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991.
Impact of Sea-Level Rise on Sea Water Intrusion in Coastal Aquifers   总被引:17,自引:0,他引:17  
Despite its purported importance, previous studies of the influence of sea-level rise on coastal aquifers have focused on specific sites, and a generalized systematic analysis of the general case of the sea water intrusion response to sea-level rise has not been reported. In this study, a simple conceptual framework is used to provide a first-order assessment of sea water intrusion changes in coastal unconfined aquifers in response to sea-level rise. Two conceptual models are tested: (1) flux-controlled systems, in which ground water discharge to the sea is persistent despite changes in sea level, and (2) head-controlled systems, whereby ground water abstractions or surface features maintain the head condition in the aquifer despite sea-level changes. The conceptualization assumes steady-state conditions, a sharp interface sea water-fresh water transition zone, homogeneous and isotropic aquifer properties, and constant recharge. In the case of constant flux conditions, the upper limit for sea water intrusion due to sea-level rise (up to 1.5 m is tested) is no greater than 50 m for typical values of recharge, hydraulic conductivity, and aquifer depth. This is in striking contrast to the constant head cases, in which the magnitude of salt water toe migration is on the order of hundreds of meters to several kilometers for the same sea-level rise. This study has highlighted the importance of inland boundary conditions on the sea-level rise impact. It identifies combinations of hydrogeologic parameters that control whether large or small salt water toe migration will occur for any given change in a hydrogeologic variable.  相似文献   
992.
Vertical gravity gradient anomalies from the Gravity and steady-state Ocean Circulation Explorer (GOCE) DIR-3 model have been used to determine gravity anomalies in mid-west Greenland by using Least-Squares Collocation (LSC) and the Reduced Point Mass (RPM) method. The two methods give nearly identical results. However, compared to LSC, the RPM method needs less computational time as the number of equations to be solved in LSC equals the number of observations. The advantage of the LSC, however, is the acquired error estimates. The observation periods are winter 2009 and summer 2012. In order to enhance the accuracy of the calculated gravity anomalies, ground gravity data from West Greenland is used over locations where the gravity change resulting from ice mass changes is negligible, i.e. over solid rock. In the period considered, the gravity anomaly change due to changes in ice mass varies from ?5 mGal to 4 mGal. It is negative over the outlet glacier Jacobshavn Isbræ, where the mass loss corresponds to a gravity change of approximately ?4 mGal. When using only GOCE vertical gravity gradients, the error estimates range from 5 mGal at the coast to 17 mGal over the ice sheet. Introducing the ground gravity data from West Greenland in the prediction reduces the errors to range from 2 to 10 mGal.  相似文献   
993.
Global forward modelling of the Earth’s gravitational potential, a classical problem in geophysics and geodesy, is relevant for a range of applications such as gravity interpretation, isostatic hypothesis testing or combined gravity field modelling with high and ultra-high resolution. This study presents spectral forward modelling with volumetric mass layers to degree 2190 for the first time based on two different levels of approximation. In spherical approximation, the mass layers are referred to a sphere, yielding the spherical topographic potential. In ellipsoidal approximation where an ellipsoid of revolution provides the reference, the ellipsoidal topographic potential (ETP) is obtained. For both types of approximation, we derive a mass layer concept and study it with layered data from the Earth2014 topography model at 5-arc-min resolution. We show that the layer concept can be applied with either actual layer density or density contrasts w.r.t. a reference density, without discernible differences in the computed gravity functionals. To avoid aliasing and truncation errors, we carefully account for increased sampling requirements due to the exponentiation of the boundary functions and consider all numerically relevant terms of the involved binominal series expansions. The main outcome of our work is a set of new spectral models of the Earth’s topographic potential relying on mass layer modelling in spherical and in ellipsoidal approximation. We compare both levels of approximations geometrically, spectrally and numerically and quantify the benefits over the frequently used rock-equivalent topography (RET) method. We show that by using the ETP it is possible to avoid any displacement of masses and quantify also the benefit of mapping-free modelling. The layer-based forward modelling is corroborated by GOCE satellite gradiometry, by in-situ gravity observations from recently released Antarctic gravity anomaly grids and degree correlations with spectral models of the Earth’s observed geopotential. As the main conclusion of this work, the mass layer approach allows more accurate modelling of the topographic potential because it avoids 10–20-mGal approximation errors associated with RET techniques. The spherical approximation is suited for a range of geophysical applications, while the ellipsoidal approximation is preferable for applications requiring high accuracy or high resolution.  相似文献   
994.
We investigated cloud properties of warm clouds in a tropical montane cloud forest at Pico del Este (1,051 m a.s.l.) in the northeastern part of Puerto Rico to address the question of whether cloud properties in the Caribbean could potentially be affected by African dust transported across the Atlantic Ocean. We analyzed data collected during 12 days in July 2011. Cloud droplet size spectra were measured using the FM-100 fog droplet spectrometer that measured droplet size distributions in the range from 2 to 49 µm, primarily during fog events. The droplet size spectra revealed a bimodal structure, with the first peak (D < 6 µm) being more pronounced in terms of droplet number concentrations, whereas the second peak (10 µm < D < 20 µm) was found to be the one relevant for total liquid water content (LWC) of the cloud. We identified three major clusters of characteristic droplet size spectra by means of hierarchical clustering. All clusters differed significantly from each other in droplet number concentration ( \(N_{\rm tot}\) ), effective diameter (ED), and median volume diameter (MVD). For the cluster comprising the largest droplets and the lowest droplet number concentrations, we found evidence of inhomogeneous mixing in the cloud. Contrastingly, the other two clusters revealed microphysical behavior, which could be expected under homogeneous mixing conditions. For those conditions, an increase in cloud condensation nuclei—e.g., from processed African dust transported to the site—is supposed to lead to an increased droplet concentration. In fact, one of these two clusters showed a clear shift of cloud droplet size spectra towards smaller droplet diameters. Since this cluster occurred during periods with strong evidence for the presence of long-range transported African dust, we hypothesize a link between the observed dust episodes and cloud characteristics in the Caribbean at our site, which is similar to the anthropogenic aerosol indirect effect.  相似文献   
995.
The limited-length-scale k-e{k-\varepsilon} model proposed by Apsley and Castro for the atmospheric boundary layer (Boundary-Layer Meteorol 83(1):75–98, 1997) is revisited with special attention given to its predictions in the constant-stress surface layer. The original model proposes a modification to the length-scale-governing e{\varepsilon} equation that ensures consistency with surface-layer scaling in the limit of small m/ max (where m is the mixing length and max its maximum) and yet imposes a limit on m as m/ max approaches one. However, within the equilibrium surface layer and for moderate values of z/ max, the predicted profiles of velocity, mixing length, and dissipation rate using the Apsley and Castro model do not coincide with analytical solutions. In view of this, a general e{\varepsilon} transport equation is derived herein in terms of an arbitrary desired mixing-length expression that ensures exact agreement with corresponding analytical solutions for both neutral and stable stability. From this result, a new expression for Ce3{C_{\varepsilon3}} can be inferred that shows this coefficient tends to a constant only for limiting values of z/L; and, furthermore, that the values of Ce3{C_{\varepsilon3}} for z/L → 0 and z/L →∞ differ by a factor of exactly two.  相似文献   
996.

The mechanical efficiency of the biocementation process is directly related to the microstructural properties of the biocemented sand, such as the volume fraction of calcite, its distribution within the pore space (localized at the contact between grains, over the grain surfaces) and the contact properties: coordination number, contact surface area, contacts orientation and types of contact. In the present work, all these micromechanical properties are computed, for the first time, from 3D images obtained by X-ray tomography of intact biocemented sand samples. The evolution of all these properties with respect to the volume fraction of calcite is analyzed and compared between each other (from untreated sand to highly cemented sand). Whatever the volume fraction of calcite, it is shown that the precipitation of the calcite is localized at the contacts between grains. These results are confirmed by comparing our numerical results with analytical estimates assuming that the granular medium is made of periodic simple cubic arrangements of grains and by considering two extreme cases of precipitation: (1) The calcite is localized at the contact, and (2) the grains are covered by a uniform layer of calcite. In overall, the obtained results show that a small percentage of calcite is sufficient to get a large amount of cohesive contacts.

  相似文献   
997.
Natural sinhalites, MgAlBO4, from the Ratnapura District, Sri Lanka, and from Bodnar Quarry near Hamburg, Sussex Co., New Jersey, USA, have been characterized by 57Fe Mössbauer spectroscopy, electron microprobe, X-ray single-crystal diffractometry and by electronic structure calculations in order to determine the oxidation state and site occupancy of iron in the sinhalite structure. The samples contain about 3.35 and 1.46 wt% of total iron oxide, respectively. The structure refinement is successful and reproduces the total iron content provided that the substitution of Mg2+ by Fe2+ on the M2 position only is assumed. The 57Fe Mössbauer spectra at 77, 293, 573 and 773 K can be resolved into two doublets with hyperfine parameters common for octahedrally coordinated high-spin Fe2+. There is no evidence for iron in the tetrahedral site. Electronic structure calculations in local spin density approximation yield hyperfine parameters for Fe2+ on the M2-site at 0, 293, 573 and 773 K in quantitative agreement with experiments. Calculated spectroscopic properties for Fe2+ on the M1-site are at variance with the experimental data and, thus, indicate that substitution of Al3+ by Fe2+, if occurring at all, must be accompanied by considerable local expansion and distortion of the M1-octahedron.  相似文献   
998.
Outcrops, offshore wells, electric logs and seismic profiles from northern Tunisia provide an opportunity to decipher the Messinian Salinity Crisis in the Strait of Sicily. Messinian deposits (including gypsum beds) near the Tellian Range reveal two successive subaerial erosional surfaces overlain by breccias and marine Zanclean clays, respectively. In the Gulf of Tunis, Messinian thick evaporites (mostly halite) are strongly eroded by a fluvial canyon infilled with Zanclean clays. The first erosional phase is referred to the intra-Messinian tectonic phase and is analogous to that found in Sicily. The second phase corresponds to the Messinian Erosional Surface that postdates the marginal evaporites, to which the entire Sicilian evaporitic series must refer. The Western and Eastern Mediterranean basins were separated during deposition of the central evaporites.  相似文献   
999.
The present-day clay mineral distribution in the southeastern Levantine Sea and its borderlands reveals a complex pattern of different sources and distribution paths. Smectite dominates the suspended load of the Nile River and of rivers in the Near East. Illite sources are dust-bearing winds from the Sahara and southwestern Europe. Kaolinite is prevalent in rivers of the Sinai, in Egyptian wadis, and in Saharan dust. A high-resolution sediment core from the southeastern Levantine Sea spanning the last 27 ka shows that all these sources contributed during the late Quaternary and that the Nile River played a very important role in the supply of clay. Nile influence was reduced during the glacial period but was higher during the African Humid Period. In contrast to the sharp beginning and end of the African Humid Period recorded in West African records (15 and 5.5 ka), our data show a more transitional pattern and slightly lower Nile River discharge rates not starting until 4 ka. The similarity of the smectite concentrations with fluctuations in sea-surface temperatures of the tropical western Indian Ocean indicates a close relationship between the Indian Ocean climate system and the discharge of the Nile River.  相似文献   
1000.
Liquid phase diffusion experiments were carried out to determine whether diffusive isotopic fractionation of a major chemical element (Ca) varies with chemical composition in high-temperature molten silicates. The objective was to determine how differences in silicate liquid structure, such as the ratio of bridging to non-bridging oxygen atoms, as well as bulk transport properties such as viscosity, relate to isotope discrimination during diffusion. This information, in turn, may relate to the lifetimes and sizes of multi-atom structures in the liquid. Diffusion couples consisting of juxtaposed natural mafic and felsic liquids were held at T = 1450 °C and P = 1.0 GPa for durations of 12-24 h in a standard piston-cylinder assembly. Experiments were done using different mafic endmember compositions (two tholeiitic basalts and a ugandite) and a single rhyolite composition. Major-element diffusion profiles and Ca isotope profiles were measured on the recovered quenched glasses. The starting materials were isotopically indistinguishable, but 44Ca/40Ca variations of ca. 5‰ arose due to a mass dependence of the Ca diffusion coefficients. Results indicate that the mass dependence of Ca diffusion coefficients varies with the magnitude and direction of aluminum gradients and the viscosity of the liquid. Some Ca fractionations result mainly from Al gradients.A simplified multicomponent diffusion model was used to model the experimental results. The model allows for diffusion of Ca in response to gradients in the concentrations of both CaO as well as Al2O3, and the model results are consistent with the inferred existence of at least two distinct species of Ca. The magnitude of isotopic discrimination during diffusion also appears to be stronger on the rhyolite versus the basalt/ugandite side of diffusion couples. The results can largely be accounted for by an adaptation of the model of Dingwell (1990), whereby in high silica liquids, Ca diffuses largely by site hopping through a quasi-stationary aluminosilicate matrix, producing strong isotopic effects because the Ca diffusion is not strongly correlated with the movement of the framework atoms. In low-silica liquids, Ca diffusion is correlated with the movement of the other components and there is less mass discrimination. Combining our Ca results with Ca, Mg, and Li data from previous studies, we show that this model can explain most of the cation- and composition-dependence of diffusive isotopic fractionations observed thus far. A key parameter controlling isotopic discrimination is the ratio of the elemental (Ca, Mg, Li) diffusivity to the Eyring (or Si) diffusivity. However, all experiments done so far also exhibit isotopic features that are not yet fully explained; some of these may relate to small temperature gradients in the capsules, or to more complex coupling effects that are not captured in simplified diffusion models.  相似文献   
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