Effect of surface albedo, water vapour, and atmospheric aerosols on the cloud-free shortwave radiative budget in the Arctic     

C. Di Biagio  A. di Sarra  P. Eriksen  S. E. Ascanius  G. Muscari  B. Holben 《Climate Dynamics》2012,39(3-4):953-969

This study is based on ground-based measurements of downward surface shortwave irradiance (SW), columnar water vapour (wv), and aerosol optical depth (τ) obtained at Thule Air Base (Greenland) in 2007–2010, together with MODIS observations of the surface shortwave albedo (A). Radiative transfer model calculations are used in combination with measurements to separate the radiative effect of A (ΔSW_A), wv (ΔSW_wv), and aerosols (ΔSW_τ) in modulating SW in cloud-free conditions. The shortwave radiation at the surface is mainly affected by water vapour absorption, which produces a reduction of SW as low as ?100 Wm^?2 (?18%). The seasonal change of A produces an increase of SW by up to +25 Wm^?2 (+4.5%). The annual mean radiative effect is estimated to be ?(21–22) Wm^?2 for wv, and +(2–3) Wm^?2 for A. An increase by +0.065 cm in the annual mean wv, to which corresponds an absolute increase in ΔSW_wv by 0.93 Wm^?2 (4.3%), has been observed to occur between 2007 and 2010. In the same period, the annual mean A has decreased by ?0.027, with a corresponding decrease in ΔSW_A by 0.41 Wm^?2 (?14.9%). Atmospheric aerosols produce a reduction of SW as low as ?32 Wm^?2 (?6.7%). The instantaneous aerosol radiative forcing (RF_τ) reaches values of ?28 Wm^?2 and shows a strong dependency on surface albedo. The derived radiative forcing efficiency (FE_τ) for solar zenith angles between 55° and 70° is estimated to be (?120.6 ± 4.3) for 0.1 < A < 0.2, and (?41.2 ± 1.6) Wm^?2 for 0.5 < A < 0.6.  相似文献   

When will it end? Long-lived intracontinental reactivation in central Australia     

Raphael Quentin de Gromard  Christopher L.Kirkland  Heather M.Howard  Michael T.D.Wingate  Fred Jourdan  Brent I.A.Mc Innes  Martin Daniík  Noreen J.Evans  Bradley J.McDonald  R.Hugh Smithies 《地学前缘(英文版)》2019,10(1):149-164

The post-Mesoproterozoic tectonometamorphic history of the Musgrave Province, central Australia, has previously been solely attributed to intracontinental compressional deformation during the 580 -520 Ma Petermann Orogeny. However, our new structurally controlled multi-mineral geochronology results,from two north-trending transects, indicate protracted reactivation of the Australian continental interior over ca. 715 million years. The earliest events are identified in the hinterland of the orogen along the western transect. The first tectonothermal event, at ca. 715 Ma, is indicated by40 Ar/39 Ar muscovite and U e Pb titanite ages. Another previously unrecognised tectonometamorphic event is dated at ca. 630 Ma by Ue Pb analyses of metamorphic zircon rims. This event was followed by continuous cooling and exhumation of the hinterland and core of the orogen along numerous faults, including the Woodroffe Thrust,from ca. 625 Ma to 565 Ma as indicated by muscovite, biotite, and hornblende40 Ar/39 Ar cooling ages. We therefore propose that the Petermann Orogeny commenced as early as ca. 630 Ma. Along the eastern transect,40 Ar/39 Ar muscovite and zircon(Ue Th)/He data indicate exhumation of the foreland fold and thrust system to shallow crustal levels between ca. 550 Ma and 520 Ma, while the core of the orogen was undergoing exhumation to mid-crustal levels and cooling below 600-660℃. Subsequent cooling to 150 -220℃ of the core of the orogen occurred between ca. 480 Ma and 400 Ma(zircon [Ue Th]/He data)during reactivation of the Woodroffe Thrust, coincident with the 450 -300 Ma Alice Springs Orogeny.Exhumation of the footwall of the Woodroffe Thrust to shallow depths occurred at ca. 200 Ma. More recent tectonic activity is also evident as on the 21 May, 2016(Sydney date), a magnitude 6.1 earthquake occurred, and the resolved focal mechanism indicates that compressive stress and exhumation along the Woodroffe Thrust is continuing to the present day. Overall, these results demonstrate repeated amagmatic reactivation of the continental interior of Australia for ca. 715 million years, including at least 600 million years of reactivation along the Woodroffe Thrust alone. Estimated cooling rates agree with previously reported rates and suggest slow cooling of 0.9 -7.0℃/Ma in the core of the Petermann Orogen between ca. 570 Ma and 400 Ma. The long-lived, amagmatic, intracontinental reactivation of central Australia is a remarkable example of stress transmission, strain localization and cratonization-hindering processes that highlights the complexity of Continental Tectonics with regards to the rigid-plate paradigm of Plate Tectonics.  相似文献   

Metal–organic complexation in the marine environment     

George W Luther III  Timothy F Rozan  Amy Witter  Brent Lewis 《Geochemical transactions》2001,2(1):65-10

We discuss the voltammetric methods that are used to assess metal–organic complexation in seawater. These consist of titration methods using anodic stripping voltammetry (ASV) and cathodic stripping voltammetry competitive ligand experiments (CSV-CLE). These approaches and a kinetic approach using CSV-CLE give similar information on the amount of excess ligand to metal in a sample and the conditional metal ligand stability constant for the excess ligand bound to the metal. CSV-CLE data using different ligands to measure Fe(III) organic complexes are similar. All these methods give conditional stability constants for which the side reaction coefficient for the metal can be corrected but not that for the ligand. Another approach, pseudovoltammetry, provides information on the actual metal–ligand complex(es) in a sample by doing ASV experiments where the deposition potential is varied more negatively in order to destroy the metal–ligand complex. This latter approach gives concentration information on each actual ligand bound to the metal as well as the thermodynamic stability constant of each complex in solution when compared to known metal–ligand complexes. In this case the side reaction coefficients for the metal and ligand are corrected. Thus, this method may not give identical information to the titration methods because the excess ligand in the sample may not be identical to some of the actual ligands binding the metal in the sample.  相似文献   

Assessing polygon edge integrity     

Steven A. Roberts  G. Brent Hall  Paul H. Calamai 《Journal of Geographical Systems》2001,3(1):87-105

Geographic entities are represented in vector GIS as geometric objects with definite position and sharp, zero or one-dimensional, boundaries. This representation ignores, and may in fact misrepresent, the underlying properties of many geographic features. This paper considers a binary classification scheme for ill-defined edges recently suggested by Couclelis (1996). Three initial perspectives of edge indeterminacy are considered for woodland polygons, namely functionally defined, using Hamming distances of the indeterminacy properties, and using the weighted trace of the connectivity matrix that defines the simplicial complex created from the indeterminacy relationships among the woodland polygons and their adjacent polygons. Finally, an analysis of the relationships created by the binary coding is carried out by examining more closely the connectivity structure of the simplicial complexes. The usefulness of the approach is discussed in the context of woodland habitat. Received: 20 March 1999/Accepted: 7 September 1999  相似文献   

40Ar/39Ar age spectra of some undisturbed terrestrial samples     

G. Brent Dalrymple  Marvin A. Lanphere 《Geochimica et cosmochimica acta》1974,38(5):715-738

⁴⁰Ar/³⁹Ar age spectra and ⁴⁰Ar/³⁶Ar vs ³⁹Ar/³⁶Ar isochrons were determined by incremental heating for 11 terrestrial rocks and minerals whose geology indicates that they represent essentially undisturbed systems. The samples include muscovite, biotite, hornblende, sanidine, plagioclase, dacite, diabase and basalt and range in age from 40 to 1700 m.y. For each sample, the ⁴⁰Ar/³⁹Ar ratios, corrected for atmospheric and neutron-generated argon isotopes, are the same for most of the gas fractions released and the age spectra, which show pronounced plateaus, thus are consistent with models previously proposed for undisturbed samples. Plateau ages and isochron ages calculated using plateau age fractions are concordant and appear to be meaningful estimates of the crystallization and cooling ages of these samples. Seemingly anomalous age spectrum points can be attributed entirely to small amounts of previously unrecognized argon loss and to gas fractions that contain too small (less than 2 per cent) a proportion of the ³⁹Ar released to be geologically significant. The use of a quantitative abscissa for age spectrum diagrams is recommended so that the size of each gas fraction is readily apparent. Increments containing less than about 4–5 per cent of the total ³⁹Ar released should be interpreted cautiously. Both the age spectrum and isochron methods of data reduction for incremental heating experiments are worthwhile, as each gives slightly different but complementary information about the sample from the same basic data. Use of a least-squares fit that allows for correlated errors is recommended for ⁴⁰Ar/³⁶Ar vs ³⁹Ar/³⁶Ar isochrons. The results indicate that the ⁴⁰Ar/³⁹Ar incremental heating technique can be used to distinguish disturbed from undisturbed rock and mineral systems and will be a valuable geochronological tool in geologically complex terranes.  相似文献   

Five hundred million years of punctuated addition of juvenile crust during extension in the Goochland Terrane,central Appalachian Piedmont Province     

Aaron J. Martin  Irene Kadel-Harder  Brent E. Owens  Kouki Kitajima  Scott D. Samson  Sanjeet K. Verma 《International Geology Review》2020,62(5):523-548

ABSTRACT

The Goochland Terrane is an enigmatic crustal block in the Appalachian Piedmont Province of central Virginia, USA. Sparse exposures of terminal Mesoproterozoic and late Neoproterozoic igneous rocks in the central Goochland Terrane offer the opportunity to investigate both the continental affinity of the terrane during the Proterozoic Eon and the timing and mechanisms of crustal growth. We apply multiple geochemical tools to these rocks: tectonic discrimination using whole-rock major and trace element abundances; whole-rock Sm-Nd isotopes; O, U-Pb, and Lu-Hf isotope analyses of spots in zircon; and measurement of O isotopes in multi-grain quartz separates. Eruption of the Sabot Amphibolite protolith is difficult to date, but we tentatively assign an age of 552 ± 11 Ma. Goochland Terrane continental crust first separated from the mantle prior to ca. 1050–1010 Ma intrusion of the Montpelier Anorthosite and the State Farm Gneiss protolith. The granitic magma that became the State Farm Gneiss protolith could have been derived entirely from partial melting of this initial Goochland Terrane crust. In contrast, the magmas that became the Montpelier Anorthosite, Neoproterozoic granitoid, and the Sabot Amphibolite were mixtures of mantle melt and preexisting Goochland Terrane crust. This production of juvenile continental crust occurred during continental extension and, eventually, rifting. The timing and compositions of terminal Mesoproterozoic magmatism in the Goochland Terrane closely match those in the nearby Blue Ridge Province. Although the compositions of the Neoproterozoic magmas in the two regions are similar, intrusion and possibly eruption occurred about 10 M.y. later in the Goochland Terrane.  相似文献   

鲁西中生代富钾火山岩及煌斑岩微量元素和Nd—Sr同位素地球化学   总被引：33，自引：1，他引：33  

邱检生 McI.  BIA 《高校地质学报》1997,3(4):384-385

鲁西中生代富钾火山岩产于断陷型陆相火山岩盆地中，煌斑岩多位于火山岩盘地的外圈。二者形成时代相近，产出的构造背景相同，在主量元素、微量元素和Nd－Sr同位索等特征上极为相似，均表现出富碱富钾、富轻稀土及大离于亲石元素和贫高场强元素及亲铁元素的特点，并具有显著偏低的εNd值和明显偏高的Isr值。研究结果表明，富钾火山岩和煌斑岩均起源于富集型地幔的部分熔融。  相似文献   

Kinematics of the Rockland Brook Fault, Nova Scotia: Implications for the interaction of the Meguma and Avalon terranes     

Brent V. Miller  R. Damian Nance  J. Brendan Murphy 《Journal of Geodynamics》1995,19(3-4)

The Cobequid-Chedabucto fault system of northern mainland Nova Scotia represents the surface expression of the Avalon-Meguma terrane boundary, but because it is exposed at high crustal levels in the Cobequid Highlands, the fault system provides little information as to the kinematic relationships of the two terranes in this area. In the eastern Cobequid Highlands, the Rockland Brook Fault (RBF) is exposed within the more deeply eroded highlands massif and juxtaposes units of widely varying ages and lithologies. Therefore, this fault is better suited to define the nature and timing of fault movement associated with Avalon-Meguma terrane interaction.In several large Carboniferous plutons along the length of the RBF, and in previously deformed Precambrian rocks, mylonitic foliation orientations are predominantly east-west trending and mineral lineations plunge southeast. Kinematic indicators such as minor fold vergence, porphyroclast systems, asymmetric boudins, shear-band fabrics, and preferred recrystallization orientations indicate dextral shear. These data are taken to infer that the central section of the RBF is dominated by dextral strike-slip motion. Transpression occurs locally where the RBF curves into restraining bends. Kinematic data in these bends indicate top to the northwest thrusting. At the easternmost extent of the RBF, high-level brittle normal faults predominate in the locally extensional environment. The timing of RBF movement is constrained only by the ca 360 Ma granite bodies which it deforms and by the Westphalian sedimentary rocks which are affected by only the latest stages of movement.These kinematic data are consistent with previously published kinematic models for the interaction of the southern margin of the Avalon Composite Terrane with the Meguma Terrane in mainland Nova Scotia. These models suggest that regional dextral shear was accompanied by localized components of transpressional thrusting, wrench tectonism, and small-scale sedimentary basin development during Devonian to Carboniferous terrane interaction.  相似文献   

Age and petrology of alkalic postshield and rejuvenated-stage lava from Kauai,Hawaii   总被引：4，自引：0，他引：4  

David A. Clague  G. Brent Dalrymple 《Contributions to Mineralogy and Petrology》1988,99(2):202-218

At the top of the Waimea Canyon Basalt on the island of Kauai, rare flows of alkalic postshield-stage hawaiite and mugearite overlie tholeiitic flows of the shield stage. These postshield-stage flows are 3.92 Ma and provide a younger limit for the age of the tholeiitic shield stage. The younger Koloa Volcanics consist of widespread alkalic rejuvenated-stage flows and vents of alkalic basalt, basanite, nephelinite, and nepheline melilitite that erupted between 3.65 and 0.52 Ma. All the flows older than 1.7 Ma occur in the west-northwestern half of the island and all the flows younger than 1.5 Ma occur in the east-southeastern half. The lithologies have no spatial or chronological pattern. The flows of the Koloa Volcanics are near-primary magmas generated by variable small degrees of partial melting of a compositionally heterogeneous garnet-bearing source that has about two-thirds the concentration of P₂O₅, rare-earth elements, and Sr of the source of the Honolulu Volcanics on the island of Oahu. The same lithology in the Koloa and Honolulu Volcanics is generated by similar degrees of partial melting of distinct source compositions. The lavas of the Koloa Volcanics can be generated by as little as 3 percent to as much as 17 percent partial melting for nepheline melilitite through alkalic basalt, respectively. Phases that remain in the residue of the Honolulu Volcanics, such as rutile and phlogopite, are exhausted during formation of the Koloa Volcanics at all but the smallest degrees of partial melting. The mantle source for Kauai lava becomes systematically more depleted in ⁸⁷Sr/⁸⁶Sr as the volcano evolves from the tholeiitic shield stage to the alkalic postshield stage to the alkalic rejuvenated stage: at the same time, the lavas become systematically more enriched in incompatible trace elements. On a shorter timescale, the lavas of the Koloa Volcanics display the same compositional trends, but at a lower rate of change. The source characteristics of the Koloa Volcanics, considered along with those of the Honolulu Volcanics, support a mixing model in which the source of rejuvenated-stage lava represents large-percent melts of a plume source mixed with small amounts of small-percent melts of a heterogeneous mid-ocean-ridge source.  相似文献   

In-situ high-temperature Raman spectroscopic studies of aluminosilicate liquids     

Isabelle Daniel  Philippe Gillet  Brent T. Poe  Paul F. McMillan 《Physics and Chemistry of Minerals》1995,22(2):74-86

We have measured in-situ Raman spectra of aluminosilicate glasses and liquids with albite (NaAlSi₃ O₈) and anorthite (CaAl₂Si₂O₈) compositions at high temperatures, through their glass transition range up to 1700 and 2000 K, respectively. For these experiments, we have used a wire-loop heating device coupled with micro-Raman spectroscopy, in order to achieve effective spatial filtering of the extraneous thermal radiation. A major concern in this work is the development of methodology for reliably extracting the first and second order contributions to the Raman scattering spectra of aluminosilicate glasses and liquids from the high temperature experimental data, and analyzing these in terms of vibrational (anharmonic) and configurational changes. The changes in the first order Raman spectra with temperature are subtle. The principal low frequency band remains nearly constant with increasing temperature, indicating little change in the T-O-T angle, and that the angle bending vibration is quite harmonic. This is in contrast to vitreous SiO₂, studied previously. Above Tg, intensity changes in the 560–590 cm^?1 regions of both sets of spectra indicate configurational changes in the supercooled liquids, associated with formation of additional Al-O-Al linkages, or 3-membered (Al, Si)-containing rings. Additional intensity at 800 cm^?1 reflects also some rearrangement of the Si-O-Al network.  相似文献