Geochemistry of organic matter and elements of black shale during weathering in Northern Guizhou,Southwestern China: Their mobilization and inter-connection     

Xuan Tang  Jinchuan Zhang  Yang Liu  Chao Yang  Qian Chen  Wei Dang  Panwang Zhao 《Chemie der Erde / Geochemistry》2018,78(1):140-151

Different from previous studies on effect of weathering upon geochemical variation along a single weathered profile, this paper provides a new methodology validated by comparing a weathered outcrop samples and their stratigraphic counterpart un-weathered core samples in a nearby shallow borehole. This outcrop and borehole penetrated the Ordovician-Silurian Wufeng–Longmaxi shales, located in the same anticline structure in the northern part of Guizhou Province, Southern China. The mineral composition, major, trace and rare earth elements (REEs) composition and Rock-Eval parameters of outcrop and core samples were analyzed and compared. Organic matter (OM) was observed in the microscope and extracted for elements analysis. The results show that short-term weathering still has significant influence on OM, mineral and elemental composition of black shales. The elements composition shows the outcrop profile was moderately weathered. The REEs compositions do not alter much during weathering process and the REEs composition and their relative ratios still are valid for rock origin determination. The OM, mainly composed by graptolite and bitumen, even entering the highly-over thermal maturity, is still sensitive to the weathering with a systematic loss 30–50% of TOC along the outcrop profile, which suggests that the OM consumption is predominantly controlled by weathering duration and the distance from the weathering surface. In turn, OM has significant influence on the trace elements transportation behavior during weathering. Some trace elements associated with the OM such as V, Cr, Th, U, Ni and Co, change significantly in their absolute concentration during weathering, but their relative ratios do not necessarily change too much and might be still reliable proxies for paleo-environmental determination. The mobility of shale minerals during weathering is in the following order: plagioclase?>?potassium feldspar and dolomite >pyrite and OM. Short-term weathering can also result in considerable transportation of elements and significant variation of minerals content in black shale, which may pose potentially high environmental and engineering risk in the regions rich in black shale.  相似文献   

Palaeoproterozoic granitic magmatism in the northern segment of the Jiao-Liao-Ji Belt: implications for orogenesis along the Eastern Block of the North China Craton     

Chao Li  Zhuang Li  Chuan Yang 《International Geology Review》2018,60(2):217-241

As the northern segment of the Jiao-Liao-Ji Belt (JLJB), the Palaeoproterozoic Liaoji Belt is a key region for deciphering the formation and evolution of the North China Craton (NCC). In this study, we present the geochronology, geochemical, and isotopic studies on the monzogranitic gneiss, which is one of the major lithotectonic elements of the Liaoji Belt. LA-ICP-MS zircon U–Pb dating reveals that the studied monzogranitic gneisses were formed in the period of 2213–2178 Ma. They are in tectonic contact with the Palaeoproterozoic volcano-sedimentary rocks in the field. The monzogranitic gneisses belong to the high-K calc-alkaline series, and are metaluminous to peraluminous. They have 10,000 Ga/Al ratios of 2.63–3.14 with an average of 2.90, and are thus classified as aluminous A-type granites. Their ε_Nd(t) values vary from ?3.4 to +2.5, indicating heterogeneous source region. The monzogranitic gneisses are characterized by enrichment in LREE and LILE (e.g. Rb, Ba, Th, and K) and depletion in HREE and HFSE (such as Nb, Ta, and Ti), and are typical to magmatism in active continental margins formed in a subduction-related tectonic setting. Taking into account their A-type affinity and regional geological data, we suggest that the monzogranitic gneisses were most probably generated in a local extensional back-arc environment during subduction.  相似文献   

Os水吸收液ICP-MS测量信号强度衰减原因研究     

周利敏  李超  李欣尉  赵鸿  屈文俊  杜安道 《岩矿测试》2018,37(4):431-438

蒸馏法能从样品中有效分离出OsO_4,吸收液直接用于ICP-MS测定,是辉钼矿Re-Os定年的关键技术环节。但实验发现,长时间放置的吸收液中Os信号强度显著降低。根据OsO_4化学性质推测原因在于一是挥发使吸收液Os含量减少,二是还原使+8价Os变成低价态,气态比例降低,若雾化效率不变,进入质谱仪的Os减少,两者都会导致信号降低,但具体影响情况不明,需深入研究。本文利用辉钼矿标准物质制备不同放置时间、酸度和温度的吸收液,对比上述条件对ICP-MS信号强度的影响。实验时将残余吸收液与稀释剂、氧化剂封入Carius管加热蒸馏,测定Os含量。结果表明:吸收液放置时间越长,酸度越低,温度越高,信号降幅越大,幅度达到3.2%~68.6%。室温下放置相同时间,低酸度吸收液的Os保存率高于高酸度吸收液,但Os信号强度低于后者,证明了挥发和还原共同导致信号衰减,且还原是主导原因。本文提出,冷冻(-18℃)可抑制OsO_4挥发,提高酸度(约3.5 mol/L)可减弱OsO_4还原,两者结合抑制信号衰减,提高了蒸馏法的灵活性和适用性。  相似文献   

青藏高原北缘前寒武纪地质演化：进展与讨论   总被引：1，自引：0，他引：1       下载免费PDF全文

王超刘良  李荣社 《地质科学》2018,53(3):972-999

青藏高原北缘前寒武纪块体主要出露于塔里木盆地南缘的铁克里克和阿尔金、祁连山及柴达木盆地周缘等地区。这些古老块体分布于相对年轻的古生代秦祁昆造山带之中,大多经历了古生代造山事件的改造叠加。近10年来,对该地区前寒武纪地层时代格架、物质组成和构造属性研究取得了许多进展：1）揭示铁克里克、北阿尔金、全吉和阿拉善地块具有相似的2.5～2.2 Ga、2.1～1.7 Ga的基底演化和1.7 Ga之后的盖层沉积记录,反映塔里木克拉通、全吉地块和华北克拉通在Columbia 超大陆中具有相关和相似性。2）一系列地层时代被重新厘定,为建立新的前寒武纪地层划分方案提供了依据;3）厘定出铁克里克新元古代裂谷火山—沉积盆地,其可以与华北克拉通南缘1 000～830 Ma的裂解事件对比,它们在新元古代早期可能构成同一个克拉通裂解边缘;4）在南阿尔金与祁连、柴达木等地块识别出性质相似的新元古代岩浆作用和变质作用,它们可能共同代表一个新元古代早期活动大陆边缘的构造杂岩,为古生代汇聚、增生于塔里木克拉通或华北克拉通南缘的外来地块,存在于秦祁昆造山带之中。目前关于青藏高原北缘前寒武纪块体的物质组成、时代格架、构造属性和古环境变化研究还存在许多问题,仍需要开展进一步的大量工作。  相似文献   

华北地台北缘集宁地区古元古代片麻状石榴花岗岩的深熔成因及地质意义   总被引：3，自引：3，他引：0  

石强  董晓杰  徐仲元  关庆彬  李鹏川  张超  崔芳华 《岩石学报》2018,34(9):2754-2772

本文对华北克拉通北缘集宁地区空间上密切共生的片麻状石榴花岗岩和孔兹岩系富铝片麻岩的岩相学、地球化学及年代学特征进行了对比研究。SHRIMP锆石U-Pb定年方面,在富铝片麻岩中获得了1910±10Ma和1839±13Ma变质锆石年龄,在片麻状石榴花岗岩中获得了1919±17Ma的变质重结晶锆石年龄。在石榴花岗岩的石榴石包裹体中识别出与富铝片麻岩相对应的进变质阶段(M1)和峰期阶段(M2)的矿物组合,由此确认富铝片麻岩的变质作用和导致石榴花岗岩形成的深熔作用是同一构造热事件的产物。通过对二者变质作用演化及特征变质矿物的对比,认为深熔作用主要发生在峰期后等温降压阶段(M3),石榴花岗岩中的石榴石为深熔作用过程中的残留矿物相或转熔矿物相,而石榴花岗岩则是混合有大量残留矿物相的熔体结晶的产物。对片麻状石榴花岗岩和富铝片麻岩的地球化学组成特征进行了对比分析,片麻状石榴花岗岩既有一定的继承性,又有十分明显的变异性。变异性表现为:1)石榴花岗岩主量和微量元素含量分布极不均匀,微量元素含量普遍低于源岩(Cs、Rb、Th、U、Nb、Ta、Zr、Hf等);2)大离子亲石元素Cs和生热元素U、Th亏损明显,Sr相对富集;3)高场强元素Nb、Ta、P、Ti的明显亏损;4)铕异常变化大,存在铕富集型、铕平坦型和铕亏损型共存的稀土配分曲线的岩石,这是深熔成因石榴花岗岩最突出的表现,也可能是原地-半原地深熔花岗岩的主要地球化学标志。综合区域上的地质资料,认为深熔作用与碰撞后伸展构造背景下基性岩浆底侵事件有关。  相似文献   

南阿尔金泥盆纪中基性杂岩体的成因及其地质意义研究     

张魁  刘良  王超  康磊  盖永升  廖小莹  马拓  赵国军 《岩石学报》2018,34(8):2481-2500

出露于南阿尔金西段的塔什萨依辉长岩和闪长岩及其内花岗质细脉是古生代多期岩浆活动的产物,它们构成了南阿尔金俯冲碰撞杂岩带的一部分,是深入探讨该地区构造演化过程的良好材料。本文通过对这些地质体野外地质特征、岩石学、地球化学特征、锆石U-Pb年代学和锆石Hf同位素特征的系统研究,以期确定其形成时代、源区性质和岩石成因,为深入探讨南阿尔金俯冲碰撞杂岩带的演化过程提供进一步约束。本文研究表明:辉长岩和闪长岩具相对较高的SiO_2含量(50.4%~53.5%)和Mg#(57~80),低的K_2O/Na_2O比值(0.17~0.67),为钙碱性系列岩石;辉长岩的∑REE偏低(36.9×10~(-6)~83.1×10~(-6)),Eu正异常(δEu=1.17~1.85);闪长岩∑REE稍高(182×10~(-6)~190×10~(-6)),Eu负异常(δEu=0.85~0.86);二者相对富集LREE和LILE,亏损HFSE。其主量元素特征、微量元素(高Nb、Zr含量,低Zr/Y比值)、锆石Hf同位素和Sr-Nd同位素组成表明二者应为大陆板内伸展背景下软流圈交代的岩石圈地幔部分熔融的产物,并在其岩浆演化过程中经历了地壳混染和分离结晶作用。花岗质细脉具高的Si O2含量(72.4%～75.5%)和K_2O/Na_2O比值(2.33～2.56),属于钾玄岩系列岩石;与闪长岩相比,两者微量元素蛛网图相似,但花岗质细脉轻重稀土分馏程度较大,Eu负异常(δEu=0.55～0.61)和P、Ti的亏损更加显著。锆石U-Pb定年结果显示,辉长岩形成时代约为400～420Ma;闪长岩和其内花岗质细脉的形成时代基本一致,约为400Ma,并具有相似的锆石Hf同位素组成和Sr-Nd同位素组成,结合地球化学特征及野外产状,推测花岗质细脉为闪长岩分异的产物。结合南阿尔金区域地质背景综合分析,塔什萨依辉长岩和闪长岩起源于造山后伸展背景下软流圈交代的岩石圈地幔的部分熔融,并经历了地壳混染和分离结晶作用;而闪长岩进一步分异形成花岗质细脉,并在其形成过程中可能伴随少量壳源熔融物质的加入。  相似文献   

A model for the representation of emergency cases     

Chao Zhang  Jiansong Wu  Chao Huang  Bo Jiang 《Natural Hazards》2018,90(1):337-348

The aim of this paper is to propose a location model of earthquake emergency service depot on the basis of hybrid multi-attribute decision-making method. The advantage of the proposed method is that practical mixed uncertainty of location decision information is considered, and the corresponding factors that affect the location of transfer stations are contained. To solve the location problem, a hybrid multi-attribute decision procedure without information transformation is developed. Besides, a novel weighting method and aggregation process is given. Finally, a numerical example is provided to show the feasibility and validity of the proposed method.  相似文献   

TLS技术在环境地质灾害监测中的应用进展   总被引：2，自引：1，他引：1  

杜超  赵进  任宪友  张亮  庄艳华 《测绘科学》2018,(6):65-71,105

针对地面三维激光扫描技术在环境地质灾害监测中的应用问题,该文在系统介绍此技术关键指标和数据处理的基础上,从滑坡监测、土壤侵蚀监测、敏感地貌微变形监测和水灾害边界追踪4个方面,详细介绍了该技术在环境地质灾害监测领域的应用历史和现状,其研究热点包括该技术在应用中的适宜性评价、监测精度评价、滤波算法的开发及灾害发生趋势预判等方面。另外,应用中高植被覆盖度和降雨天气的干扰问题可通过继续优化软硬件并加强与其他技术联合应用予以弥补。  相似文献   

序列蒙特卡洛算法的数字地图线状特征跟踪模型     

丛超  米曽真 《测绘科学》2018,(5):5-12,17

针对数字地图中的线状特征,如道路、河流的提取问题,该文提出一种基于序列蒙特卡洛的特征提取算法。算法利用粒子滤波方法与贝叶斯模型的建模思路,描述数字地图道路的状态及其观测估计方法;在此基础上,讨论跟踪过程中的模拟退火处理以及粒子聚类分析;最后,将跟踪模型应用在数字地图的特征提取中。实验表明,与传统的数字栅格地图道路提取算法以及基于其他粒子滤波的算法相比较,基于跟踪模型的算法具有较强的鲁棒性以及精度,同时能够很好地处理扫描栅格地图中缺失的道路信息提取。  相似文献   

一种盾构施工引起的地面沉降预测方法   总被引：1，自引：0，他引：1  

周爱红  倪莹莹  尹超  孙武 《测绘科学》2018,(3):167-172

针对盾构施工引起的地面沉降的影响因素众多、关系错综复杂,常规数学模型难以准确预测沉降量的问题,该文提出了采用主成分分析法和粒子群优化的支持向量机方法来建立预测模型。并结合工程实例将预测结果与常用的多元线性回归模型和基于Levenberg-Marquardt算法改进的BP神经网络模型(LM-BP)的预测结果做了比较。结果表明:PCA-PSO-SVM的预测结果精度较多元线性回归模型和LM-BP神经网络有很大的提高,证明了该研究方法具有一定的理论意义和参考价值。  相似文献