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991.
Seabed topography is ubiquitous across basin‐floor environments, and influences sediment gravity flows and sediment dispersal patterns. The impact of steep (several degrees) confining slopes on sedimentary facies and depositional architecture has been widely documented. However, the influence of gentle (fraction of a degree) confining slopes is less well‐documented, largely due to outcrop limitations. Here, exceptional outcrop and research borehole data from Unit A of the Permian Laingsburg Formation, South Africa, provide the means to examine the influence of subtle lateral confinement on flow behaviour and lobe stacking patterns. The dataset describes the detailed architecture of subunits A.1 to A.6, a succession of stacked lobe complexes, over a palinspastically restored 22 km across‐strike transect. Facies distributions, stacking patterns, thickness and palaeoflow trends indicate the presence of a south‐east facing low angle (fraction of a degree) lateral intrabasinal slope. Interaction between stratified turbidity currents with a thin basal sand‐prone part and a thick mud‐prone part and the confining slope results in facies transition from thick‐bedded sandstones to thin‐bedded heterolithic lobe fringe‐type deposits. Slope angle dictates the distance over which the facies transition occurs (hundreds of metres to kilometres). These deposits are stacked vertically over tens of metres in successive lobe complexes to form an aggradational succession of lobe fringes. Extensive slides and debrites are present at the base of lobe complexes, and are associated with steeper restored slope gradients. The persistent facies transition across multiple lobe complexes, and the mass flow deposits, suggests that the intrabasinal slope was dynamic and was never healed by deposition during Unit A times. This study demonstrates the significant influence that even subtle basin‐floor topography has on flow behaviour and depositional architecture of submarine lobe complexes. In addition, we present a new aggradational lobe fringe facies associations and recognition criteria for subtle confinement in less well‐exposed and subsurface basin fills.  相似文献   
992.
Tectonic forcing of delta progradation is increasingly being invoked to explain stratal stacking patterns in foreland basins. Nonetheless, the recognition of different types of tectonic forcing and their consequences for the spatial and temporal distribution of accommodation often rely on incomplete data sets and indirect sequence stratigraphic criteria. Previous work has concluded that the Cenomanian–Turonian Frontier Formation of northern Utah, north‐west Colorado and south‐west Wyoming (‘Vernal Delta’) owes its origin largely to tectonic overprinting of depositional patterns, although the lack of a comprehensive sequence stratigraphic framework for the unit has hampered evaluation of this claim. This study provides detailed facies and sequence stratigraphic analyses based on outcrop sections and wireline log suites from the Uinta, Piceance and Green River basins. Four genetically related intervals were defined and mapped by using regionally traceable stratigraphic horizons (flooding surfaces and sequence boundaries). Internally, intervals are composed of distal and proximal delta front lithologies, and coastal plain facies. Overall, Intervals 1 to 4 form a major basinward projection of coarse clastic strata generated in response to four separate, high‐frequency regressions. Furthermore, a change through time from southward projection of elongate lobes (Intervals 1 and 2) to eastward dispersal and development of a broad, arcuate planform (Intervals 3 and 4) can be explained in terms of changes in prevailing tectonic forcing mechanisms. North–south trending Sevier Orogeny forebulge structures controlled Intervals 1 and 2. West–east progradation (Intervals 3 and 4) was probably controlled by Proterozoic basement lineament reactivation due to Laramide foreland uplifts. Therefore, this study provides direct geological evidence for the initiation of local Laramide deformation as early as 90 Ma. These findings contribute to a more complete understanding of tectonic forcing of coastal to shallow marine successions in foreland basins and the tectonic evolution of the western USA.  相似文献   
993.
New zircon LA-ICP-MS U–Pb age, zircon Hf isotope, and whole-rock major and trace elemental data of the Late Cretaceous Ageledaban complex in the Karakorum Terrane (KKT), northwest Tibet, provide new constraints on the tectonic processes of the collision and thickening of the terrane between the Lhasa and Qiangtang terranes. The granitoids from the Ageledaban complex have a variable SiO2 content, from 62.83 to 73.35 wt.% and A/CNK<1.1 (except for YM61-2). They have rare earth element and trace element patterns that are enriched in light rare earth elements, Rb, Pb, Th, and U, and are depleted in Ba, P, Sr, Ti, and Nb, indicative of weakly peraluminous-metaluminous I-type affinity. Zircon U–Pb dating reveals that the Ageledaban complex was emplaced at ca. 80 Ma. Zircons from the monzogranite and monzonite samples with concordant 206Pb/238U ages about 80 Ma have a zircon εHf(t) of ?6.6 to ?1.1, corresponding to the Mesoproterozoic Hf crustal model ages (TDMC = 1.2–1.6 Ga); the remaining inherited zircons from the monzonite with concordant 206Pb/238U ages of about 108.1 Ma have εHf(t) values that range from ?8.3 to ?5.0, corresponding to the Mesoproterozoic Hf crustal model ages with an average of 1.6 Ga. These signatures indicate that the Ageledaban granitoids may have been derived from the partial melting of a mixed mantle-crust source. Together with the age and geochemical data in the literature, we propose that the collisional event in the KKT in northwestern Tibet would postdate the northern Lhasa–southern Qiangtang collision, which occurred first in the Amdo in the east and later in the Shiquanhe in central Tibet. Our results support the previous view that the collision of the Bangong–Nujiang suture zone (BNSZ) may be diachronous.  相似文献   
994.
Stable isotopes of the water molecule (δ18O and δD) for groundwater, lake water, streams, and precipitation were coupled with physical flux measurements to investigate groundwater–lake interactions and to establish a water balance for a structurally complex lake. Georgetown Lake, a shallow high-latitude high-elevation lake, is located in southwestern Montana, USA. The lake is situated between two mountain ranges with highlands primarily to the east and south of the lake and a lower valley to the west. An annual water balance and (δ18O and δD) isotope balance were used to quantify annual groundwater inflows of 2.5?×?107 m3/year and lake leakage outflows of 1.6?×?107 m3/year. Roughly, 57% of total inflow to the lake is from groundwater, and 37% of total outflow at Georgetown Lake is groundwater. Stable isotopes of groundwater and springs around the lake and surrounding region show that the east side of the lake contains meteoric water recharged annually from higher mountain sources, and groundwater discharge to the lake occurs through this region. However, springs located in the lower western valley and some of the surrounding domestic wells west of the lake show isotopic enrichment indicative of strong to moderate evaporation similar to Georgetown Lake water. This indicates that some outflowing lake water recharges groundwater through the underlying west-dipping bedrock in the region.  相似文献   
995.
One of the key components controlling the chemical composition and climatology of Titan's atmosphere is the removal of reactive atomic hydrogen from the atmosphere. A proposed process of the removal of atomic hydrogen is the heterogeneous reaction with organic aerosol. In this study, we investigate the effect of heterogeneous reactions in Titan's atmospheric chemistry using new measurements of the heterogeneous reaction rate [Sekine, Y., Imanaka, H., Matsui, T., Khare, B.N., Bakes, E.L.O., McKay, C.P., Sugita, S., 2008. Icarus 194, 186-200] in a one-dimensional photochemical model. Our results indicate that 60-75% of the atomic hydrogen in the stratosphere and mesosphere are consumed by the heterogeneous reactions. This result implies that the heterogeneous reactions on the aerosol surface may predominantly remove atomic hydrogen in Titan's stratosphere and mesosphere. The results of our calculation also indicate that a low concentration of atomic hydrogen enhances the concentrations of unsaturated complex organics, such as C4H2 and phenyl radical, by more than two orders in magnitude around 400 km in altitude. Such an increase in unsaturated species may induce efficient haze production in Titan's mesosphere and upper stratosphere. These results imply a positive feedback mechanism in haze production in Titan's atmosphere. The increase in haze production would affect the chemical composition of the atmosphere, which might induce further haze production. Such a positive feedback could tend to dampen the loss and supply cycles of CH4 due to an episodic CH4 release into Titan's atmosphere.  相似文献   
996.
We present new experimental results on impact shock chemistry into icy satellites of the outer planets. Icy mixtures of pure water ice with CO2, Na2CO3, CH3OH, and CH3OH/(NH4)2SO4 at 77 K were ablated with a powerful pulsed laser—a new technique used to simulate shock processes which can occur during impacts. New products were identified by GC-MS and FTIR analyses after laser ablation. Our results show that hydrogen peroxide is formed in irradiated H2O/CO2 ices with a final concentration of 0.23%. CO and CH3OH were also detected as main products. The laser ablation of frozen H2O/Na2CO3 generates only CO and CO2 as destruction products from the salt. Pulsed irradiation of water ice containing methanol leads also to the formation of CO and CO2, generates methane and more complex molecules containing carbonyl groups like acetaldehyde, acetone, methyl formate, and a diether, dimethyl formal. The last three compounds are also produced when adding ammonium sulfate to H2O/CH3OH ice, but acetone is more abundant. The formation of two hydrocarbons, CH4 and C2H6 is observed as well as the production of three nitrogen compounds, nitrous oxide, hydrogen cyanide, and acetonitrile.  相似文献   
997.
Nitrogen isotopes appear to be escaping from Mars at approximately the primordial ratio 14N/15N ≈ 275 and to have an atmospheric nitrogen depletion time scale of about 800 Myr. For the standard model of a progressive decline of an initial inventory of atmospheric nitrogen, having no source of N, the agreement of the isotopic ratio of escaping N with primitive nitrogen would be coincidental. Here we propose a steady state model in which nitrates, produced early in Mars' history, are later decomposed by the current impact flux. The detection of near-surface nitrates can discriminate between the standard and the steady state models. Based on current estimates of N loss to space, we predict a quantity of nitrates equivalent to 60 ± 30 mbars for a steady state, or a global layer of about 3 m of pure NaNO3.  相似文献   
998.
999.
Sodium sulfate readily forms a metastable heptahydrate from concentrated aqueous solutions on cooling to around 10 °C. It crystallises much more easily than the well recognised and less soluble decahydrate (mirabilite), although the existence of the heptahydrate is almost entirely ignored in the geochemical literature on sodium sulfate. There is strong evidence that the heptahydrate is stable below a triple point temperature of −9.5 °C at low water vapour pressures, conditions which are found in cold dry environments such as the surface of Mars and the icy moons of Jupiter.  相似文献   
1000.
Ashdown Brickworks, near Bexhill, East Sussex, has produced a large number of vertebrate fossils from the Wadhurst Clay Formation, part of the Wealden Supergroup (Hastings Group; Valanginian; Lower Cretaceous). Here we describe the microvertebrate fauna of the ‘conglomerate bed’, representing a rich sample of taxa. While most of the recovered teeth and bones are abraded, some heavily, most can be identified to species level. The taxa include four species of hybodont sharks (Egertonodus basanus, Planohybodus ensis, Polyacrodus parvidens, P. brevicostatus), three taxa of bony fishes (an unidentified Lepidotes-like semionotiform, the pycnodontiform Ocloedus, and an albuliform), three taxa of crocodyliforms (the goniopholid Hulkepholis, a bernissartiid, and the atoposaurid Theriosuchus), and the theropod dinosaurs Baryonyx and an allosauroid. Sediments of the Wadhurst Clay Formation as a whole indicate freshwater to very slightly brackish-water environments of deposition, and the mainly aquatic time-averaged mixture of fishes and tetrapods recovered from the ‘conglomerate bed’, together with isolated terrestrial species, confirms this interpretation.  相似文献   
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