Reclassification of Villalbeto de la Peña—Occurrence of a winonaite‐related fragment in a hydrothermally metamorphosed polymict L‐chondritic breccia     

Addi Bischoff  Kathryn A. Dyl  Marian Horstmann  Karen Ziegler  Karl Wimmer  Edward D. Young 《Meteoritics & planetary science》2013,48(4):628-640

The Villalbeto de la Peña meteorite that fell in 2004 in Spain was originally classified as a moderately shocked L6 ordinary chondrite. The recognition of fragments within the Villalbeto de la Peña meteorite clearly bears consequences for the previous classification of the rock. The oxygen isotope data clearly show that an exotic eye‐catching, black, and plagioclase‐(maskelynite)‐rich clast is not of L chondrite heritage. Villalbeto de la Peña is, consequently, reclassified as a polymict chondritic breccia. The oxygen isotope data of the clast are more closely related to data for the winonaite Tierra Blanca and the anomalous silicate‐bearing iron meteorite LEW 86211 than to the ordinary chondrite groups. The REE‐pattern of the bulk inclusion indicates genetic similarities to those of differentiated rocks and their minerals (e.g., lunar anorthosites, eucritic, and winonaitic plagioclases) and points to an igneous origin. The An‐content of the plagioclase within the inclusion is increasing from the fragment/host meteorite boundary (approximately An₁₀) toward the interior of the clast (approximately An₅₂). This is accompanied by a successive compositionally controlled transformation of plagioclase into maskelynite by shock. As found for plagioclase, compositions of individual spinels enclosed in plagioclase (maskelynite) also vary from the border toward the interior of the inclusion. In addition, huge variations in oxygen isotope composition were found correlating with distance into the object. The chemical and isotopical profiles observed in the fragment indicate postaccretionary metamorphism under the presence of a volatile phase.  相似文献   

Glacier Peak and mid-Lateglacial Katla cryptotephras in Scotland: potential new intercontinental and marine-terrestrial correlations     

Sean D. F. Pyne-O'Donnell  Britta J. L. Jensen 《第四纪科学杂志》2020,35(1-2):155-162

Using contiguous high resolution sampling methods, we report the detection of a Glacier Peak volcanic ash from North America in Lateglacial Interstadial lake sediments in western Scotland. It occurs in close proximity to the Icelandic Borrobol and Penifiler tephras, but is distinguishable by its rhyolitic major-element composition that is consistent with the earliest set G layer, one of a number of mid-Interstadial Glacier Peak eruptions dated between 13.71 and 13.41 cal ka bp. Another cryptotephra layer present in these same Interstadial sediments has a rhyolitic composition consistent with the Icelandic Katla source. However, it is in a stratigraphic position below the widespread mid-Lateglacial Stadial Vedde Ash from Katla, which is also present in these cores. The Katla layer is stratigraphically well defined, suggesting primary airfall, and is compositionally similar to a mid-Interstadial rhyolitic tephra reported from a North Atlantic marine sequence south of Iceland dated to ~13.6 ka. The detection of Glacier Peak G in the European tephrostratigraphy will permit direct high-precision correlation of mid-Interstadial palaeoenvironments between North American and European terrestrial sequences. Any correlation between the new Katla layer and similar marine layers remains provisional, though if verified would permit similar correlation between North Atlantic marine and European terrestrial records.  相似文献   

Informing policy to protect coastal coral reefs: Insight from a global review of reducing agricultural pollution to coastal ecosystems     

Frederieke J. Kroon  Britta Schaffelke  Rebecca Bartley 《Marine pollution bulletin》2014

The continuing degradation of coral reefs has serious consequences for the provision of ecosystem goods and services to local and regional communities. While climate change is considered the most serious risk to coral reefs, agricultural pollution threatens approximately 25% of the total global reef area with further increases in sediment and nutrient fluxes projected over the next 50 years. Here, we aim to inform coral reef management using insights learned from management examples that were successful in reducing agricultural pollution to coastal ecosystems. We identify multiple examples reporting reduced fluxes of sediment and nutrients at end-of-river, and associated declines in nutrient concentrations and algal biomass in receiving coastal waters. Based on the insights obtained, we recommend that future protection of coral reef ecosystems demands policy focused on desired ecosystem outcomes, targeted regulatory approaches, up-scaling of watershed management, and long-term maintenance of scientifically robust monitoring programs linked with adaptive management.  相似文献   

Field Studies on the Fate and Transport of Pharmaceutical Residues in Bank Filtration   总被引：5，自引：0，他引：5  

Thomas Heberer  y Mechlinski  Britta Fanck  rea Knappe  Gudrun Massmann  Asaf Pekdeger  Birgit Fritz 《Ground Water Monitoring & Remediation》2004,24(2):70-77

Bank filtration and artificial ground water recharge are important, effective, and cheap techniques for surface water treatment and removal of microbes, as well as inorganic, and some organic, contaminants. Nevertheless, physical, chemical, and biological processes of the removal of impurities are not understood sufficiently. A research project titled Natural and Artificial Systems for Recharge and Infiltration attempts to provide more clarity in the processes affecting the removal of these contaminants. The project focuses on the fate and transport of selected emerging contaminants during bank filtration at two transects in Berlin, Germany. Several detections of pharmaceutically active compounds (PhACs) in ground water samples from bank filtration sites in Germany led to furthering research on the removal of these compounds during bank filtration. In this study, six PhACs including the analgesic drugs diclofenac and propyphenazone, the antiepileptic drugs carbamazepine and primidone, and the drug metabolites clofibric acid and 1-acetyl-1-methyl-2-dimethyl-oxamoyl-2-phenylhydrazide were found to leach from the contaminated streams and lakes into the ground water. These compounds were also detected at low concentrations in receiving public supply wells. Bank filtration either decreased the concentrations by dilution (e.g., for carbamazepine and primidone) and partial removal (e.g., for diclofenac), or totally removed PhACs (e.g., bezafibrate, indomethacine, antibiotics, and estrogens). Several PhACs, such as carbamazepine and especially primidone, were readily transported during bank filtration. They are thought to be good indicators for evaluating whether surface water is impacted by contamination from municipal sewage effluent or whether contamination associated with sewage effluent can be transported into ground water at ground water recharge sites.  相似文献   

Technological capability and transfer for achieving South Africa's development goals     

Britta Rennkamp  Anya Boyd 《Climate Policy》2015,15(1):12-29

Technological capability and technology transfer both play important roles in achieving low-carbon development targets and the concepts of both have appeared in national development and climate policy debates. Yet, they differ. Improving capabilities and transfer mechanisms are two differing approaches to technological development. Technology transfer is associated with a key political dynamic within international climate policy, in that developing countries request support from industrialised countries. Whereas technological capability focuses on building internal capabilities and is often framed in the context of national industrial policy plans rather than relying on external support. We argue that technology development, a combination of these approaches, can contribute to South Africa's low-carbon development through innovation and technology-based mitigation actions that increase domestic technological capabilities. Technological capability needs to become a determinant of mitigation action to effectively contribute to achieving South Africa's low-carbon development goals. International technology transfer and cooperation should contribute to boosting domestic capabilities to advance technological development. Technology transfer based on pure sales will not contribute to achieving long-term low-carbon development goals.  相似文献   

Contaminants and habitat choice in the Baltic Sea: Behavioural experiments with the native species, Monoporeia affinis, and the invasive genus, Marenzelleria     

Ann-Kristin Eriksson Wiklund  Sandra VilhelmssonStig Johan Wiklund  Britta Eklund 《Estuarine, Coastal and Shelf Science》2009

The invasive polychaete genus, Marenzelleria and the native amphipod, Monoporeia affinis are food and habitat competitors in the Baltic Sea. Previous studies have shown that moderate densities of Marenzelleria can affect the behaviour of M. affinis. To examine the short-term interactive effects of interspecific habitat choice and environmental contaminants a series of habitat colonisation experiments were performed. The contaminants examined included harbor sediments and sediment spiked with the antifouling substances, Cu, Zn and Irgarol. Polychaetes and amphipods were exposed to contaminants in single-species and two-species experiments. In spiked-sediment experiments, M. affinis showed clear dose-dependent response. These experiments verified that behavioural response of M. affinis to different habitats is a sensitive method for testing toxicity under controlled conditions. In experiments with three different harbor sediments and reference sediment both species showed the lowest preference for the reference sediment. This sediment also had the lowest content of quality food, indicating that factors such as food quality and quantity may override the disturbing effects of contaminants in natural sediments. The presence of Marenzelleria spp. did not affect amphipod habitat choice, indicating no short-term effects, which implies that both species can co-exist provided sufficient food is available.  相似文献   

Chemical variations of sulfides and metal in enstatite chondrites—Introduction of a new classification scheme          下载免费PDF全文

Mona Weyrauch  Marian Horstmann  Addi Bischoff 《Meteoritics & planetary science》2018,53(3):394-415

In this study, the metal and sulfide compositions of 45 enstatite chondrites were analyzed to determine possible mineral-chemical trends correlated with the petrologic type. Data for 35 additional samples were taken from the literature. Considering the data from this huge number of different E chondrite samples (80 in total), none of the trends previously described in the literature could be clearly confirmed. Also, among the opaque phases of enstatite chondrites, no other “new” correlations between mineral chemistry and the petrologic type were found. However, major differences in the sulfide and metal chemistry became obvious. Specifically, a certain number of chondrites in the EH and the EL groups have Cr in troilite above 2 wt%, Fe in niningerite or alabandite above 20 wt%, and lack abundant daubréelite. Differences were also found for Ni concentrations in kamacite. Thus, we propose a system for classifying E chondrites by defining four major subgroups: EH_a, EL_a, EH_b, and EL_b. All subgroups show full petrologic sequences that are similar to each other. This observation, in combination with the differences in sulfide and metal chemistry, suggests an origin of the samples from different parent bodies. Considering the anomalous E chondrite samples that neither fit in the previous classification scheme nor in the new one described here, the samples investigated in this study require at least eight different parent bodies.  相似文献   

Operationalizing the Adaptation Fund: challenges in allocating funds to the vulnerable     

Britta Horstmann 《Climate Policy》2013,13(4):1086-1096

The Adaptation Fund of the Kyoto Protocol marks a change in the international climate change financing architecture due to its independence from official development assistance, direct access and the majority of developing countries in governance. A major goal of the Adaptation Fund is to finance concrete adaptation projects and programmes in developing countries that are particularly vulnerable to the effects of climate change. The presented analysis considers the results of operationalization of the fund between 2008 and 2010, and the role vulnerability had in the allocation of funds. The definition of ‘vulnerability’ remains broad and currently does not allow for a prioritization in the allocation of funds. Criteria like ‘level of vulnerability’ or ‘adaptive capacity’ still need to be specified. The possibilities for the Adaptation Fund Board to implement a vulnerability-oriented funding approach are limited by the legal basis of the Kyoto Protocol and the principle of a country-driven approach. The effective support of vulnerable communities primarily depends on the institutional capacities and the institutional arrangement at the national level and the quality of analysis the adaptation projects and programmes are based on.  相似文献   

Si‐bearing metal and niningerite in Almahata Sitta fine‐grained ureilites and insights into the diversity of metal on the ureilite parent body     

Marian Horstmann  Munir Humayun  Mario Fischer‐Gödde  Addi Bischoff  Mona Weyrauch 《Meteoritics & planetary science》2014,49(10):1948-1977

A detailed mineralogical and chemical study of Almahata Sitta fine‐grained ureilites (MS‐20, MS‐165, MS‐168) was performed to shed light on the origin of these lithologies and their sulfide and metal. The Almahata Sitta fine‐grained ureilites (silicates <30 μm grain size) show textural and chemical evidence for severe impact smelting as described for other fine‐grained ureilites. Highly reduced areas in Almahata Sitta fine‐grained ureilites show large (up to ～1 mm) Si‐bearing metal grains (up to ～4.5 wt% Si) and niningerite [Mg_>0.5,(Mn,Fe)_<0.5S] with some similarities to the mineralogy of enstatite (E) chondrites. Overall, metal grains show a large compositional variability in Ni and Si concentrations. Niningerite grains probably formed as a by‐product of smelting via sulfidation. The large Si‐Ni variation in fine‐grained ureilite metal could be the result of variable degrees of reduction during impact smelting, inherited from coarse‐grained ureilite precursors, or a combination of both. Large Si‐bearing metal grains probably formed via coalescence of existing and newly formed metal during impact smelting. Bulk and in situ siderophile trace element abundances indicate three distinct populations of (1) metal crystallized from partial melts in MS‐20, (2) metal resembling bulk chondritic compositions in MS‐165, and (3) residual metal in MS‐168. Almahata Sitta fine‐grained ureilites developed their distinctive mineralogy due to severe reduction during smelting. Despite the presence of E chondrite and ureilite stones in the Almahata Sitta fall, a mixing relation of E chondrites or their constituents and ureilite material in Almahata Sitta can be ruled out based on isotopic, textural, and mineral‐chemical reasons.  相似文献   

Phase-field study of grain boundary tracking behavior in crack-seal microstructures     

Kumar Ankit  Britta Nestler  Michael Selzer  Mathias Reichardt 《Contributions to Mineralogy and Petrology》2013,166(6):1709-1723

In order to address the growth of crystals in veins, a multiphase-field model is used to capture the dynamics of crystals precipitating from a super-saturated solution. To gain a detailed understanding of the polycrystal growth phenomena in veins, we investigate the influence of various boundary conditions on crystal growth. In particular, we analyze the formation of vein microstructures resulting from the free growth of crystals as well as crack-sealing processes. We define the crystal symmetry by considering the anisotropy in surface energy to simulate crystals with flat facets and sharp corners. The resulting growth competition of crystals with different orientations is studied to deduce a consistent orientation selection rule in the free-growth regime. Using crack-sealing simulations, we correlate the grain boundary tracking behavior depending on the relative rate of crack opening, opening trajectory, initial grain size, and wall roughness. Further, we illustrate how these parameters induce the microstructural transition between blocky (crystals growing anisotropically) to fibrous morphology (isotropic) and formation of grain boundaries. The phase-field simulations of crystals in the free-growth regime (in 2D and 3D) indicate that the growth or consumption of a crystal is dependent on the orientation difference with neighboring crystals. The crack-sealing simulation results (in 2D and 3D) reveal that crystals grow isotropically and grain boundaries track the opening trajectory if the wall roughness is high, opening increments are small, and crystals touch the wall before the next crack increment starts. Further, we find that within the complete crack-seal regime, anisotropy in surface energy results in the formation of curved/oscillating grain boundaries (instead of straight) when the crack-opening velocity is increased and wall roughness is not sufficiently high. Additionally, the overall capability of phase-field method to simulate large-scale polycrystal growth in veins (in 3D) is demonstrated enumerating the main advantages of adopting the novel approach.  相似文献