Holocene hydrological reconstructions from stable isotopes and paleolimnology, Cordillera Real, Bolivia     

Mark B. Abbott  Brent B. Wolfe  Ramn Aravena  Alexander P. Wolfe  Geoffrey O. Seltzer 《Quaternary Science Reviews》2000,19(17-18)

Multiproxy analyses of sediment cores from Lago Taypi Chaka Kkota (LTCK) Cordillera Real, Bolivia, provide a record of drier conditions following late Pleistocene deglaciation culminating in pronounced aridity between 6.2 and 2.3 ka B.P. Today LTCK is a glacial-fed lake that is relatively insensitive to changes in P–E because it is largely buffered from dry season draw-down through the year-round supply of glacial meltwater. This was not the case during the middle to late Holocene when glaciers were absent from the watershed. Lake-water δ¹⁸O values inferred from δ¹⁸O analysis of sediment cellulose range from −12.9 to −5.3‰ and average −8.7‰ between 6.2 and 2.3 ka B.P. Modern lake-water δ¹⁸O from LTCK averages −14.8‰ which is compatible with the δ¹⁸O_lw value of −14.3‰ for the surface sediment cellulose. Analyses of δ¹⁸O from modern surface waters in 23 lakes that span the range from glacial-fed to closed basin vary from −16.6 to −2.5‰. This approximates the magnitude of the down-core shift in δ¹⁸O_lw values in LTCK during the middle to late Holocene from −12.9 to −5.3‰. Strong paleohydrologic change during the middle Holocene is also evident in diatom assemblages that consist of shallow-water, non-glacial periphytic taxa and bulk organic δ¹³C and δ¹⁵N that show increases likely resulting from degradation of lacustrine organic matter periodically exposed to subaerial conditions. Neoglaciation began after 2.3 ka B.P. as indicated by changes in the composition of the sediments, lower δ¹⁸O values, and a return to diatom assemblages characteristic of the glacial sediments that formed during the Late Pleistocene. Collectively, these data indicate that the past 2.3 ka B.P. have been the wettest interval during the Holocene. Millennial-scale shifts in the paleohydrologic record of LTCK during the early to middle Holocene conform to other regional paleoclimatic time-series, including Lake Titicaca and Nevado Sajama, and may be driven by insolation and resultant changes in atmospheric circulation and moisture supply. In contrast, an apparent 1200-year lag in the onset of wetter conditions at LTCK (2.3 ka B.P.) compared to Lake Titicaca (3.5 ka B.P.) provides evidence for variable sub-regional hydrologic response to climate change during the middle to late Holocene.  相似文献   

Use of voltammetric solid-state (micro)electrodes for studying biogeochemical processes: Laboratory measurements to real time measurements with an in situ electrochemical analyzer (ISEA)     

George W. Luther III  Brian T. Glazer  Shufen Ma  Robert E. Trouwborst  Tommy S. Moore  Edouard Metzger  Chareonkwan Kraiya  Tim J. Waite  Gregory Druschel  Bjrn Sundby  Martial Taillefert  Donald B. Nuzzio  Timothy M. Shank  Brent L. Lewis  Paul J. Brendel 《Marine Chemistry》2008,108(3-4):221-235

Solid-state voltammetric (micro)electrodes have been used in a variety of environments to study biogeochemical processes. Here we show the wealth of information that has been obtained in the study of sediments, microbial mats, cultures and the water column including hydrothermal vents. Voltammetric analyzers have been developed to function with operator guidance and in unattended mode for temporal studies with an in situ electrochemical analyzer (ISEA). The electrodes can detect the presence (or absence) of a host of redox species and trace metals simultaneously. The multi-species capacity of the voltammetric electrode can be used to examine complex heterogeneous environments such as the root zone of salt marsh sediments. The data obtained with these systems clearly show that O₂ and Mn²⁺ profiles in marine sedimentary porewaters and in microbial biofilms on metal surfaces rarely overlap indicating that O₂ is not a direct oxidant for Mn²⁺. This lack of overlap was suggested originally by Joris Gieskes' group. In waters emanating from hydrothermal vents, Fe²⁺, H₂S and soluble molecular FeS clusters (FeS_aq) are detected indicating that the reactants for the pyrite formation reaction are H₂S and soluble molecular FeS clusters. Using the ISEA with electrodes at fixed positions, data collected continuously over three days near a Riftia pachyptila tubeworm field generally show that O₂ and H₂S anti-correlate and that H₂S and temperature generally correlate. Unlike sedimentary environments, the data clearly show that Riftia live in areas where both O₂ and H₂S co-exist so that its endosymbiont bacteria can perform chemosynthesis. However, physical mixing of diffuse flow vent waters with oceanic bottom waters above or to the side of the tubeworm field can dampen these correlations or even reverse them. Voltammetry is a powerful technique because it provides chemical speciation data (e.g.; oxidation state and different elemental compounds/ions) as well as quantitative data. Because (micro)organisms occupy environmental niches due to the system's chemistry, it is necessary to know chemical speciation. Voltammetric methods allow us to study how chemistry drives biology and how biology can affect chemistry for its own benefit.  相似文献   

‘Locationally disadvantaged’: planning governmentalities and peri-urban agricultural futures     

Laura Wynne  Dana Cordell  Brent Jacobs 《The Australian geographer》2020,51(3):377-397

ABSTRACT

Peri-urban areas are the interface between urban and rural regions, with these regions traditionally acting as foodbowls for adjacent urban areas. This peri-urban agriculture provides a diverse suite of benefits to urban areas. Increasingly, however, peri-urban areas are being converted to residential uses, driven in part by higher land values secured for land converted for residential development. In Sydney, planning and development has tended to treat peri-urban areas as ‘suburbs in waiting’. Using a Foucauldian governmentality approach, this paper investigates the prevailing rationalities in metropolitan-level strategic planning documents—in particular A Plan for Growing Sydney and the Draft South West District Plan—and how these rationalities relate to peri-urban agriculture. Our analysis shows that the three overarching rationalities—the global city, the compact city and the sustainability agenda—frame the urbanisation of peri-urban agricultural lands as necessary and inevitable, and only integrate agriculture as part of the future of the city of Sydney when it can be rationalised within the ‘global city’ narrative. As a result, peri-urban areas are not considered to have unique planning needs, but are imagined as latent spaces that will enable Sydney to meet its housing and job targets through their future development.  相似文献   

Conceptualizations of local knowledge in collaborative environmental governance     

Brent Taylor  Rob C. de Loë 《Geoforum》2012,43(6):1207-1217

A major challenge to integrating local knowledge into collaborative environmental governance processes stems from the underlying differences between positivist science and local knowledge; these differences often result in strong differences of opinion regarding which forms of knowledge are valid in environmental decision-making. Previous research on these issues has mainly focused on the attitudes of scientists towards local knowledge. Studies of the views of local and non-scientific actors regarding their own knowledge are much less common. Through a qualitative case study of water allocation planning in South Australia, we analyzed participants’ conceptualizations of local knowledge and the role of local knowledge in collaborative governance. We found that participants defined local knowledge broadly across a number of dimensions and that many acknowledged variability in the nature and quality of different types of local knowledge. While most recognized the value of local knowledge in supporting technical investigations and developing policies, very few participants identified a role for local knowledge in the early stages of the collaborative process (i.e., in framing problems or establishing research protocols). Previous research has highlighted “epistemological anxiety” among scientists and resource managers toward local knowledge as a significant barrier to its effective use in environmental decision-making. This study suggests that state and local actors, and scientists and non-scientists, share similar reservations about local knowledge and highlights the need for researchers and practitioners to take into account the attitudes of all types of participants when considering how to overcome the epistemological challenges related to integrating local knowledge into collaborative management.  相似文献   

Practical finite analytic methods for simulation of advection-dominated solute transport     

M. Salman Sabahi  Hanif Montazeri  Mojtaba Ardestani  Brent Sleep 《水文科学杂志》2013,58(12):2204-2213

Abstract

The practical finite-analytic (PFA) method was applied to the solution of the one-dimensional advection–dispersion equation (ADE) for solute transport in porous media under advection-dominated (high Peclet number, Pe) conditions. Several PFA spatial-temporal computational molecules were developed for Cauchy and pulse loading boundary conditions. The PFA solutions were compared with solutions from the upwind method and quadratic upwind differencing (QUICK) scheme. For all boundary conditions the trapezoidal explicit PFA (EPFA) computational molecule gave the most accurate results at very high Pe number as long as the Courant number (Cr) was close to one. Stability analysis shows that the PFA molecules are always stable for high Pe number.  相似文献   

Last interglacial western camel (Camelops hesternus) from eastern Beringia     

Grant D. Zazula  Derek G. Turner  Brent C. Ward  Jeffrey Bond 《Quaternary Science Reviews》2011,30(19-20):2355-2360

Western camel (C. hesternus) fossils are rare from Eastern Beringia, thus there is little available information on their chronology, paleoecology, and biogeography in this region. In August of 2010, a partial proximal phalanx of a western camel was recovered from a sedimentary exposure along the White River, in the formerly glaciated terrain of southwest Yukon, northwest Canada. The fossil specimen was recovered in situ from sediments that are correlated by stratigraphic, tephra and radiocarbon data to the Marine Isotope Stage (MIS) 5 interglacial period (Sangamonian). Associated paleoenvironmental data indicates that this western camel inhabited a shrub tundra ecosystem that did not include spruce trees or boreal forest during a relatively cold interval between MIS 5e and 5a. This is the oldest reliably dated western camel fossil from Eastern Beringia and supports the model of range expansion for this species to the high latitudes of northwest North America during the last interglacial (sensu lato).  相似文献   

Assessment of the crop coefficient for saltgrass under native riparian field conditions in the desert southwest          下载免费PDF全文

A. Salim Bawazir  Richard Luthy  J. Phillip King  Brent F. Tanzy  Juan Solis 《水文研究》2014,28(25):6163-6171

Limited urban water supplies in southwestern USA cause water managers and planners to re‐assess water losses and needs from consumptive water use by riparian vegetation. Here, we report on field measurements of evapotranspiration (ET) for inland saltgrass [Distichlis spicata var. stricta (L.) Greene]; a once common riparian plant native to the desert southwest. The objective was to develop a saltgrass crop coefficient, Kc, similar to agricultural crop coefficients commonly used in irrigation water management. The developed Kc, in conjunction with the local climate, can then be used to assess the water savings that may be achieved in riparian zones for saltgrass versus invasive species and for use in irrigation management and scheduling of saltgrass in urban setting. The ET of saltgrass was measured in its native riparian setting located in the flood plain of the Rio Grande, north of Caballo Lake, New Mexico, in 2011 using an eddy covariance technique in the energy budget method. Total ET of 692 mm was measured during the growing season (n = 241 days) and 837 mm during the year. The American Society of Civil Engineers standardized ET for short crop (ETso) was calculated using climate data measured at the study site as 1560 mm during the growing season and 1870 mm during the year. Crop coefficients (ET/ETso) were fitted with a polynomial equation as a function of day of the year to develop saltgrass Kc function. A graphical and simplified method of computing Kc as a function of day of the year and crop season was also developed as an alternative method. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Evaluating the hydrological and hydrochemical responses of a High Arctic catchment during an exceptionally warm summer          下载免费PDF全文

Daniel Lamhonwah  Melissa J. Lafrenière  Scott F. Lamoureux  Brent B. Wolfe 《水文研究》2017,31(12):2296-2313

The Arctic has experienced substantial warming during the past century with models projecting continued warming accompanied by increases in summer precipitation for most regions. A key impact of increasing air surface temperatures is the deepening of the active layer, which is expected to alter hydrological processes and pathways. The aim of this study was to determine how one of the warmest and wettest summers in the past decade at a High Arctic watershed impacted water infiltration and storage in deeply thawed soil and solute concentrations in stream runoff during the thaw period. In June and July 2012 at the Cape Bounty Watershed Observatory, we combined active layer measurements with major ion concentrations and stable isotopes in surface waters to characterize the movement of different runoff sources: snowmelt, rainfall, and soil water. Results indicate that deep ground thaw enhanced the storage of infiltrated water following rainfall. Soil water from infiltrated rainfall flowed through the thawed transient layer and upper permafrost, which likely solubilized ions previously stored at depth. Subsequent rainfall events acted as a hydrological flushing mechanism, mobilizing solutes from the subsurface to the surface. This solute flushing substantially increased ion concentrations in stream runoff throughout mid to late July. Results further suggest the importance of rainfall and soil water as sources of runoff in a High Arctic catchment during mid to late summer as infiltrated snowmelt is drained from soil following baseflow. Although there was some evaporation of surface water, our study indicates that flushing from solute stores in the transient layer was the primary driver of increased ion concentrations in stream runoff and not evaporative concentration of surface water. With warmer and wetter summers projected for the Arctic, ion concentrations in runoff (especially in the late thaw season), will likely increase due to the deep storage and subsurface flow of infiltrated water and subsequent flushing of previously frozen solutes to the surface.  相似文献   

The Impact of Biofilm Growth on Transport of Escherichia coli O157:H7 in Sand     

Aimin Wang  Bin Lin  Brent E. Sleep  Steven N. Liss 《Ground water》2011,49(1):20-31

Understanding the transport behavior, survival, and persistence of pathogens such as Escherichia coli O157:H7 in the subsurface is essential to protection of public health. In this study, the transport of E. coli O157:H7 in a two‐dimensional bench‐scale sand aquifer system, hereafter referred to as the sandbox, was investigated, with a focus on the impact of biofilm development on E. coli retention and survival. Biofilm growth was initiated through flushing with unsterilized groundwater and addition of glucose, nitrate, and phosphate. Retention of E. coli from an injection test in clean sand, prior to promotion of biofilm growth, was approximately 9%. Subsequent to biofilm growth, 47% of injected E. coli cells were retained under similar flow conditions. After 10 d of no flow, sterile water was flushed through the biofouled sandbox and substantial concentrations (up to 1.5 × 10⁵ cells/mL) of E. coli were measured in the effluent indicating that E. coli had survived the starvation period. Confocal laser scanning microscopy revealed that E. coli were located not only on the surface but also within the biofilm. Imposition of starvation conditions resulted in biofilm sloughing and possible mobilization of biofilm‐associated E. coli.  相似文献   

Evidence for multiple modes of uranium immobilization by an anaerobic bacterium     

Allison E. Ray  John R. Bargar  Alice C. Dohnalkova  Brent M. Peyton  Timothy S. Magnuson 《Geochimica et cosmochimica acta》2011,75(10):2684-6510

Microbial reduction of hexavalent uranium has been studied widely for its potential role in bioremediation and immobilization of soluble U(VI) in contaminated groundwater. More recently, some microorganisms have been examined for their role in immobilization of U(VI) via precipitation of uranyl phosphate minerals mediated by microbial phosphate release, alleviating the requirement for long-term redox control. Here, we investigated the mechanism of U(VI) removal mediated by an environmental isolate, strain UFO1, that is indigenous to the Field Research Center (FRC) in Oak Ridge, TN and has been detected in U(VI)-contaminated sediments. Changes in U(VI) speciation were examined in the presence and absence of the electron-shuttling moiety, anthraquinone-2,6-disulfonate (AQDS). Cell suspensions were capable of nearly complete removal of 100 μM U(VI) from solution within 48 h; U(VI) removal was not dependent on the presence of an exogenous electron donor or AQDS, although AQDS increased the rate of U(VI) removal. X-ray Absorption Near Edge Structure (XANES) and Extended X-ray Absorption Fine Structure (EXAFS) spectroscopic measurements indicated that U(IV) was the predominant oxidation state of uranium in cell suspensions in both the absence and presence of 100 μM AQDS. Interestingly, 17% of the cell-associated precipitates in a U(VI)-treated suspension that lacked AQDS had spectral characteristics consistent with a uranyl phosphate solid phase. The potential involvement of phosphate was consistent with observed increases in soluble phosphate concentrations over time in UFO1 cell suspensions, which suggested phosphate liberation from the cells. TEM-EDS confirmed the presence of uranyl phosphate with a U:P ratio consistent with autunite (1:1). EXAFS analyses further suggested that U(IV) was bound to low-Z neighbors such as C or P, inferred to be present as functional groups on biomass. These results suggest that strain UFO1 has the ability to facilitate U(VI) removal from solution via reductive and phosphate precipitation mechanisms. Both mechanisms offer potential for the remediation of U-contaminated sediments at the FRC or elsewhere.  相似文献