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51.
The 1991 eruption of Mount Pinatubo generated extreme sediment yields from watersheds heavily impacted by pyroclastic flows. Bedload sampling in the Pasig–Potrero River, one of the most heavily impacted rivers, revealed negligible critical shear stress and very high transport rates that reflected an essentially unlimited sediment supply and the enhanced mobility of particles moving over a smooth, fine-grained bed. Dimensionless bedload transport rates in the Pasig–Potrero River differed substantially from those previously reported for rivers in temperate regions for the same dimensionless shear stress, but were similar to rates identified in rivers on other volcanoes and ephemeral streams in arid environments. The similarity between volcanically disturbed and arid rivers appears to arise from the lack of an armored bed surface due to very high relative sediment supply; in arid rivers, this is attributed to a flashy hydrograph, whereas volcanically disturbed rivers lack armoring due to sustained high rates of sediment delivery. This work suggests that the increases in sediment supply accompanying massive disturbance induce morphologic and hydrologic changes that temporarily enhance transport efficiency until the watershed recovers and sediment supply is reduced.  相似文献   
52.
Understanding how the strength of basaltic rock varies with the extrinsic conditions of stress state, pressure and temperature, and the intrinsic rock physical properties is fundamental to understanding the dynamics of volcanic systems. In particular it is essential to understand how rock strength at high temperatures is limited by fracture. We have collated and analysed laboratory data for basaltic rocks from over 500 rock deformation experiments and plotted these on principal stress failure maps. We have fitted an empirical flow law (Norton’s law) and a theoretical fracture criterion to these data. The principal stress failure map is a graphical representation of ductile and brittle experimental data together with flow and fracture envelopes under varying strain rate, temperature and pressure. We have used these maps to re-interpret the ductile–brittle transition in basaltic rocks at high temperatures and show, conceptually, how these failure maps can be applied to volcanic systems, using lava flows as an example.  相似文献   
53.
Detailed soil erosion studies bene?t from the ability to quantify the magnitude of erosion over time scales appropriate to the process. An inventory balance for 7Be was used to calculate sediment erosion in a 30·73 m2 plot during a series of runoff‐producing thunderstorms occurring over three days at the Deep Loess Research Station in Treynor, Iowa, USA. The inventory balance included determination of the pre‐ and post‐storm 7Be inventories in the soil, the atmospheric in?ux of 7Be during the event, and pro?les of the 7Be activity in the soil following the atmospheric deposition. The erosion calculated in the plot using the 7Be inventory balance was 0·058 g cm?2, which is 23 per cent of the annual average erosion determined using 137Cs inventories. The calculated erosion from the mass balance is similar to the 0·059 g cm?2 of erosion estimated from the amount of sediment collected at the outlet of the 6 ha ?eld during the study period and the delivery ratio (0·64). The inventory balance of 7Be provides a new means for evaluating soil erosion over the time period most relevant to quantifying the prediction of erosion from runoff. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
54.
 The structure of coesite has been determined at ten pressures up to a maximum of 8.68 GPa by single-crystal X-ray diffraction. The dominant mechanism of compression is the reduction of four of the five independent Si–O–Si angles within the structure. There is no evidence of the fifth linkage, Si1–O1–Si1, deviating from 180°. Some Si–O bond distances also decrease by up to 1.6% over the pressure range studied. The pattern of Si–O–Si angle reduction amounts to a rotation of the Si2 tetrahedron around the [001] direction. This rotation induces significant internal deformation of the Si1 tetrahedron. Comparison of the experimental data with rigid-unit distance least-squares simulations of coesite suggests that this pattern of compression, the anomalous positive values of both s23 and K′′ in the equation of state of coesite, its high elastic anisotropy and the unusual straight Si1–O1–Si1 linkage within the structure are all consequences of the connectivity of the tetrahedral framework. Received: 11 July 2002 / Accepted: 14 January 2003 Acknowledgements The help of Christian Baerlocher of ETH Zurich in providing both the DLS-76 software and advice in its use is gratefully acknowledged, as are discussions with Paul Ribbe of Virginia Tech and the comments of two anonymous reviewers. The data analysis was supported by the National Science Foundation under grant EAR-0105864 to N.L. Ross and R.J. Angel.  相似文献   
55.
The concentrations of Rare Earth Elements (REE) and Redox Sensitive Elements (RSE) were measured in groundwaters along a transect of the forest-marsh interface of a surficial aquifer system in North Inlet, SC. The well transect extended from a forest recharge area across the marsh and tidal creek to a tidal recharge area of beach ridge. The concentrations of the RSE (Fe, Mn, and U) were consistent with reducing conditions through the transect. Fe was present at concentrations ranging from a few micromolar to greater than one hundred micromolar in most wells. U was depleted with respect to salinity predicted concentrations, indicating removal with respect to the seawater endmember. Dissolved Mn concentrations were generally low in all wells, indicating no significant solid source of Mn (as MnOx) in this system. When extrapolated to a global scale, estimates of U removal during seawater exchange with the aquifer solids equaled 10–20% of the total riverine dissolved U input flux. REE concentrations in the forest recharge area were high in shallow wells, and showed a light enriched fractionation pattern, characteristic of soil leaching by Natural Organic Matter (NOM) rich waters. A decrease in REE concentration with depth in the forest wells coupled with a trend towards Heavy REE (HREE) enriched fractionation pattern indicated removal of the REE coincident with NOM and Dissolved Organic Carbon (DOC) removal. The saline waters of the beach ridge wells show a Light REE (LREE) enriched fractionation pattern and have the highest overall concentrations of the REE, indicating a significant REE source to the seawater endmember waters. The concentration gradients along the beach ridge flow path indicate a large source in the deep wells, and net export of dissolved REE to the tidal creek system and the coastal ocean. Ultrafiltration experiments indicate a transition from a colloidal dominated reservoir for the REE in the forest wells to a colloidal and dissolved reservoir in the beach ridge wells. The ultrafiltration data coupled with a correlation with Dissolved Inorganic Carbon (DIC) release suggest that there is diagenetic mobilization of an REE rich organic carbon phase in the saline endmember wells. We suggest here that degradation of this relic terrestrial organic carbon and REE rich phase results in the export of dissolved REE equal to or exceeding river inputs in this region.  相似文献   
56.
Saturated and aromatic biomarker ratios continue to change systematically through the oil window and into the gas-condensate window to high vitrinite reflectances (Ro = 1.16%) in mature marine and lacustrine Mesozoic clastic samples from a South African basin. Two of the ratios reverse above Ro = 0.9%. These unusual maturation effects result from isolated periods of high rates of maturation increase. The basin cooled regionally after the break-up of Gondwana but high heating rates prevailed during the late Cretaceous-early Tertiary, as Africa moved across a hotspot, and again in the late Tertiary as a result of a possible hotspot and hydrothermal event.  相似文献   
57.
A characteristic feature of the Partridge River intrusion of the Keweenawan Duluth Complex is the approximately fivefold to ninefold increase in the concentrations of incompatible elements in the lower zone compared with cumulates stratigraphically higher. The concentrations of incompatible elements decrease from the lower zone upward to steady state values, which is ascribed to variations in the proportions of trapped liquid rather than variable degrees of fractional crystallization of a single parental magma. The calculated average composition of trapped liquid using our algorithm is similar to typical Keweenawan low-alumina, high Ti---P basalts associated with the Duluth Complex but is different from the leading edge ferrodioritic liquid quenched in the chilled margin of the intrusion. This difference suggests that the chilled margin does not represent the original (parental) magma composition from which the whole intrusion solidified, and that the enrichment of incompatible elements may be related to the local flotation of magmatic suspensions. To test the latter hypothesis numerically, we have used heat-mass transfer models, assuming a sheet-like magma chamber, to calculate the parameters of the model that best reproduce the observed distribution of incompatible elements in a mush zone at the base of the Partridge River intrusion. The results indicate that a mush zone enriched in the incompatible elements is produced if the velocity of movement of the lower solidification front into the magma body was less than the floating velocity of the bulk crystal mush. The dynamic parameters that best reproduce the observed distribution of incompatible elements include a magma emplacement pressure of 2 kbar, critical crystallinities of 50–68% in the mush zone from which the liquid is being expelled, and an emplacement temperature of 1160°C for the initial magma.  相似文献   
58.
Tertiary continental flood basalts on Qeqertarssuaq and Nuussuaq in West Greenland contain ~3?km of picrites and variably contaminated tholeiites. The picrites are in the Naujánguit member of the Vaïgat Formation and they have 7–29?wt% MgO, La/Sm?=?0.9–2.1, and 143Nd/144Nd?=?0.51263–0.51307. They appear to have crystallised from high-Mg parental magmas (14.4–16.4?wt% MgO) with isotope and trace element ratios similar to recent Icelandic picrites. Discrete horizons of tholeiites, including the Asûk and?Kûgánguaq, have elevated SiO2 (50–58 wt%), La/Sm?=?3–7, 87Sr/86Sr?=?0.70550–0.71224, and low 143Nd/144Nd?=?0.51234–0.51174. These lavas have low Cu and Ni abundances (typically 10–50?ppm Ni or Cu), and in the case of the Asûk on Qeqertarssuaq, they contain droplets of native iron. The low Cu and Ni contents are attributed to scavenging by magmatic sulphides formed in response to crustal contamination of picritic magmas. Two contamination trends are recognised, one to a sediment end-member with high Th/Nb and Archaean model Nd ages, and the other to a meta-igneous component with high La/Sm, low Th/Nb and Rb/Nb, and Proterozoic source ages. Overall, 206Pb/204Pb varies from 16.47–21.68. Both contamination trends are associated with low Cu and Ni, and high SiO2, and it is argued that the magmatic sulphides were triggered by the increases in silica, rather than simply by the introduction of additional crustal-derived sulphur. Geochemically, the Asûk and Kûgánguaq rocks resemble the most contaminated Nadezhdinsky lavas of the Siberian Trap, which are widely regarded as the source of the Ni and Cu mineralisation in the giant Noril'sk deposits. Mass balance considerations indicate that the parental liquids to the contaminated magmas contained sufficient Ni, Cu, S and platinum group elements to form substantial magmatic sulphide deposits. However, unlike the lavas at Noril'sk, the contaminated (low Cu and Ni) West Greenland basalts are in isolated units with no evidence for a gradual recovery in Ni and Cu abundances with height in the lava column. Comparison with Noril'sk suggests that although significant quantities of metals were scavenged by sulphides in West Greenland, the metal contents of the sulphides may not have been upgraded by continued interaction with subsequent magma batches.  相似文献   
59.
Two Red Clay profiles near Xi’an and Xifeng were investigated in an attempt to determine magnetostratigraphic and palaeoclimatic records. The results show that aeolian dust accumulation and the related East Asia palaeomonsoon system had begun by 6.5 Ma, and it is deduced that the Tibetan Plateau had reached a significant elevation at that time. The late Tertiary palaeoclimatic history of the Red Clay as reflected by magnetic susceptibility is reconstructed during the period of 6.5–2.5 Ma. Stepwise increase in susceptibility of aeolian dust accumulation appears to have a close correlation to the uplift processes of the Tibetan Plateau. The remarkable increase of aeolian dust accumulation at 3.2 Ma appears to be due to the influence of global ice volume on the East Asia monsoon. Palaeomonsoon variation during the late Tertiary as recorded in the Red Clay sequences from the Chinese Loess Plateau can be regarded as the product of a number of interacting factors, such as uplift of the Tibetan Plateau, solar radiation, global ice volume, etc. Project supported by the National Natural Science Foundation of China and the Foundation of Xi’an Laboratory of Loess and Quaternary Geology, Chinese Academy of Sciences.  相似文献   
60.
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