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941.
An in‐house fully three‐dimensional general‐purpose finite element model is applied to solve the hydrodynamic structure in a periodic Kinoshita‐generated meandering channel. The numerical model solves the incompressible Reynolds‐averaged Navier–Stokes equations for mass and momentum, while solving the k ? ε equations for turbulence. The free surface is described by the rigid‐lid approximation (using measured water surface data) for flat (smooth‐bed) and self‐formed (rough‐bed) conditions. The model results are compared against experimental measurements in the ‘Kinoshita channel’, where three‐dimensional flow velocities and turbulence parameters were measured. This validation was carried out for the upstream‐valley meander bend orientation under smooth (flat bed) conditions. After validation, several simulations were carried out to predict the hydrodynamics in conditions where either it was not possible to perform measurements (e.g. applicability of the laboratory acoustic instruments) and to extrapolate the model to other planform configurations. For the flat smooth‐bed case, a symmetric (no skewness) planform configuration was modeled and compared to the upstream‐skewed case. For the self‐formed rough‐bed case, prediction of the hydrodynamics during the progression of bedforms was performed. It appears that the presence of bedforms on a bend has the following effects: (i) the natural secondary flow of the bend is disrupted by the presence of the bedforms, thus depending on the location of the dune, secondary flows might differ completely from the traditional orientation; (ii) an increment on both the bed and bank shear stresses is induced, having as much as 50% more fluvial erosion, and thus a potential increment on the migration rate of the bend. Implications on sediment transport and bend morphodynamics are also discussed in the paper. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
942.
This article summarises activities and preliminary results of the International Programme on Landslides Project no. 179 “Database of glacial lake outburst floods (GLOFs)”. This project is planned for 3 years (2013–2015); the main objectives of the first year are (1) to create an online database and (2) to select collaborating partners. A survey of existing and relevant documents, information and organisations has been initiated along with the creation of a website (www.glofs-database.org) and the establishment of international collaboration. The first preliminary results show regional differences in various attributes of GLOF events (e.g. triggers, chronological distribution). These differences should be taken into consideration in regionally focused methods of hazard assessment, mitigation and consequently risk management.  相似文献   
943.
Nitrate (NO3 ?) reduction processes are important for depleting the NO3 ? load from agricultural source areas before the discharge water reaches surface waters or groundwater aquifers. In this study, we experimentally demonstrate the co-occurrence of microbial iron sulfide oxidation by NO3 ? (MISON) and other NO3 ?-depleting processes in a range of contrasting sediment types: sandy groundwater aquifer, non-managed minerotrophic freshwater peat and two brackish muddy sediments. Approximately 1/3 of the net NO3 ? reduction was caused by MISON in three of the four environments despite the presence of organic carbon in the sediment. An apparent salinity limitation to MISON was observed in the most brackish environment. Addition of high surface area synthetically precipitated iron sulfide (FeS x ) to the aquifer sediment with the lowest natural FeS x reactivity increased both the relative fraction of NO3 ? reduction linked to MISON from approximately 30–100 % and the absolute rates by a factor of 17, showing that the potential for MISON-related NO3 ? reduction is environmentally significant and rate limited by the availability of reactive FeS x .  相似文献   
944.
The surface sediments of two mud mounds (“Mound 11” and “Mound 12”) offshore southwest Costa Rica contain abundant authigenic carbonate concretions dominated by high-Mg calcite (14–20 mol-% MgCO3). Pore fluid geochemical profiles (sulfate, sulfide, methane, alkalinity, Ca and Mg) indicate recent carbonate precipitation within the zone of anaerobic oxidation of methane (AOM) at variable depths. The current location of the authigenic carbonate concretions is, however, not related to the present location of the AOM zone, suggesting mineral precipitation under past geochemical conditions as well as changes in the flow rates of upward migrating fluids. Stable oxygen and carbon isotope analysis of authigenic carbonate concretions yielded δ18Ocarbonate values ranging between 34.0 and 37.7 ‰ Vienna standard mean ocean water (VSMOW) and δ13Ccarbonate values from ?52.2 to ?14.2 ‰ Vienna Pee Dee belemnite (VPDB). Assuming that no temperature changes occurred during mineral formation, the authigenic carbonate concretions have been formed at in situ temperature of 4–5 °C. The δ18Ocarbonate values suggest mineral formation from seawater-derived pore fluid (δ18Oporefluid = 0 ‰ VSMOW) for Mound 12 carbonate concretions but also the presence of an emanating diagenetic fluid (δ18Oporefluid ≈5 ‰) in Mound 11. A positive correlation between δ13Ccarbonate and δ18Ocarbonate is observed, indicating the admixing of two different sources of dissolved carbon and oxygen in the sediments of the two mounds. The carbon of these sources are (1) marine bicarbonate (δ13Cporefluid ≈0 ‰) and (2) bicarbonate which formed during the AOM (δ13Cporefluid ≈?70 ‰). Furthermore, the δ18Oporefluid composition, with values up to +4.7 ‰ Vienna standard mean ocean water (VSMOW), is interpreted to be affected by the presence of emanating, freshened and boron-enriched fluids. Earlier, it has been shown that the origin of 18O-enriched fluids are deep diagenetic processes as it was indicated by the presence of methane with thermogenic signature (δ13CCH4 = ?38 ‰). A combination of present geochemical data with geophysical observations indicates that Mounds 11 and 12 represent a single fluid system interconnected by deep-seated fault(s).  相似文献   
945.
Seafloor methane emission from the Quepos Slide on the submarine segment of the Costa Rica fore-arc margin was estimated by extrapolating flux measurements from individual seeps to the total area covered by bacterial mats. This approach is based on the combination of detailed mapping to determine the abundance of seeps and the application of a numerical model to estimate the amount of benthic methane fluxes. Model results suggest that the majority of the studied seeps transport rather limited amount of methane (on average: ~177 μmol cm?2 a?1) into the water column due to moderate upward advection, allowing for intense anaerobic oxidation of methane (AOM; on average: 53 % of the methane flux is consumed). Depth-integrated AOM rates (56–1,538 μmol CH4 cm?2 a?1) are comparable with values reported from other active seep sites. The overall amount of dissolved methane released into the water column from the entire area covered by bacterial mats on the Quepos Slide is estimated to be about 0.28 × 106 mol a?1. This conservative estimate which relies on rather accurate determinations of seafloor methane fluxes emphasizes the potential importance of submarine slides as sites of natural methane seepage; however, at present the global extent of methane seepage from submarine slides is largely unknown.  相似文献   
946.
Previous studies showed that 85 % of total organic matter (TOM) in digested sewage sludge (biosolids) used as a sealing layer material over sulfide tailings at the Kristineberg Mine, northern Sweden, had been degraded 8 years after application, resulting in a TOM reduction from 78 to 14 %. To achieve a better understanding of the field observations, laboratory studies were performed to evaluate biodegradation rates of the TOM under anaerobic conditions. Results reveal that the original biosolid consisted of ca. 60 % TOM (48.0 % lignin and 11.8 % carbohydrates) that had not been fully degraded. The incubation experiments proved that 27.8 % TOM in the biosolid was further degraded anaerobically at 20–22 °C during the 230 days’ incubation period, and that a plateau to the biodegradation rate was approached. Based on model results, the degradation constant was found to be 0.0125 (day?1). The calculated theoretical gas formation potential was ca. 50 % higher than the modeled results based on the average degradation rate. Cumulated H2S equated to 0.65 μmoL g?1 of biosolid at 230 days. However, the large sulfurous compounds reservoir (1.76 g SO4 2? kg?1 biosolid) together with anaerobic conditions can generate high concentrations of this gas over a long-term perspective. Due to the rate of biodegradability identified via anaerobic processes, the function of the biosolid to serve as an effective barrier to inhibit oxygen migration to underlying tailings, may decrease over time. However, a lack of readily degradable organic fractions in the biosolid and a large fraction of organic matter that was recalcitrant to degradation suggest a longer degradation duration, which would prolong the biosolid material’s function and integrity.  相似文献   
947.
The paper presents data on the petrology and geochemistry of plutonic rocks dredged from the Stalemate Fracture Zone, Northwest Pacific Ocean, during Cruise SO201-1 of the R/V “Sonne”. We proposed also the reconstruction of their formation conditions and interpretation of their tectonic evolution. The genesis of gabbroids found among plutonic rocks composing the Cretaceous-Paleogene basement of the northwestern part of the Pacific Ocean was related to magmatism at the ancient spreading center and provides record of the evolution of the parental magmatic melts of N-MORB. Along with related peridotites, basalts, and dolerites, these rocks can be attributed to the disintegrated the Cretaceous-Paleogene oceanic lithosphere of the Pacific Ocean. The shallow mantle beneath the ancient oceanic crust of this area is made up of depleted magmatic spinel lherzolite, harzburgite, and dunite. The fact that gabbro-diorite and diorite that are not genetically related to the rocks of the Cretaceous-Paleogene basement of the Northwest Pacific occur at the eastern termination of the Stalemate Fracture Zone possibly reflects the complicated structure of the tectonic collage of rocks of different age that were produced in different geodynamic environments and were later tectonically brought together near the frontal portion of the Aleutian island arc. Judging by the isotopic-geochemical characteristics of these rocks, they cannot be classed with the family of oceanic plagiogranites. Deformations of the oceanic basement can be discerned throughout the whole Stalemate Fracture Zone as brecciation and large-amplitude vertical displacements within the oceanic lithosphere.  相似文献   
948.
The present article describes, for the first time, petrological and geochemical details of the Mawpyut differentiated complex which is related to the Sylhet trap located at Jaintia Hills district, Meghalaya, northeastern India. The Mawpyut complex occurs as an arcuate body that intrudes into the surrounding Shillong Group rocks. The complex in general contains ‘ultramafic’ and ‘mafic’ rocks, as well as minor syenitic veins that postdate the main units. The lithotypes correspond to cumulate and noncumulate units. The cumulate unit is represented by olivine clinopyroxenite, clinopyroxenite, plagioclase‐bearing ultramafic, olivine gabbronorite, mela‐gabbronorite, melagabbro, orthopyroxene gabbro, and gabbro, all with a pronounced cumulus texture. The noncumulate unit is marked by gabbro, monzonite, monzodiorite, and quartzsyenite. The use of several major and trace element variation diagrams suggests that magmatic differentiation led to the formation of cumulate and noncumulate units. In chondrite‐normalized REE diagrams the cumulate rocks show flat LREE and MREE patterns and a moderate positive Eu anomaly (in plagioclase‐bearing ultramafics) due to plagioclase cumulation. The rocks of the noncumulate unit show a strongly fractionated REE pattern and no Eu anomaly. The noncumulate mafic rocks are geochemically comparable to high‐phosphorous/high‐titanium basalts (HPT) indicative of low pressure fractional crystallization. In a primitive mantle‐normalized multielement diagram some of the cumulate rocks show pronounced negative anomalies for K and P, indicating anorogenic mafic magmatism in a within‐plate setting. The rocks of the noncumulate unit show a slight negative anomaly for Yb and a Nb–Ta trough, indicating a subduction‐related signature that perhaps is inherited from subducted sedimentary rocks incorporated during crustal contamination of the derived magma (left after crystal cumulation) with country rocks. Various trace element ratios for the cumulate mafic rocks indicate parent EMI/EMII/HIMU sources with a very limited crustal signature. The noncumulate mafic rocks (corresponding to the derived evolved magma) indicate EMI/EMII/HIMU sources with a pronounced crustal contamination. The Sr–Nd isotopic compositions of the Mawpyut samples typically plot in the continental flood basalt field, with an affinity to the EMII source. The isotopic compositions of the noncumulate rocks also clearly indicate crustal contamination. We suggest that partial melting (involving garnet in the residue) of the enriched mantle source EMI/EMII/HIMU could have derived the parental melt; this melt, in turn, underwent assimilation and fractional crystallization to produce the variety of cumulate‐noncumulate lithologies of the Mawpyut complex. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   
949.
The hazard posed by a rip current depends in part on the ability of beach users to identify a rip current and to associate surf conditions with the potential for rip currents. Understanding which visual features beach users associated with rip currents is an important step in the development of appropriate programs and educational materials aimed at improving the ability of beach users to identify a rip current. A face-to-face survey (n = 392) was conducted to assess the ability of beach users to identify a rip current using five near eye-level photographs that simulate the view of the beach and surf zone as the respondent approached the beach. The survey was conducted on three heavily used public beaches in Texas (Galveston, Port Aransas, and Corpus Christi) at the height of the summer beach season in 2012. Only 13 % of respondents correctly selected the photograph showing the most hazardous conditions and correctly identified the precise location of the rip current on the photograph. The majority of beach users (87 %) incorrectly indicated that the photograph with the heaviest surf represented the most hazardous surf conditions and greatest potential for the development of rip currents, or failed to identify rip currents in photographs. Respondents who were able to correctly identify the rip current tended to recognize the breaking wave pattern, areas of darker water, or the proximity to structures as key visual characteristics of rip currents and also had higher self-reported abilities to swim in rough water and escape a rip current.  相似文献   
950.
In this article the problem of credible commitment in carbon policy is discussed. Investors favour long-term predictability of the policy, but without any external enforcement mechanisms a commitment made by a government can be withdrawn, leading to scepticism and lack of credibility. This results in increased market risks and investment hold-up. Regulatory uncertainty stems from (i) strategic interactions between government and firms, (ii) potential learning about climate damage and abatement cost and (iii) political volatility. Although commitment to future policy encourages private investment, it also imposes costs in the form of reduced flexibility to accommodate new information or preferences. The article reviews devices that may help policy makers raise the level of commitment while also leaving some room for flexible adjustments. In particular, legislation of a long-term governance framework, delegation to an independent carbon agency and securitization of investors' stakes in emission markets offer palliative approaches.  相似文献   
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