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231.
232.
Cytochrome c and ferricyanide reducing activities are measured in a Desulfovibrio desulfuricans (strain ATCC No. 17990) that indicate that the APS reductase activity is constitutive. This enzymatic activity is also measured in a Saanich Inlet isolate identified as Desulfovibrio salexigens (Saanich). Successful measurement of the Cytochrome c reducing activity was also made in the sediment extracts from Saanich Inlet, and this activity was found to be present in sediments as deep as 50 cm. Bacterial biomass distributions were estimated using measurements of ATP in the Saanich Inlet sediments. ETS activity measurements correlated well with the in situ [35S]-SO42? reduction rate measurements; both of the methods showing a subsurface maximum in activity at a depth of about 10 cm. However, some differences between the results obtained from these two procedures were also found, e.g., the in situ [35S]-SO42? reduction activity approximated zero values at or near 25 cm depth, while 5–10% of the surface ETS activity was present at a depth of as much as 50 cm. The hypothesis presented is that the subsurface maximum may be due to the anaerobic oxidation of methane by [35S]-SO42? ions as mediated by the sulfate-reducing bacteria. A discussion of the strong interactive relationships between a variety of organisms in an ecosystems context, so necessary in bringing about organic matter diagenesis in anoxic marine environments, is also presented. 相似文献
233.
Ben De Mol Max Kozachenko Andy Wheeler Hugo Alvares Jean-Pierre Henriet Karine Olu-Le Roy 《International Journal of Earth Sciences》2007,96(1):103-120
High-resolution seismic profiles, swath bathymetry, side-scan sonar data and video imageries are analysed in this detailed
study of five carbonate mounds from the Belgica mound province with special emphasis on the well-surveyed Thérèse Mound. The
selected mounds are located in the deepest part of the Belgica mound province at water depths of 950 m. Seismic data illustrate
that the underlying geology is characterised by drift sedimentation in a general northerly flowing current regime. Sigmoidal
sediment bodies create local slope breaks on the most recent local erosional surface, which act as the mound base. No preferential
mound substratum is observed, neither is there any indication for deep geological controls on coral bank development. Seismic
evidence suggests that the start-up of the coral bank development was shortly after a major erosional event of Late Pliocene–Quaternary
age. The coral bank geometry has been clearly affected by the local topography of this erosional base and the prevailing current
regime. The summits of the coral banks are relatively flat and the flanks are steepest on their upper slopes. Deposition of
the encased drift sequence has been influenced by the coral bank topography. Sediment waves are formed besides the coral banks
and are the most pronounced bedforms. These seabed structures are probably induced by bottom current up to 1 m/s. Large sediment
waves are colonised by living corals and might represent the initial phase of coral bank development. The biological facies
distribution of the coral banks illustrate a living coral cap on the summit and upper slope and a decline of living coral
populations toward the lower flanks. The data suggest that the development of the coral banks in this area is clearly an interaction
between biological growth processes and drift deposition both influenced by the local topography and current regime. 相似文献
234.
Fitting semivariograms with analytical models can be tedious and restrictive. There are many smooth functions that could be
used for the semivariogram; however, arbitrary interpolation of the semivariogram will almost certainly create an invalid
function. A spectral correction, that is, taking the Fourier transform of the corresponding covariance values, resetting all
negative terms to zero, standardizing the spectrum to sum to the sill, and inverse transforming is a valuable method for constructing
valid discrete semivariogram models. This paper addresses some important implementation details and provides a methodology
to working with spectrally corrected semivariograms. 相似文献
235.
Robert N. Clayton Glenn J. MacPherson Ian D. Hutcheon Andrew M. Davis Lawrence Grossman Toshiko K. Mayeda Carol Molini-Velsko John M. Allen Ahmed El Goresy 《Geochimica et cosmochimica acta》1984,48(3):535-548
We have discovered two FUN inclusions, CG-14 and TE, among a group of five forsterite-rich inclusions in Allende, two of which are described for the first time herein. All five consist of euhedral forsterite and spinel crystals poikilitically enclosed by fassaite. Forsterite and spinel are usually segregated from one another, sometimes into a spinel-rich mantle and a forsterite-rich core. Some inclusions contain vesicles, indicating that they were once molten. The crystallization sequence inferred from textures is: spinel, forsterite, fassaite and, finally, Mg-rich melilite. One concentrically-zoned inclusion contains melilite in its mantle whose composition lies on the opposite side of the liquidus minimum in the melilite binary from that in its core. This suggests that segregation of forsterite from spinel in all of these inclusions could be due to volatilization of MgO and SiO2 relative to Al2O3 and CaO from the outsides of droplets. CG-14 is relatively uniformly enriched in refractory elements relative to Cl chondrites by a factor similar to that for Ca-, Al-rich coarse-grained inclusions except for Ca, Al and Hf which are unusually low. No Ce anomaly such as found in FUN inclusions Cl and HAL is present in CG-14. Whole-rock samples of CG-14 and TE are more strongly mass-fractionated in oxygen relative to “normal” Allende inclusions than the FUN inclusion EK 1-4-1 and less so than Cl. Relative to bulk Allende, both inclusions have strongly massfractionated magnesium and silicon and 25Mg excesses or deficits of 24Mg or 26Mg. CG-14 has a 29Si excess or a deficit of 28Si or 30Si. Volatilization loss cannot be responsible for the magnesium and silicon isotope fractionations, as this would require prohibitively large mass loss from these magnesium-rich inclusions. The remarkable similarity in textures between FUN and non-FUN inclusions implies similar thermal histories, arguing against different rates of evaporative loss of major elements. Sputtering alone may be insufficient to account for the magnitude and direction of oxygen isotope fractionation in FUN inclusions. 相似文献
236.
Oxygen isotopic compositions of minerals in 22 samples of submarine gabbros were determined. The gabbros were collected using the submersible Alvin from the 700 m vertical section of the rift-valley wall of the Mid-Cayman spreading center. Our study indicates that in the Mid-Cayman Rise seawater barely reached the bottom of the plutonic layer. Abundant seawater penetration (water/rock mass ratio > 1) was limited to the upper part of the plutonic layer. From the observed oxygen isotopic compositions of coexisting minerals, and from the experimental and empirical determinations of equilibrium fractionation of oxygen isotopes for mineral-water, and mineral-mineral pairs, we show the following: (1) pyroxene and olivine did not exchange oxygen with seawater, (2) plagioclase is in isotopic disequilibrium with pyroxene; (3) the rate of oxygen exchange in plagioclase was not slowed by the absence of cation exchange; (4) plagioclase and amphibole have exchanged oxygen with seawater or isotopically modified seawater (δ18O ≤ 3%.); and (5) amphibole has exchanged or acquired (during formation) hydrogen from seawater at 380°C ≤ T ≤ 600°C. The decrease in extent of isotopic exchange of plagioclase and the decrease in amphibole abundance with depth indicate that seawater flux decreased rapidly with depth (water/rock mass ratio falling from 1.7 to 0.2 over a 300 m interval). 相似文献
237.
Alan Matthews Julian R. Goldsmith Robert N. Clayton 《Geochimica et cosmochimica acta》1983,47(3):645-654
Oxygen isotope fractionations between zoisite and water have been studied at 400–700°C, PH2O = 13.4 kbar, using the three-isotope method described by Matsuhisaet al. (1978) and Matthewset al. (1983a). The zoisite-waier exchange reaction takes place extremely slowly and consequently direct-exchange calibration of equilibrium fractionation factors was possible only at 600 and 700°C. Fractionation factors at 400–600°C were determined from samples hydrothermally crystallized from a glass of the anhydrous zoisite composition. At 600°C, both exchange procedures gave identical fractionations within experimental error. Scanning electron microscope studies showed that the zoisite-water exchange reaction occurs largely by solution-precipitation mass-transfer mechanisms. The slow kinetics of zoisite-water exchange may be typical of hydrous silicates, since additional experiments on tremolite-water and chlorite-water exchange also showed very low rates. When the zoisite-water fractionation factors determined in this study are combined with the quartz and albite-water data of Matsuhisaet al. (1979) and the calcite-water data of O'Nellet al. (1969), mineral-pair fractionations are obtained for which the coefficients “A” in the equation 1000 In α = A × 106T?2 are:
Ab | Cc | Zo | |
Q | 0.50 | 0.50 | 1.56 |
Ab | 0.00 | 1.06 | |
Cc | 1.06 |