Levels of tributyltin in sediments from Tagus estuary nature reserve     

J.?M.?F.?NogueiraEmail author  B.?Simplício  M.?H.?Floréncio  A.?M.?M.?Bettencourt 《Estuaries and Coasts》2003,26(3):798-802

Concentrations of tributyltin in sediments from 9 selected stations located in the upper Tagus River estuary nature reserve, Portugal, were determined. Tributyltin (TBT) concentrations in the sediments ranged from 5 to 35 ng g⁻¹ on a dry weight basis. The persistent TBT contamination observed in the sediments from this important European ecosystem is primarily related to shipping activities as well as the naval industrial complexes located downstream. This exploratory survey suggests that both dumping and dredging, or the effects of tidal transport of resuspended sediments, are likely the main sources for the TBT contamination observed in the upper estuary. Although the TBT contents found in the sediments studied are low relative to concentrations reported from other parts of the world, they appear to represent a potential risk for some resident marine populations.  相似文献   

Permian volcanism in the Central Western Carpathians (Slovakia): Basin-and-Range type rifting in the southern Laurussian margin     

J.?DostalEmail author  J.?Vozár  J.?D.?Keppie  D.?Hovorka 《International Journal of Earth Sciences》2003,92(1):27-35

The 1,500- to 2,000-m-thick Permian volcano-sedimentary Malu?iná Formation of the uppermost nappe of the Central Western Carpathians (a segment of the Alpine-Carpathian orogenic belt) occurs in several fault blocks distributed across Slovakia. This unit is a part of a post-Variscan overstep suite that followed accretion of the Gothic terranes to Laurussia. It consists of three upward-fining megacycles of semi-arid/arid, fluvial-lacustrine clastic redbeds and local dolomites and evaporites. Abundant intercalated volcanic rocks are predominantly mafic lava flows; volcaniclastic rocks and dykes are subordinate. Felsic rocks are represented by rare volcaniclastics and dykes. Compositionally, the mafic rocks are rift-related continental tholeiites with enriched light REE patterns having (La/Yb)_n ratios between 2 and 5.5 and with mantle-normalized patterns characterized by negative Nb-Ta anomalies. The rocks were derived from subcontinental lithospheric mantle and were affected by crustal contamination. It is inferred that the volcanism of the Malu?iná Formation formed in a Basin and Range tectonic setting in which rifting followed collision of the Palaeo-Tethys ridge with the trench bordering southern Laurussia. This model can be applied to other Permian volcanic suites of rift basins in the Eastern Alps and Carpathians over a strike-length of about 1,000 km, which indicates the width of the slab window.  相似文献   

A paleoenvironmental reconstruction of Laguna Babícora, Chihuahua, Mexico based on ostracode paleoecology and trace element shell chemistry     

Manuel R. Palacios-Fest  Ana Luisa Carreño  José R. Ortega-Ramírez  Guillermo Alvarado-Valdéz 《Journal of Paleolimnology》2002,27(2):185-206

Paleoecology of Laguna Babícora, Chihuahua, Mexico was reconstructed using ostracode faunal assemblages and shell chemistry. The paleolimnological record is used to show the magnitude of paleoclimatic changes in the area from 25,000 years to the present.Faunal assemblages consist of four species of the genus Limnocythere: L. sappaensis, L. ceriotuberosa, L. bradburyi and L. platyforma, all associated with Candona caudata, Candona patzcuaro and Cypridopsis vidua. A paleosalinity index developed from these assemblages indicates that the lake's salinity fluctuated frequently from oligo- to meso-haline conditions during the last 25,000 years. This pattern and low salinity range are in good agreement with modern TDS (here used as an indicator of salinity) values recorded from 26 wells and one spring from the area (258–975 mg l^–1). To estimate paleotemperature we examined the trace element content (Mg/Ca ratios) from individual valves of L. ceriotuberosa and L. platyforma, the two species most commonly recorded in Laguna Babícora.Shell Mg/Ca ratios of 204 specimens of these two species were used to estimate water temperature (Mg/Ca) by means of experimental standard coefficients. Our data show that paleowater temperature ranged from 5.6–21.3 °C (with 2 values ranging from 0.2–4.8 °C), which suggest a close correlation with atmospheric temperatures around the lake. These results are in good agreement with a modern mean winter temperature (3.5 °C) and mean summer temperature (20 °C) recorded in the area between 1970 and 1980.  相似文献   

Seismic Activity Around and Under Krakatau Volcano,Sunda Arc: Constraints to the Source Region of Island Arc Volcanics     

Špičák  A.  Hanuš  V.  Vaněk  J. 《Studia Geophysica et Geodaetica》2002,46(3):545-565

There is general agreement that calc-alkaline volcanic rocks at convergent plate margins are genetically related to the process of subduction (Ringwood, 1974; Maaloe and Petersen, 1981; Hawkesworth et al., 1997). However, opinions on the mode and site of generation of primary magma for island arc volcanism differ substantially. The site of generation of calc-alkaline magma is thought to be either in the mantle wedge (Plank and Langmuir, 1988; McCulloch and Gamble, 1991) or in the subducting slab (White and Dupré, 1986; Defant and Drummond, 1990; Edwards et al., 1993; Ryan and Langmuir, 1993). We present seismological evidence in favour of the latter concept. A distinctive seismicity pattern around and under the Krakatau volcano was identified during systematic studies of the SE Asian convergent plate margins by means of global seismological data. A column-like cluster of events, probably associated with the dynamics of the volcano, is clearly separated from the events in the Wadati-Benioff zone. The accuracy of hypocentral determinations of the events of the cluster does not differ from the accuracy of the events belonging to the subducting slab. The depths of the cluster events vary from very shallow to about 100 km without any apparent discontinuity. On the other hand, there is a pronounced aseismic gap in the Wadati-Benioff zone directly beneath the volcano at depths between 100-150 km. The Krakatau cluster connects this aseismic gap to the volcano at the surface. The pervasive occurrence of earthquakes in the continental wedge between the subducting slab and the Earth surface bears witness to the brittle character of the continental lithosphere and casts doubt on the existence of large-scale melting of mantle material. The aseismic gap (Hanu and Vank, 1985), interpreted by us as a partially melted domain occurring in subducted slabs in practically all active subduction zones that reach depths greater than 100 km, is here used as evidence for the location of the primary source region of island arc volcanics in the subducting plate.  相似文献   

Une dépression piézométrique naturelle en hausse au Sahel (Sud-Ouest du Niger)A rising piezometric depression in the Sahel (southwestern Niger)     

Guillaume Favreau  Christian Leduc  Christelle Marlin  Abdou Guéro 《Comptes Rendus Geoscience》2002,334(6):395-401

In southwest Niger, the Continental Terminal water table displays a natural hollow shape about 10 m in depth over an area of 4000 km². A 10-year survey of this hollow aquifer has shown that current recharge is above $\text{20 }\text{mm}\text{yr}{}^{\mathrm{?1}}$. The water table has risen continuously since the 1950–1960s as a result of land clearance. This shows a disequilibrium in the aquifer balance. The long-term recharge rate is estimated by radioisotopes to be around $\text{1 }\text{mm}\text{yr}{}^{\mathrm{?1}}$. This figure fits with the only possible origin of the piezometric depression, i.e. evapotranspiration losses in its centre. To cite this article: G. Favreau et al., C. R. Geoscience 334 (2002) 395–401.  相似文献   

The Magnetic Helicity Budget of a cme-Prolific Active Region     

Green  L.M.  López fuentes  M.C.  Mandrini  C.H.  Démoulin  P.  Van Driel-Gesztelyi  L.  Culhane  J.L. 《Solar physics》2002,208(1):43-68

Coronal mass ejections (CMEs) are thought to be the way by which the solar corona expels accumulated magnetic helicity which is injected into the corona via several methods. DeVore (2000) suggests that a significant quantity is injected by the action of differential rotation, however Démoulin et al. (2002b), based on the study of a simple bipolar active region, show that this may not be the case. This paper studies the magnetic helicity evolution in an active region (NOAA 8100) in which the main photospheric polarities rotate around each other during five Carrington rotations. As a result of this changing orientation of the bipole, the helicity injection by differential rotation is not a monotonic function of time. Instead, it experiences a maximum and even a change of sign. In this particular active region, both differential rotation and localized shearing motions are actually depleting the coronal helicity instead of building it. During this period of five solar rotations, a high number of CMEs (35 observed, 65 estimated) erupted from the active region and the helicity carried away has been calculated, assuming that each can be modeled by a twisted flux rope. It is found that the helicity injected by differential rotation (–7×10⁴² Mx²) into the active region cannot provide the amount of helicity ejected via CMEs, which is a factor 5 to 46 larger and of the opposite sign. Instead, it is proposed that the ejected helicity is provided by the twist in the sub-photospheric part of the magnetic flux tube forming the active region.  相似文献   

The use of transplanted cultured tropical oysters (Saccostrea commercialis) to monitor Cd levels in North Queensland coastal waters (Australia)     

Olivier F  Ridd M  Klumpp D 《Marine pollution bulletin》2002,44(10):1051-1062

Bivalves are commonly used to detect metal pollution in the marine environment. Commercially cultured Milky oysters (Saccostrea commercialis) were transplanted in various sites along the North Queensland coast and analyzed for two metals of potentially anthropogenic origin (Cd, Zn). To provide additional information, naturally occurring Black Lip oysters (Saccostrea echinata) were also collected at the transplantation sites. The study demonstrated that the oysters species transplanted are good bioindicators of these metal concentrations in tropical waters, sensitive to variations in the environment at concentrations which are much smaller than pollution signals commonly reported for temperate waters. Three transplant experiments were carried out from May 1999 to February 2000. Milky oysters transplanted to offshore areas (Orpheus Is., Kelso Reef) accumulated Cd in the soft parts whereas oysters sampled from cages placed in Ross Creek and the Herbert River estuaries showed a decrease in Cd concentration, which resulted from an increase in dry weight. Dry weight appeared to be an important covariant affecting Cd concentration in the oysters whereas it does not unambiguously affect Zn concentrations. For the duration of the experiments, oysters sampled from the Magnetic Is. reference site showed effectively constant Cd concentrations and total Cd contents which indicates that any seasonal cycle affecting metal concentration is weak. It was found that Cd accumulation in oysters increased as ambient dissolved Cd concentration decreased, from which it was concluded that for these oysters, the predominant source of Cd was from the particulate phase rather than the dissolved phase.  相似文献   

Heavy metals in molluscs from the Basque Coast (Northern Spain): results from an 11-year monitoring programme   总被引：1，自引：0，他引：1  

Franco J  Borja A  Solaun O  Pérez V 《Marine pollution bulletin》2002,44(9):973-976

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Simultaneous SOHO and Ground-Based Observations of a Large Eruptive Prominence and Coronal Mass Ejection   总被引：1，自引：0，他引：1  

Plunkett  S.P.  Vourlidas  A.  Šimberová  S.  Karlický  M.  Kotrč  P.  Heinzel  P.  Kupryakov  Yu.A.  Guo  W.P.  Wu  S.T. 《Solar physics》2000,194(2):371-391

Coronal mass ejections (CMEs) are frequently associated with erupting prominences near the solar surface. A spectacular eruption of the southern polar crown prominence was observed on 2 June 1998, accompanied by a CME that was well-observed by the LASCO coronagraphs on SOHO. The prominence was observed in its quiescent state and was followed throughout its eruption by the SOHO EIT and later by LASCO as the bright, twisted core of the CME. Ground-based H observations of the prominence were obtained at the Ondejov Observatory in the Czech Republic. A great deal of fine structure was observed within the prominence as it erupted. The prominence motion was found to rotate about its axis as it moved outward. The CME contained a helical structure that is consistent with the ejection of a magnetic flux rope from the Sun. Similar structures have been observed by LASCO in many other CMEs. The relationship of the flux rope to other structures in the CME is often not clear. In this event, the prominence clearly lies near the trailing edge of the structure identified as a flux rope. This structure can be observed from the onset of the CME in the low corona all the way out to the edge of the LASCO field of view. The initiation and evolution of the CME are modeled using a fully self-consistent, 3D axisymmetric, MHD code.  相似文献   

Radio Emission from Three-dimensional Relativistic Hydrodynamic Jets: Observational Evidence of Jet Stratification     

Aloy MA  Gómez JL  Ibáñez JM  Martí JM  Müller E 《The Astrophysical journal》2000,536(2):L85-L88

High-resolution, high signal-to-noise ratio, blue-violet spectra of three red giant branch tip stars in M15 have been obtained with the Keck I High-Resolution Echelle Spectrograph. These spectra have been analyzed to determine the abundances of several neutron-capture elements, including the radioactive chronometer element thorium. There are two principal results of this study. First, the abundances of the heavier (Z>/=56) elements for each of the three stars is well matched by a scaled solar system r-process abundance distribution. Second, a weighted mean-observed Th/Eu ratio for the stars implies an age for the neutron-capture material in M15 stars of 14+/-3 Gyr, in reasonable agreement with other recent age estimates for Galactic globular clusters.  相似文献