hotter core.Work supported by the United States National Science Foundation and by the Air Force Office of Scientific Research, Office of Aerospace Research, United States Air Force, under Grant AF-AFOSR-68-1496.  相似文献   
64.
This is a paper from the Swedish research project ‘The coastal zone—scientific criteria for planners’. The goal has been to establish simple, general scientific methods for management of Swedish coastal waters. In this paper the focus is on a set of empirical data from 21 so-called type areas and on the exchange of surface water. The working hypothesis has been that the water retention (or residence) time is regulated by the morphometry. The theory has been verified. It has been shown that the water retention time can be determined from a formula based on only two key morphometric parameters, the exposure and the mean coastal width. It provides an 86% degree of explanation (r2=0·86) of the variation in empirically determined retention times and can be physically linked to the basic mass balance equation. The formula is valid for the bioproductive season (May–Oct.) and for small (1–100 km2) Swedish coastal areas. It cannot be directly applied to areas affected by heavy tides.  相似文献   
65.
In order to preserve diversity it is essential to understand how assemblages change across space. Despite this fact, we still know very little about how marine diversity is spatially distributed, especially among lesser‐studied invertebrate taxa. In the present study beta‐diversity patterns of sea urchins, sponges, mushroom corals and larger foraminifera were assessed in the Spermonde Archipelago (Indonesia). Using ordinations we showed that the inshore zone (<5 km offshore), midshore zone (5 < x < 30 km offshore) and distance offshore zone (>30 km offshore) all contained distinct assemblages of sponges and corals, while only foraminifera assemblages from the inshore (<5 km offshore) zone were distinct. There was a significant spatial pattern of community similarity for all taxa surveyed, but this pattern proved to be wholly related to environmental variables for sponges and foraminifera, and primarily for mushroom corals and sea urchins. The lack of a pure spatial component suggests that these taxa may not be dispersal limited within the spatial scales of this study (c. 1600 km2). The analyses of the corals and foraminifera were additionally tested at two spatial scales of sampling. Both taxa were primarily associated with local‐scale environmental variables at the local scale and larger‐scale variables at the larger scale. Mean inter‐plot similarity was also higher and variation lower at the larger scale. The results suggest that substantial variation in similarity can be predicted using simple locally assessed environmental variables combined with remotely sensed parameters.  相似文献   
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There are several pre-orogenic Neoproterozoic granitoid and metavolcanic rocks in the Lufilian–Zambezi belt in Zambia and Zimbabwe that are interpreted to have been emplaced in a continental-rift setting that is linked to the break-up of the Rodinia supercontinent. However, no geochemical data were previously available for these rocks in the Zambian part of the belt to support this model. We conducted petrographic and whole-rock chemical analyses of the Neoproterozoic Nchanga Granite, Lusaka Granite, Ngoma Gneiss and felsic metavolcanic rocks from the Lufilian–Zambezi belt in Zambian, in order to evaluate their chemical characteristics and tectonic settings. Other magmatic rocks of importance for understanding the evolution of the belt in Zambia, included in this study, are the Mesoproterozoic Munali Hills Granite and associated amphibolites and the Mpande Gneiss. The Neoproterozoic rocks have monzogranitic compositions, aluminum-saturation indices (ASI) < 1.1, and high contents of high field strength elements (HFSE) and rare earth elements (REE). The chondrite-normalised spider diagrams are similar to those of A-type granites from the Lachlan fold belt and show negative Sr, P, and Ti anomalies. On various tectonic discrimination diagrams the Neoproterozoic rocks plot mainly in A-type granite fields. These petrographic and trace element compositions indicate that these rocks are A-type felsic rocks, but they do not have features of granites and rhyolites emplaced in true continental-rift settings, as previously suggested. On the basis of the A-type features and independent regional geological and geochronological data, we suggest that the Neoproterozoic granitoid and felsic metavolcanic rocks were emplaced during the earliest extensional stages of continental rifting in the Lufilian–Zambezi belt. The apparent continental-arc like chemistry of the granitoid and felsic metavolcanic rocks is thus inferred to be inherited from calcalkaline sources. The Mesoproterozoic Munali Hills Granite and Mpande Gneiss have trace element features e.g., Nb–Ta depletions, which indicate that that these gneisses were emplaced in a convergent-margin setting. The MORB-normalised spider diagram of co-magmatic amphibolites exhibit a fractionated LILE/HFSE pattern recognized in subduction zones. This inference is consistent with remnants of ocean crust, juvenile Island arcs and ophiolites elsewhere in the Mesoproterozoic Irumide belt in Zambia and Zimbabwe. In addition, we report the first U–Pb zircon age of 1090.1 ± 1.3 Ma for the Munali Hills Granite. The age for the Munali Hills Granite provides new constraints on correlation and tectono-thermal activity in the Lufilian–Zambezi belt. The age of the Munali Hills Granite indicates that some supracrustal rocks in the Zambezi belt of Zambia, which were previously thought to be Neoproterozoic and correlated with the Katanga Supergroup in the Lufilian belt, are Mesoproterozoic or older. Consequently, previous regional lithostratigraphic correlations in the Lufilian–Zambezi belt would require revision.  相似文献   
68.
69.
Subsurface sediments of tidal flats and the marine deep biosphere share several features. Although on different scales in time and space, geochemical profiles and microbial successions follow the same trends. Microbial activities are governed by the availability of electron acceptors and the quality of electron donors. Two deep-biosphere sites and a shallow site from a German North Sea tidal flat were exemplarily chosen to compare geochemical settings and microbiological features. At all sites, microbial abundance was elevated at sulfate–methane transition zones. The known discrepancy between cultivation-based and molecular diversity assessments is observed, but similar microbial community compositions are found with each of the approaches at deep and shallow sites. These findings lead to the conclusion that we are presently unable to draw a cutting line between the shallow and the deep subsurface. Rather, there appears to exist only one “subsurface biosphere” with gradual differences. Therefore, tidal flats serve as an excellent model to perform microbiological experiments and to test novel techniques before applying them to much deeper and older samples. Responsible editor: Meinhard Simon  相似文献   
70.
Electrochemical treatment is a promising emerging technology in which direct current is applied to drive the degradation of aqueous contaminants. Several bench-scale studies have demonstrated the capability of electrochemical oxidation to fully mineralize refractory organics such as pesticides and perfluorinated compounds. However, insights into large-scale design and field performance are critically lacking. Here, we designed six pilot-scale reactors and tested their performance and efficiency for the treatment of groundwater contaminated with 1,4-dioxane (1,4-DX) at concentrations exceeding 1000 mg/L. Anode surface area-normalized degradation rates increased with increasing potential applied, while the process was more energy-efficient per mass unit removed at low potentials. While not all 1,4-DX was completely mineralized, the detected ring-opening intermediates are known to be readily biodegradable. Analyses of potential by-products from chloride oxidation revealed the generation of chloromethanes and perchlorate at low mg/L concentrations. Towards the end of the 8.5-month pilot test, decreasing currents and degradation rates indicated progressing passivation of the electrodes, likely due to cathodic carbonate precipitation and/or poisoning by the uniquely high organic carbon load of this source zone groundwater. The findings of our study demonstrate that electrochemical groundwater remediation is a capable approach for the treatment of persistent organic pollutants. Our pilot-scale test provides practitioners with a basis for evaluating its efficiency under site-specific conditions and collecting critical performance metrics for technology scale-up.  相似文献   
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