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41.
The role of microbial sulfate reduction on organic matter oxidation was studied quantitatively in temperate intertidal surface sediments of the German Wadden Sea (southern North Sea) on a seasonal base in the years 1998–2007. The sampling sites represent the range of sediments found in the back-barrier tidal area of Spiekeroog Island: sands, mixed and muddy flats. The correspondingly different contents in organic matter, metals, and porosities lead to significant differences in the activity of sulfate-reducing bacteria with volumetric sulfate reduction rates (SRR) in the top 15 cm of up to 1.4 μmol cm?3 day?1. Depth-integrated areal SRR ranged between 0.9 and 106 mmol m?2 day?1, with the highest values found in the mudflat sediments and lower rates measured in sands at the same time, demonstrating the impact of both temperature and organic matter load. According to a modeling approach for a 154-km2 large tidal area, about 39, 122, and 285 tons of sulfate are reduced per day, during winter, spring/autumn, and summer, respectively. Hence, the importance of areal benthic organic matter mineralization by microbial sulfate reduction increases during spring/autumn and summer by factors of about 2 and 7, respectively, when compared to winter time. The combined results correspond to an estimated benthic organic carbon mineralization rate via sulfate reduction of 78 g C m?2 year?1.  相似文献   
42.
Currently, the most widely accepted hypothesis to explain high As concentrations in Bangladesh groundwaters is that dissolved organic C (DOC) reduces solid Fe (hydr)oxides and mobilizes sorbed arsenate. The nature of the DOC and its release mechanism are still controversial. Based on weekly to biweekly sampling over the course of one monsoon cycle at six monitoring wells of different depths, it is proposed that storativity changes drive natural DOC release from clay–peat layers to the adjacent aquifers. With a decrease in hydraulic heads during the dry season, total mineralization and DOC concentrations increased. With the onset of the rainy season and an increase in hydraulic heads, release of clay–peat derived components stopped and vertical water displacement due to groundwater recharge from rainwater occurred, causing aquifer flushing and a decrease in total mineralization and DOC concentrations. Total As and DOC concentrations correlated over depth. However, at the depth of maximum concentrations, the As peak was observed during the rainy season. At present, the reason for this inverse seasonal trend between As and DOC is unclear. Higher mineralization or DOC concentrations could lead to increased As sorption or the increased arsenite release is a time-lag abiotic or microbial response to the DOC peak. The vulnerability of the Pleistocene aquifer towards increased As concentrations was found to be much higher than previously assumed. Though sorption capacities were determined to be higher than in the Holocene aquifer, probably due to intact Fe (hydr)oxides, long-term continuous As input from overlying clay and peat layers by the proposed seasonal storativity changes has led to increased aqueous As concentrations of 85 μg/L, considerably higher than drinking water standards. Until now, aquifer and especially aquitard and aquiclude hydraulics have not been considered sufficiently when attempting to explain As mobilization in Bangladesh.  相似文献   
43.
The level of Kluane Lake, the largest lake in Yukon Territory, was lower than at present during most of the Holocene. The lake rose rapidly in the late seventeenth century to a level 12 m above present, drowning forest and stranding driftwood on a conspicuous high-stand beach, remnants of which are preserved at the south end of the lake. Kluane Lake fell back to near its present level by the end of the eighteenth century and has fluctuated within a range of about 3 m over the last 50 yr. The primary control on historic fluctuations in lake level is the discharge of Slims River, the largest source of water to the lake. We use tree ring and radiocarbon ages, stratigraphy and sub-bottom acoustic data to evaluate two explanations for the dramatic changes in the level of Kluane Lake. Our data support the hypothesis of Hugh Bostock, who suggested in 1969 that the maximum Little Ice Age advance of Kaskawulsh Glacier deposited large amounts of sediment in the Slims River valley and established the present course of Slims River into Kluane Lake. Bostock argued that these events caused the lake to rise and eventually overflow to the north. The overflowing waters incised the Duke River fan at the north end of Kluane Lake and lowered the lake to its present level. This study highlights the potentially dramatic impacts of climate change on regional hydrology during the Little Ice Age in glacierised mountains.  相似文献   
44.
The history of hardwater lake Sacrower See (Brandenburg, northeastern Germany) was reconstructed back to the 17th century based on a multi-proxy study of five short sediment cores dated by varve chronology, 210Pb and 137Cs isotopes. We were able to distinguish three main phases: The lake was mesotrophic prior to the 1830s with an oxic hypolimnion. From the early 19th century on, δ13C of organic matter indicates that primary productivity starts to increase slowly. Between the 1830s and 1872, the lake went through a transition towards eutrophy. Low calcite contents in the homogeneous sediment are caused by dissolution connected to increasing primary productivity and growing importance of decomposition processes. After 1873, and accelerated since 1963, Sacrower See is characterised by growing nutrient input, and thus further increasing primary productivity. The lake is eutrophic, and decomposition of organic matter causes high oxygen consumption in the hypolimnion, which becomes regularly anoxic during thermal summer stratification. Biogenic varves are preserved in the sediment, characterised by layers of autochthonous, biochemically precipitated calcite crystals. In this study, we were able to demonstrate that Sacrower See is an example of exceptional slow increase of anthropogenically enhanced nutrient input, and of the imprint which these processes have on sediments of a hardwater lake.  相似文献   
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The thermotectonic evolution of the East Alpine Rhenodanubian flysch zone (RDFZ) and the collisional history along the orogenic front is reconstructed using apatite fission-track (FT) thermochronology. The apatite FT data provides evidence for a burial depth of at least 6 km for the samples, which were totally reset. Burial was not deeper than 11 km, since the zircon fission-track system was not reset. The RDFZ represents an accretionary wedge with a complex burial and cooling history due to successive and differential accretion and exhumation. The sedimentary sequences were deposited along a convergent margin, where accretion started before Maastrichtian and lasted until Miocene. Accretion propagated from a central area (Salzburg-Ybbsitz) both to the west and to the east. In the west, accretion lasted from Middle Eocene to Early Oligocene, reflecting underplating of the RDFZ by the European continental margin sediments. In the east, where three nappes (Greifenstein, Kahlenberg and Laab nappes) can be distinguished, the exhumation started between Late Oligocene and Early Miocene. The Kahlenberg and Laab nappes show total resetting of the apatite FT ages, while in the Greifenstein nappe there is only partial resetting. According to a new paleogeographic reconstruction, the Kahlenberg and Laab nappes were placed on top of the Greifenstein nappe by an out-of-sequence thrust.  相似文献   
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Mobile jack-up drilling rigs are deployed at many locations during their service life. This necessitates retrieval of the platform’s legs and spudcan footings before the rig move. In soft soils, where the spudcans embed deeply, the extraction process can be difficult, time consuming and therefore costly. Water jetting systems, devised to ease spudcan extraction, are a common feature on modern jack-up units. However, their effectiveness in reducing the pull-out load required is questioned by the offshore industry. To investigate their efficiency, centrifuge experiments of a reduced scale spudcan model with jets have been performed at the University of Western Australia. The footing was extracted from penetrations of up to 1.5 diameters in normally consolidated clay. Similar to spudcan extraction in the field, these were carried out under load control, applying a constant extraction force. Both influences of pull-out load magnitude and jetting flow rate were investigated. The study demonstrates that jetting is efficient in facilitating spudcan extraction, as it reduces the required uplift load. Practical guidance is provided in applying the results to field conditions.  相似文献   
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