Structural phase transition in titanite,CaTiSiO5: A ramanspectroscopic study     

Ekhard Salje  Claudia Schmidt  Ulrich Bismayer 《Physics and Chemistry of Minerals》1993,19(7):502-506

The structural phase transition in titanite is correlated with a strong temperature dependence of Raman scattering cross sections and, to a somewhat lesser extent, with shifts of the phonon frequencies. Their quantitative temperature evolution in the low-symmetry phase (P2₁/a) is compatible with a nearly 2D Ising behaviour with β≈0.12 and T _c = 497 K. At temperatures above 860 K, the phonon signals agree with A 2/a symmetry but not in the temperature interval between 497 K and 860 K. In this temperature range new structural states give rise to additional phonon signals. A model based on mobile APBs between slabs of P2₁/a material, first proposed by van Heurck et al. (1991), is in qualitative agreement with our experimental observations.  相似文献   

Stability Analysis of the Climate-Vegetation System in the Northern High Latitudes   总被引：6，自引：0，他引：6  

Victor Brovkin  Samuel Levis  Marie-France Loutre  Michel Crucifix  Martin Claussen  Andrey Ganopolski  Claudia Kubatzki  Vladimir Petoukhov 《Climatic change》2003,57(1-2):119-138

The stability of the climate-vegetation system in the northern high latitudesis analysed with three climate system models of different complexity: A comprehensive 3-dimensional model of the climate system, GENESIS-IBIS, and two Earth system models of intermediate complexity (EMICs), CLIMBER-2 andMoBidiC. The biogeophysical feedback in the latitudinal belt 60–70° N, although positive, is not strong enough to support multiple steady states: A unique equilibriumin the climate-vegetation system is simulated by all the models on a zonal scale for present-day climate and doubled CO₂ climate.EMIC simulations with decreased insolation also reveal a unique steady state. However, the climate sensitivity to tree cover, T_F, exhibits non-linear behaviour within the models. For GENESIS-IBIS and CLIMBER-2, T_F islower for doubled CO₂ climate than for present-day climate due to a shorter snow season and increased relative significance ofthe hydrological effect of forest cover. For the EMICs, T_F is higher for low tree fraction than for high treefraction, mainly due to a time shift in spring snow melt in response to changes in tree cover. The climate sensitivity to tree coveris reduced when thermohaline circulation feedbacks are accounted for in the EMIC simulations. Simpler parameterizations of oceanic processes have opposite effects on T_F: T_F is lower in simulations with fixed SSTs and higher in simulations with mixed layer oceans. Experiments with transient CO₂ forcing show climate and vegetation not in equilibrium in the northern high latitudes at the end of the 20thcentury. The delayed response of vegetation and accelerated global warming lead to rather abrupt changes in northern vegetation cover in the first halfof the 21st century, when vegetation cover changes at double the present day rate.  相似文献   

Preliminary magnetic studies of lagoon and stream sediments from Chascomús Area (Argentina)—magnetic parameters as indicators of heavy metal pollution and some results of using an experimental method to separate magnetic phases     

Marcos A. E. Chaparro  Juan M. Lirio  Héctor Nuñez  Claudia S. G. Gogorza  Ana M. Sinito 《Environmental Geology》2005,49(1):30-43

Magnetic properties of lagoon and stream sediments from Chascomús area (Buenos Aires Province) and the relevance of various magnetic parameters as giving pollution status are studied in the present work. This work is focussed on magnetic parameters, such as concentration-dependent (magnetic susceptibility, saturation anhysteric and isothermal remanent magnetisation) and feature-dependent parameters (S-ratio, coercivity of remanence, anhysteric susceptibility/magnetic susceptibility-ratio), as pollution indicators. Firstly and most importantly, different magnetic parameters and chemical measurements were correlated in order to investigate their goodness, obtaining the best results for feature-dependent magnetic parameters. Coercivity of remanence correlate very well with chemical variables, showing correlations at high level of significance up to 0.9094, and the anhysteric susceptibility/magnetic susceptibility-ratio also shows very good correlations (up to 0.8376). Some results and advantages of using a new experimental method in order to discriminate hard and soft magnetic phases are also shown. This method uses alternately backfield isothermal remanent magnetisation and alternating field demagnetisation. From the experimental separation, the presence of hard magnetic phases in some samples was confirmed.  相似文献   

Going to the Extremes   总被引：8，自引：1，他引：8  

Claudia Tebaldi  Katharinec Hayhoe  Julie M. Arblaster  Gerald A. Meehl 《Climatic change》2006,79(3-4):185-211

Projections of changes in climate extremes are critical to assessing the potential impacts of climate change on human and natural systems. Modeling advances now provide the opportunity of utilizing global general circulation models (GCMs) for projections of extreme temperature and precipitation indicators. We analyze historical and future simulations of ten such indicators as derived from an ensemble of 9 GCMs contributing to the Fourth Assessment Report of the Intergovernmental Panel on Climate Change (IPCC-AR4), under a range of emissions scenarios. Our focus is on the consensus from the GCM ensemble, in terms of direction and significance of the changes, at the global average and geographical scale. The climate extremes described by the ten indices range from heat-wave frequency to frost-day occurrence, from dry-spell length to heavy rainfall amounts. Historical trends generally agree with previous observational studies, providing a basic sense of reliability for the GCM simulations. Individual model projections for the 21st century across the three scenarios examined are in agreement in showing greater temperature extremes consistent with a warmer climate. For any specific temperature index, minor differences appear in the spatial distribution of the changes across models and across scenarios, while substantial differences appear in the relative magnitude of the trends under different emissions rates. Depictions of a wetter world and greater precipitation intensity emerge unequivocally in the global averages of most of the precipitation indices. However, consensus and significance are less strong when regional patterns are considered. This analysis provides a first overview of projected changes in climate extremes from the IPCC-AR4 model ensemble, and has significant implications with regard to climate projections for impact assessments. An erratum to this article is available at . An erratum to this article can be found at  相似文献   

New Activity of Chiron: Results from 5 Years of Photometric Monitoring     

René DuffardDaniela Lazzaro  Sandro PintoJorge Carvano  Claudia AngeliAlvaro Alvarez Candal  Silvia Fernández 《Icarus》2002,160(1):44-51

The results of photometric observations of Centaur object Chiron carried out at the Observatório do Pico dos Dias (OPD, Brazil), the Estación Astrof?́sica de Bosque Alegre (EABA, Argentina), and Complejo Astronómico El Leoncito (CASLEO, Argentina) from 1997 to 2001 are presented here. The analysis of the photometric data shows that the brightness of Chiron reached a minimum value in 1999 and began increasing again in 2000. The absolute magnitude, H_V, varied from 7.26 in June 1999 to 5.78 in April 2001. The data tend to indicate that Chiron is starting a new outburst of activity which is compatible with a sporadic cometary behavior not related to heliocentric distance.  相似文献   

Structure and ageing of oceanic crust at 14°S on the East Pacific Rise     

Ingo Grevemeyer  Wilfried Weigel  & Claudia Jennrich† 《Geophysical Journal International》1998,135(2):573-584

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Eruption style and petrology of a new carbonatitic suite from the Mt. Vulture Southern Italy/: The Monticchio Lakes Formation     

Francesco Stoppa  Claudia Principe 《Journal of Volcanology and Geothermal Research》1997,78(3-4)

The Monticchio Lakes Formation MLF is a newly identified carbonatite-melilitite tuff sequence which is exposed in the southwestern sector of the Vulture volcano. It is the youngest example ca. 0.13 m.y. of this type of volcanism in Italy, although other carbonatites of smaller volume, but with similar characteristics, have been discovered recently. This volcanic event occurred in isolation after a 0.35 m.y. period of inactivity at Vulture. The eruption produced two maar-type vents and formed tuff aprons mainly composed of dune beds of lapilli. Depositional features suggest that a dry surge mechanism, possibly triggered by CO₂ expansion, was dominant during tuff emplacement. The MLF event involved a mixture of carbonatite and melilitite liquids which were physically separated before the eruption. Abundant mantle xenoliths are direct evidence of the deep-seated origin of the parental magma and its high velocity of propagation towards the surface. Often, these nodules form the core of lapilli composed of concentric shells of melilitite andror porphyritic carbonatite. Coarse-ash beds alternate with lapilli beds and consist of abundant lumps and spherulae of very fine-grained calcite immersed in a welded, highly compacted carbonatite matrix. Porphyritic carbonatite shells of the lapilli and fine-grained spherulae of calcite in the tuff matrix suggest incipient crystallisation of a carbonatite liquid in subvolcanic conditions and eruption of carbonatite-spray droplets. Dark coloured juvenile fragments mainly consist of melilite, phlogopite, calcite, apatite, perovskite, and häuyne crystals in a carbonatite or melilitite matrix. The rocks have an extremely primitive, ultramafic composition with very high Mga) 85. and Cr and Ni content 1500 ppm-. The calcite contains high SrO, BaO and REE of up to 1.5 wt.%. Similar compositions are typical of primary, magmatic carbonates which are found in both intrusive and extrusive carbonatites. The high modal Sr-Ba-REE-rich calcite, the typical mineralogy, and the high amount of Sr-group elements identify the carbonate component as a carbonatite. The very high Mga, mantle debris and C, O, He isotope ratios in the range of mantle values indicate a near-primary character for the carbonatite which is distinctive of a restricted group of extrusive carbonatites only found in continental rift areas.  相似文献   

The aging of gypsum in underground mines   总被引：1，自引：0，他引：1  

Christophe Auvray  Franoise Homand  Claudia Sorgi 《Engineering Geology》2004,74(3-4):183-196

The aging properties of gypsum extracted from two underground mines in France (Livry–Gargan and Grozon) have been highlighted by means of observation performed using scanning electron microscopy on samples taken along horizontal boreholes drilled through to the middle of several pillars. The aging process is exhibited by the presence of traces of dissolution (edges of the dissolved crystals, corroded crystalline surfaces, important intra- and intercrystalline space). These dissolution figures decrease in number and in intensity from the wall heading towards the middle of the pillar. The “older” pillars display a greater number of dissolution traces than the “more recent” pillars. Then, the role of the aging has been assessed by determining various physical and mechanical parameters on cylindrical samples of 38 mm in diameter and 76 mm in height, machined from the set of drilled boreholes. The following parameters have been quantified: density, grains density, total porosity, porosity accessible to water, intrinsic permeability to nitrogen, velocity of ultrasonic compression and shear waves, dynamic Young's modulus, dynamic Poisson's ratio, uniaxial compressive strength and static Young's modulus. Significant variations in parameter values between the wall and the middle of the pillar were recorded and recognized as being strongly correlated with the intensity of dissolution traces, and hence with gypsum aging.  相似文献   

Assessing streams in Germany with benthic invertebrates: Development of a multimetric invertebrate based assessment system   总被引：3，自引：0，他引：3  

Jürgen Bhmer  Claudia Rawer-Jost  Armin Zenker  Carolin Meier  Christian K. Feld  Regina Biss  Daniel Hering 《Limnologica》2004,34(4):416-432

The main aim of the study was to develop a multimetric assessment system for macroinvertebrate communities of small and mid-sized streams in Germany in accordance with the Water Framework Directive of the European Union. The system should be applicable by water authorities, capable of distinguishing between different impacts, and specifically adapted to all types of small and mid-sized rivers in Germany. An assessment system has been developed consisting of two modules based on the established indices for saprobic degradation and acidity, and a third module covering general degradation. For the third module a new multimetric index (MMI) was developed and tested using preclassifications for stream hydromorphological degradation, land use and general impairment as impact measures. More information on sampling method, season and the type of dominating human impairment allowed to further analyse the index' capabilities and sensitivity. It performed well in all seasons and detected all types of impairment except acidity. The usefulness of the impact measures used in this study is discussed with regard to the development of a multimetric index. The comparison of the new index with other indices showed that it is especially sensitive in detecting macroinvertebrate community responses to hydromorphological degradation and pollution such as the German AQEM index, while IBI 12 and Renkonen's similarity more reflect general community shifts caused by any type of disturbance. The new assessment system will be proposed for future use by state agencies for nationwide monitoring in the context of the Water Framework Directive implementation.  相似文献   

Quartz microstructures developed during non-steady state plastic flow at rapidly decaying stress and strain rate   总被引：7，自引：0，他引：7  

Claudia A. Trepmann  Bernhard Stckhert 《Journal of Structural Geology》2003,25(12):2035-2051

Synseismic loading to very high stresses (>0.5 GPa) and subsequent creep during stress relaxation in the uppermost plastosphere at temperatures of ca. 300–350 °C, near the lower tip of an inferred once seismically active crustal scale fault, was proposed based on peculiar microstructures identified in rocks exposed over >100 km² in the Sesia Zone, European Western Alps. Here we discuss the conspicuous and highly heterogeneous microstructural record of quartz in disseminated small-scale shear zones. Sub-basal deformation lamellae and arrays of elongate subgrains on the TEM-scale indicate an early stage of glide-controlled deformation at high stresses. Distributed brittle failure is indicated by healed microcracks. Very fine-grained recrystallised aggregates with a pronounced crystallographic preferred orientation reflect intense plastic flow by dislocation creep. Locally, a fine-grained foam microstructure indicates a final stage of static grain growth at low differential stress. For the previously inferred peak stresses of about 0.5 GPa and given temperatures, initial strain rates on the order of 10⁻¹⁰ s⁻¹ are predicted by available flow laws for dislocation creep of quartz. We emphasise the importance of short-term non-steady state deformation in the uppermost plastosphere underlying seismically active upper crust. The related heterogeneous record of quartz is governed by the local stress history at constant temperature.  相似文献