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91.
Evidence of long-term metal pollution in the Fal Estuary is provided by analyses of Cu in oyster (Ostrea edulis) communities extending over more than 120 yr and by analyses of Cu and Zn in sediments dating back to 1921. Indications are that levels of Cu pollution from mining have declined very slowly but that Zn pollution has not. In Restronguet Creek, the most heavily polluted area, metal levels in waters and sediments are elevated by orders of magnitude. The invertebrate fauna of the creek is limited, but far richer than might be predicted from laboratory toxicity data. The cockleCerastoderma edule exemplifies organisms that are excluded from the creek owing to the toxicity of dissolved Cu, whereasOstrea edulis, by virtue of its innate tolerance to Cu and Zn, grown in the Iower reaches. On the other hand, the population of the ragwornNereis diversicolor, which penetrates into the most heavily polluted areas, is demonstrably far more tolerant of Cu and Zn than population from clean areas and appears to be a tolerant strain. To a considerable degree, therefore, the distribution of species is dependent not only on the innate ability of some species to tolerate Cu and Zn, but on the capacities of other populations to develop metal resistance and thereby maintain their original range of distribution. Present-day problems in the Fal Estuary appear to stem not only from mining wastes but also from the increased usage of tributyltins in antifouling paints. In the dogwhelkNucella lapillus, the incidence of imposex (the appearance of a penis and other male characters in females) is virtually 100% at sites along the English Channel coast of southwest England. The degree of imposex is related to the body concentration of hexane-extractable organotin, which includes both tributyltin and dibutyltin fractions. The highest degree of imposex, where the female penis approaches that of the male in size, occurs in the Fal Estuary; also, in some males the penis becomes deformed. Populations of dogwhelks have declined dramatically in this estuary, and are also characterised by the presence of relatively fewer females and by the absence of juveniles and egg capsules. Reproductive failure in females is now known to be caused by blockage of the pallial oviduct during the development of imposex. 相似文献
92.
John B. Reid Jr. Eric Steig Wilfred B. Bryan 《Contributions to Mineralogy and Petrology》1989,101(3):318-325
Basalt petrologists disagree as to whether the commonly used projection, forsterite-diopside-silica, in the system CMAS (CaO-MgO-Al2O3-SiO2), can adequately resolve differences in basaltic glass compositions for purposes of petrogenetic modelling. Here, we suggest than an analogous plot, the aluminium-factor diagram (ALFE) of Nesbitt and Cramer (1981), has greater diagnostic value than Fo-Di-Sil. A plot of molar (Al2O2-CaO-Na2O-K2O)/(FeO + MgO) vs FeO/(FeO + MgO), it produces more coherent patterns both for experimental basalt glasses, and for natural lavas. It is, like Fo-Di-Sil, a projection through plagioclase, but has the advantage that it monitors changes in Fe/(Fe + Mg) in melts and associated crystalline phases, and is particularly useful in assessing the timing of clinopyroxene crystallization in a suite of lavas. The diagram owes its greater resolving power to the fact that the computation of its coordinates is less sensitive to analytical uncertainty than for Fo-Di-Sil. In the latter diagram, normative quartz is calculated as a residual and thus manifests the uncertainties in all the major elements. 相似文献
93.
Henry J.B. Dick Robert L. Fisher Wilfred B. Bryan 《Earth and Planetary Science Letters》1984,69(1):88-106
Modal analyses of 273 different peridotites representing 43 dredge stations in the Atlantic, Caribbean, and Indian Oceans define three separate melting trends. Peridotites dredged in the vicinity of “mantle plumes” or hot spots have the most depleted compositions in terms of basaltic components, while peridotites dredged at locations removed from such regions are systematically less depleted. The modal data correlate well with mineral compositions, with the peridotites most depleted in pyroxene also having the most refractory mineral compositions. This demonstrates that they are the probable residues of variable degrees of mantle melting. Further, there is a good correlation between the modal compositions of the peridotites and the major element composition of spatially associated dredged basalts. This demonstrates for the first time that the two must be directly related, as is frequently postulated. The high degree of depletion of the peridotites in basaltic major element components in the vicinity of some documented mantle plumes provides direct evidence for a thermal anomaly in such regions—justifying their frequent designation as “hot spots”. The high incompatible element concentrations in these “plume” basalts, however, are contrary to what is expected for such high degrees of melting, and thus require either selective contributions from locally more abundant enriched veins and/or contamination by a volatile-rich metasomatic front from depth. 相似文献
94.
Eugene E. Epstein Bryan H. Andrew Frank H. Briggs Bruce M. Jakosky Frank D. Palluconi 《Icarus》1983,56(3):465-475
Measurements at 3.5 mm of the disk-average brightness temperature of Mars during the 1978 opposition can be represented by (The errors cited are from the internal scatter; the estimated absolute calibration uncertainty is 3%.) This longitudinal variation must be taken into account if Mars is to be used as a calibration source at millimeter wavelengths. The total range of the 3.5-mm variation is three to four times larger than both the 2.8-cm and 20-μm variations. This unexpected result can possibly be explained by subsurface scattering from rocks ?1.5-cm radius. 相似文献
95.
Al(III) and Fe(III) binding by humic substances in freshwaters, and implications for trace metal speciation 总被引:2,自引:0,他引:2
Edward Tipping Carlos Rey-Castro Stephen E Bryan John Hamilton-Taylor 《Geochimica et cosmochimica acta》2002,66(18):3211-3224
Published experimental data for Al(III) and Fe(III) binding by fulvic and humic acids can be explained approximately by the Humic Ion-Binding Model VI. The model is based on conventional equilibrium reactions involving protons, metal aquo ions and their first hydrolysis products, and binding sites ranging from abundant ones of low affinity, to rare ones of high affinity, common to all metals. The model can also account for laboratory competition data involving Al(III), Fe(III) and trace elements, supporting the assumption of common binding sites. Field speciation data (116 examples) for Al in acid-to-neutral waters can be accounted for, assuming that 60-70 % (depending upon competition by iron, and the chosen fulvic acid : humic acid ratio) of the dissolved organic carbon (DOC) is due to humic substances, the rest being considered inert with respect to ion binding. After adjustment of the model parameter characterizing binding affinity within acceptable limits, and with the assumption of equilibrium with a relatively soluble form of Fe(OH)3, the model can simulate the results of studies of two freshwater samples, in which concentrations of organically complexed Fe were estimated by kinetic analysis.The model was used to examine the pH dependence of Al and Fe binding by dissolved organic matter (DOM) in freshwaters, by simulating the titration with Ca(OH)2 of an initially acid solution, in equilibrium with solid-phase Al(OH)3 and Fe(OH)3. For the conditions considered, Al, which is present at higher free concentrations than Fe(III), competes significantly for the binding of Fe(III), whereas Fe(III) has little effect on Al binding. The principal form of Al simulated to be bound at low pH is Al3+, AlOH2+ being dominant at pH >6; the principal bound form of Fe(III) is FeOH2+ at all pH values in the range 4-9. Simulations suggest that, in freshwaters, both Al and Fe(III) compete significantly with trace metals (Cu, Zn) for binding by natural organic matter over a wide pH range (4-9). The competition effects are especially strong for a high-affinity trace metal such as Cu, present at low total concentrations (∼1 nM). As a result of these competition effects, high-affinity sites in humic matter may be less important for trace metal binding in the field than they are in laboratory systems involving humic matter that has been treated to remove associated metals. 相似文献
96.
Some exciting developments have been made recently, in the field of digital image rectification, which are of interest to both the photogrammetric specialist and non-specialist. This paper outlines the technical processes involved in generating digitally rectified images, as well as raising some of the issues that are becoming apparent when applying this modern technology to archaeological and architectural presentation. 相似文献
97.
Lauren D. Somers Jeffrey M. McKenzie Samuel C. Zipper Bryan G. Mark Pablo Lagos Michel Baraer 《水文研究》2018,32(3):318-331
As Andean glaciers rapidly retreat due to climate change, the balance of groundwater and glacial meltwater contributions to stream discharge in tropical, proglacial watersheds will change, potentially increasing vulnerability of water resources. The Shullcas River Watershed, near Huancayo, Peru, is fed only partly by the rapidly receding Huaytapallana glaciers (<20% of dry season flow). To potentially increase recharge and therefore increase groundwater derived baseflow, the government and not‐for‐profit organizations have installed trenches along large swaths of hillslope in the Shullcas Watershed. Our study focuses on a nonglacierized subcatchment of the Shullcas River Watershed and has 2 objectives: (a) create a model of the Shullcas groundwater system and assess the controls on stream discharge and (b) investigate the impact of the infiltration trenches on recharge and baseflow. We first collected hydrologic data from the field including a year‐long hydrograph (2015–2016), meteorological data (2011–2016), and infiltration measurements. We use a recharge model to evaluate the impact of trenched hillslopes on infiltration and runoff processes. Finally, we use a 3‐dimensional groundwater model, calibrated to the measured dry season baseflow, to determine the impact of trenching on the catchment. Simulations show that trenched hillslopes receive approximately 3.5% more recharge, relative to precipitation, compared with unaltered hillslopes. The groundwater model indicates that because the groundwater flow system is fast and shallow, incorporating trenched hillslopes (~2% of study subcatchment area) only slightly increases baseflow in the dry season. Furthermore, the location of trenching is an important consideration: Trenching higher in the catchment (further from the river) and in flatter terrain provides more baseflow during the dry season. The results of this study may have important implications for Andean landscape management and water resources. 相似文献
98.
99.
Bryan A. P. Kent Shahin E. Dashtgard Chuqiao Huang James A. MacEachern H. Dan Gibson Gwyneth Cathyl-Huhn 《Basin Research》2020,32(1):163-185
The lower Nanaimo Group was deposited in the (forearc) Georgia Basin, Canada and records the basin's initiation and early depositional evolution. Nanaimo Group strata are subdivided into 11 lithostratigraphic units, which are identified based on lithology, paleontology, texture and position relative to both the basal nonconformity and to each other. Significant topography on the basal nonconformity, however, has resulted in assignment of lithostratigraphic units that are not time correlative, and hence, cannot reliably be used to accurately reconstruct basin evolution. Herein, we present a sequence stratigraphic framework for lower Nanaimo Group strata in the Comox Sub-Basin (northern Georgia Basin) that integrates both facies analysis and maximum depositional ages (MDAs) derived from detrital zircon. This stratigraphic framework is used to define significant sub-basin-wide surfaces that bound depositional units and record the evolution of the basin during its early stages of development. Seven distinct depositional phases are identified in the lower 700 m of the lower Nanaimo Group. Depositional phases are separated by marine flooding surfaces, regressive surfaces, or disconformities. The overall stratigraphy reflects net transgression manifested as an upwards transition from braided fluvial conglomerates to marine mudstones. Transgression was interrupted by periods of shoreline progradation, and both facies analysis and MDAs reveal a disconformity in the lowermost part of the Nanaimo Group in the Comox Sub-Basin. Stratigraphic reconstruction of the Comox Sub-Basin reveals two dominant depocenters (along depositional strike) for coarse clastics (sandstones and conglomerates) during early development of the Georgia Basin. The development and position of these depocenters is attributed to subduction/tectonism driving both subsidence in the north-northwest and uplift in the central Comox Sub-Basin. Our work confirms that in its earliest stages of development, the Georgia Basin evolved from an underfilled, ridged forearc basin that experienced slow and stepwise drowning to a shoal-water ridged forearc basin that experienced rapid subsidence. We also propose that the Georgia Basin is a reasonable analogue for ridged forearc basins globally, as many ridged forearcs record similar depositional histories during their early evolution. 相似文献
100.
Late Holocene chronology,origin, and evolution of the St. Bernard Shoals,Northern Gulf of Mexico,USA
Several shore-parallel marine sand bodies lie on the Louisiana continental shelf. They are Trinity Shoal, Ship Shoal, Outer
Shoal, and the St. Bernard Shoals. These shoals mark the submerged positions of ancient shorelines associated with abandoned
deltas. Three of these shoals are single elongate deposits. The fourth shoal, the St. Bernard Shoals, consists of a group
of discrete sand bodies ranging in size from 44 to 0.05 km2, 25 km southeast of the Chandeleur Islands in 15–18 m of water. The St. Bernard Shoals are stratigraphically above the St.
Bernard delta complex, which was active 2,500–1,800 years b.p. Understanding the evolution of the St. Bernard Shoals is necessary to reconstruct the Holocene chronology of the St. Bernard
delta complex and the eastern Louisiana continental shelf. For this study, 47 vibracores and 400 km of shallow seismic reflection
data collected in 1987 across the Louisiana shelf were analyzed. In June 2008, 384 km of higher-resolution seismic reflection
data were acquired across the study area and appended to the preexisting datasets. Vibracores were integrated with seismic
profiles to identify facies and their regional distribution. Our results demonstrate that the deltaic package stratigraphically
below the St. Bernard Shoals is chronologically younger than the northern distributaries, but derived from the same trunk
distributary channel (Bayou la Loutre). The river eventually bypassed the northern distributaries, and began to deposit sediment
further onto the continental shelf. After abandonment, the overextended delta lobe was rapidly transgressed, creating a transgressive
shoreline that eventually coalesced with earlier shorelines in the region to form the Chandeleur Islands. The St. Bernard
Shoals formed by the reworking of the relict distributary deposits exposed on the inner to mid shelf during and subsequent
to shoreface ravinement. 相似文献