Mercury-bearing black shales and human Hg intake in eastern Finland: impact and mechanisms   总被引：1，自引：0，他引：1  

K. Loukola-Ruskeeniemi  M. Kantola  T. Halonen  K. Seppänen  P. Henttonen  E. Kallio  P. Kurki  H. Savolainen 《Environmental Geology》2003,43(3):283-297

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Weather as a Chronic Hazard for Road Transportation in Canadian Cities   总被引：2，自引：1，他引：2  

Jean Andrey  Brian Mills  Mike Leahy  Jeff Suggett 《Natural Hazards》2003,28(2-3):319-343

Inclement weather creates a chronic hazard for Canadian travellers. Past studies indicate that road collision rates increase during precipitation, although the magnitude of theincrease varies from study to study, partly as a result of variations in weather and driving conditions,but also because of differences in methods. The goal of the current study is to improve ourunderstanding of the links between weather and travel risk in mid-sized Canadian cities by using astandardized method for analyzing data from six cities with different climates: Halifax-Dartmouth,Ottawa, Québec, Hamilton, Waterloo Region, and Regina. The study has four interrelated objectives: (1) Toconduct a sensitivity analysis to determine the extent to which risk estimates vary depending onthe criteria used to define precipitation events and `normal' conditions; (2) To compare therelative risk of collision and injury during precipitation relative to `normal' conditions; (3) Todetermine the extent to which weather-related risks vary fordifferent Canadian cities; and (4) To explore any differences in collision characteristics between events and controls, especially as theyvary from city to city. Results are based on a matched-pair analysis, using six-hour time blocks over afour-year period, 1995 to 1998. Results indicate only modest sensitivity to the criteria used to define precipitation events and `normal' conditions. On average, precipitation is associated with a 75 percentincrease in traffic collisions and a 45 percent increase in related injuries, as compared to `normal'seasonal conditions, but risk levels vary depending on the characteristics of the weather event.Both sensitivity to specific weather conditions and weather-related accident profiles vary from city tocity in ways that are not easily explained.  相似文献   

Capture of Helium and Other Volatiles during the Growth of Olivine Phenocrysts in Picritic Basalts from the Juan Fernandez Islands   总被引：1，自引：0，他引：1  

NATLAND  JAMES H. 《Journal of Petrology》2003,44(3):421-456

Olivine crystals in basalt contain helium that can be extractedfor isotopic analysis. Helium-bearing olivine phenocrysts inpicritic tholeiites from the Juan Fernandez Islands, SE Pacific,crystallized from moderately differentiated liquids. None arexenocrysts of mantle peridotite. The helium occurs in cavitiesor bubbles in inclusions best seen at high magnification inthe olivine. The olivine grew around spinel, sulfide, and bubblesthat preferentially nucleated on crystal surfaces. Inclusionswithin these phases range from large cavities to tiny, facetedpits arranged in rows. Many crystals contain curving trainsof inclusions along annealed features. The inclusions formedduring mixing between cooler differentiated magma and hotterolivine-charged magma, which accelerated vesiculation. Bubblesnucleated on the olivine as they do on ice when stirred in carbonatedwater. Mixing also induced thermal stress fracturing, like thecracking of ice dropped into water. Cracking, irregular extinction,and subgrain formation occurred when faceted crystals collidedwith each other or with conduit walls. Boundary layer meltsand bubbles were drawn quickly into the fractures. Thus fewinclusions contain equilibrium proportions of minerals and vapor.Mantle-derived helium clearly permeated into shallow storagereservoirs, including rift zones where magmatic differentiation,mixing, and vapor exsolution were fairly extensive. KEY WORDS: Juan Fernandez; volatiles; inclusions; olivine; picrite  相似文献   

Atomistic simulation of the structure and elastic properties of pyrite (FeS2) as a function of pressure     

Sithole  H.M.  Ngoepe  P.E.  Wright  K. 《Physics and Chemistry of Minerals》2003,30(10):615-619

Interatomic potential parameters have been derived at simulated temperatures of 0 K and 300 K to model pyrite FeS₂. The predicted pyrite structures are within 1% of those determined experimentally, while the calculated bulk modulus is within 7%. The model is also able to simulate the properties of marcasite, even though no data for this phase were included in the fitting procedure. There is almost no difference in results obtained for pyrite using the two potential sets; however, when used to model FeS₂ marcasite, the potential fitted at 0 K performs better. The potentials have also been used to study the high-pressure behaviour of pyrite up to 44 GPa. The calculated equation of state gives good agreement with experiment and shows that the Fe–S bonds shorten more rapidly that the S–S dimer bonds. The behaviour of marcasite at high pressure is found to be similar to that of pyrite.  相似文献   

Iron and Sulfur Chemistry in a Stratified Lake: Evidence for Iron-Rich Sulfide Complexes   总被引：5，自引：1，他引：5  

George W. Luther III  Brian Glazer  Shufen Ma  Robert Trouwborst  Bradley R. Shultz  Gregory Druschel  Charoenwan Kraiya 《Aquatic Geochemistry》2003,9(2):87-110

A four month study of a man-made lake used for hydroelectric power generation in northeastern Pennsylvania USA was conducted to investigate seasonal anoxia and the effects of sulfide species being transported downstream of the power generation equipment. Water column analyses show that the system is iron-rich compared to sulfide. Total Fe(II) concentrations in the hypolimnion are typically at least twice the total sulfide levels. In situ voltammetric analyses show that free Fe(II) as [Fe(H₂O)₆]²⁺ or free H₂S as H₂S/HS^- are either not present or at trace levels and that iron-rich sulfide complexes are present. From the in situ data and total Fe(II) and H₂S measurements, we infer that these iron-rich sulfide complexes may have stoichiometries such as Fe₂SH³⁺ (or polymeric forms of this and other stoichiometries). These iron-rich sulfide complexes appear related to dissolution of the iron-rich FeS mineral, mackinawite, because IAP calculations on data from discrete bottle samples obtained from bottom waters are similar to the pK_sp of mackinawite. Soluble iron-sulfide species are stable in the absence of O₂ (both in lake waters and the pipeline) and transported several miles during power generation. However, iron-sulfide complexes can react with O₂ to oxidize sulfide and can also dissociate releasing volatile H₂S when the waters containing them are exposed to the atmosphere downstream of the powerplant. Sediment analyses show that the lake is rich in oxidized iron solids (both crystalline and amorphous). Fe concentrations in FeS solids are low (<5 μmole/gr_{dry wt}) and the pyrite concentration ranges from about equal to the solid FeS to 30 times the solid FeS concentration. The degree of pyritization is below 0.12 indicating that pyrite formation is limited by free sulfide, which can react with the iron-rich sulfide complexes.  相似文献   

Metamorphic petrology and zircon geochronology of high-grade rocks from the central Mozambique Belt of Tanzania: crustal recycling of Archean and Palaeoproterozoic material during the Pan-African orogeny   总被引：7，自引：0，他引：7  

H. Sommer  A. Kröner  C. Hauzenberger  S. Muhongo  M. T. D. Wingate 《Journal of Metamorphic Geology》2003,21(9):915-934

New data on the metamorphic petrology and zircon geochronology of high‐grade rocks in the central Mozambique Belt (MB) of Tanzania show that this part of the orogen consists of Archean and Palaeoproterozoic material that was structurally reworked during the Pan‐African event. The metamorphic rocks are characterized by a clockwise P–T path, followed by strong decompression, and the time of peak granulite facies metamorphism is similar to other granulite terranes in Tanzania. The predominant rock types are mafic to intermediate granulites, migmatites, granitoid orthogneisses and kyanite/sillimanite‐bearing metapelites. The meta‐granitoid rocks are of calc‐alkaline composition, range in age from late Archean to Neoproterozoic, and their protoliths were probably derived from magmatic arcs during collisional processes. Mafic to intermediate granulites consist of the mineral assemblage garnet–clinopyroxene–plagioclase–quartz–biotite–amphibole ± K‐feldspar ± orthopyroxene ± oxides. Metapelites are composed of garnet‐biotite‐plagioclase ± K‐feldspar ± kyanite/sillimanite ± oxides. Estimated values for peak granulite facies metamorphism are 12–13 kbar and 750–800 °C. Pressures of 5–8 kbar and temperatures of 550–700 °C characterize subsequent retrogression to amphibolite facies conditions. Evidence for a clockwise P–T path is provided by late growth of sillimanite after kyanite in metapelites. Zircon ages indicate that most of the central part of the MB in Tanzania consists of reworked ancient crust as shown by Archean (c. 2970–2500 Ma) and Palaeoproterozoic (c. 2124–1837 Ma) protolith ages. Metamorphic zircon from metapelites and granitoid orthogneisses yielded ages of c. 640 Ma which are considered to date peak regional granulite facies metamorphism during the Pan‐African orogenic event. However, the available zircon ages for the entire MB in East Africa and Madagascar also document that peak metamorphic conditions were reached at different times in different places. Large parts of the MB in central Tanzania consist of Archean and Palaeoproterozoic material that was reworked during the Pan‐African event and that may have been part of the Tanzania Craton and Usagaran domain farther to the west.  相似文献   

Lithofacies succession of maar crater deposits in the Eifel area (Germany)   总被引：2，自引：0，他引：2  

M. Pirrung  C. Fischer  G. Büchel  R. Gaupp  H. Lutz  F. -O. Neuffer 《地学学报》2003,15(2):125-132

ABSTRACT Maar craters often contain exceptionally preserved fossils and maar sediments may reflect detailed environmental changes. Volcanosedimentary processes in a Middle Eocene maar crater lake are illustrated by the deposits of Eckfeld Maar in the Tertiary Hocheifel Volcanic Field (Rhenish Massif, Germany). The maar origin of the basin is evident from a circular negative gravity anomaly which indicates a low-density funnel-shaped basin filling. From the facies analysis of an Eocene (Eckfeld) and a Pleistocene (Döttingen) maar we develop a lithozone classification for the interpretation of maar sediments: syn-/post-eruptive breccias are followed by a fining-upwards sequence of lacustrine mud with coarse layers and final swamp deposits. From the facies analysis and regional geological data we reconstruct the pre- to post-eruptive history of a maar crater prior to post-Eocene uplift. These observations can be used for the interpretation of Tertiary and Quaternary maar craters that are ideal fossil and sediment traps.  相似文献   

Estimation of causative fault parameters of the Rudbar earthquake of June 20, 1990 from near field SH-wave data     

I. Sarkar  H. Hamzehloo  K. N. Khattri   《Tectonophysics》2003,364(1-2):55-70

We analyze the strong motion accelerograms recorded for the large (M_S=7.7, M_W=7.3, m_b=6.4) Rudbar earthquake of June 20, 1990. The earthquake had a complex source process. We have identified the imprints of rupture of three localized asperities on the major causative fault on the accelerograms. These asperities are interpreted to correspond to (i) the main shock that initiated the rupture process and was located in the domino block between the Kabateh and Zard Goli faults, (ii) a foreshock that occurred about 10 s earlier in the Kabateh fault and (iii) a later shock, on the western end of the Baklor fault, which terminated the bilateral rupture process at the western end. We estimate the strike, dip and slip of these causative sub-event rupture planes using the SH spectral amplitudes, based on a point source representation of sub-events and a non-linear least square formulation for inversion of the amplitude data. The results of our inversion of the near field data are comparable to other studies based on teleseismic data.  相似文献   

Early formed regional antiforms and synforms that fold younger matrix schistosities: their effect on sites of mineral growth     

T. H. Bell  A. P. Ham  K. A. Hickey 《Tectonophysics》2003,367(3-4):253-278

In the metamorphic cores of many orogenic belts, large macroscopic folds in compositional layering also appear to fold one or more pervasive matrix foliations. The latter geometry suggests the folds formed relatively late in the tectonic history, after foliation development. However, microstructural analysis of four examples of such folds suggests this is not the case. The folds formed relatively early in the orogenic history and are the end product of multiple, near orthogonal, overprinting bulk shortening events. Once large macroscopic folds initiate, they may tighten further during successive periods of sub-parallel shortening, folding or reactivation of foliations that develop during intervening periods of near orthogonal shortening. Reactivation of the compositional layering defining the fold limbs causes foliation to be rotated into parallelism with the limbs.Multiple periods of porphyroblast growth accompanied the multiple phases of deformation that postdated the initial development of these folds. Some of these phases of deformation were attended by the development of large numbers of same asymmetry spiral-shaped inclusion trails in porphyroblasts on one limb of the fold and not the other, or larger numbers of opposite asymmetry spirals on the other limb, or similar numbers of the same asymmetry spirals on both limbs. Significantly, the largest disparity in numbers from limb to limb occurred for the first of these cases. For all four regional folds examined, the structural relationships that accompanied these large disparities were identical. In each case the shear sense operating on steeply dipping foliations was opposite to that required to originally develop the fold. Reactivation of the folded compositional layering was not possible for this shear sense. This favoured the development of sites of approximately coaxial shortening early during the deformation history, enhancing microfracture and promoting the growth of porphyroblasts on this limb in comparision to the other. These distributions of inclusion trail geometries from limb to limb cannot be explained by porphyroblast rotation, or folding of pre-existing rotated porphyroblasts within a shear zone, but can be explained by development of the inclusion trails synchronous with successive sub-vertical and sub-horizontal foliations.  相似文献   

The early Caledonian (Finnmarkian) event reassessed in Finnmark: Ar/Ar cleavage age data from NW Varangerhalvøya, N. Norway     

A. H. N. Rice  W. Frank 《Tectonophysics》2003,374(3-4):219-236

The relative significance of early (Finnmarkian) and late (Scandian) Caledonian deformation in N. Norway is uncertain. Early studies suggested pervasive Finnmarkian deformation whilst later results indicated a restricted Finnmarkian domain. The present work suggests it was more widespread than accepted and that inter Finnmarkian–Scandian deformation occurred. ⁴⁰Ar/³⁹Ar dating of 2–6 and 6–11 μm pelitic fractions from the lower to mid-greenschist facies Tanahorn Nappe (five samples; base Middle Allochthon) and the epizone Løkvikfjellet and Barents Sea Groups (three samples; North Varanger Region) in the north Scandinavian Caledonides show slightly discordant spectra. Most spectra from the Tanahorn Nappe preserve possible evidence of an early Caledonian event in the high temperature steps, with recoil/excess Ar effects in the low temperature steps; no pre-Caledonian relict component has been recorded. The results indicate Finnmarkian deformation continued to 460 Ma, with Scandian reactivation at 425–415 Ma. From the North Varanger Region, a strongly crenulated sample yielded plateau ages (444–442 Ma); means of combined young steps from weakly to uncrenulated samples gave 470–450 Ma, suggesting penetrative strike-slip deformation occurred in the late Finnmarkian to inter-Finnmarkian–Scandian period. No Scandian ages were recorded in the North Varanger Region. Reassessment of published data from the Laksefjord Nappe and Gaissa Thrust Belt suggests they were affected by Finnmarkian deformation.  相似文献