Quantification of mineral matter in the Argonne Premium Coals using interactive Rietveld-based X-ray diffraction     

Colin R. Ward  John C. Taylor  C. E. Matulis  L. S. Dale 《International Journal of Coal Geology》2001,46(2-4)

The mineral matter in the eight reference North American coal samples of the Argonne Premium Coal series has been investigated on a quantitative basis using X-ray diffraction (XRD) techniques. X-ray diffraction data obtained from electronic low-temperature (oxygen–plasma) ash (LTA) residues, from ashes produced by heating the coals in air at 370°C, and also from the raw coals themselves, were evaluated using an interactive data processing system ( ™) based on Rietveld interpretation methods. The results from the three types of material (LTA, 370°C ash and raw coal) were compared for each sample. This allowed the components present in the raw coals in crystalline form to be recognised separately from mineral artifacts produced, particularly in the low-rank coals, from interaction of organically associated elements (Ca, S, etc.) during the two ashing processes.After the allowance for the production of any artifacts, the quantitative mineral assemblages identified from XRD of the raw coals were found to be consistent, even for coals having a relatively low ash percentage (around 5%), with the results obtained from the respective mineral concentrates prepared by the ashing methods. The effects of heating the coal to 370°C could also be distinguished, relative to the raw coal or the LTA, through changes in components such as pyrite and the clay minerals.Although some areas of uncertainty exist, particularly with magnesium in the low-rank coals, the calculated chemical compositions of the coal ash derived from the mineral mixtures identified for each coal were also found to be consistent with the results of direct chemical analysis of the respective coal ash materials.  相似文献   

A case example of near-surface correction for multicomponent VSPS     

Xinwu Zeng  Colin MacBeth 《Geophysical Prospecting》1996,44(5):889-910

A deterministic near-surface correction procedure is developed for multicomponent VSP data, shot using directional sources and recorded using three-component receivers. The method is capable of removing unwanted effects of acquisition such as unequal source strengths or misorientations, but may also remove near-surface multiples and anisotropy. This is of considerable benefit for obtaining accurate and consistent estimates of subsurface anisotropy from different source combinations. Application of the technique is illustrated using a dataset from the Romashkino reservoir in Russia, where three or four different directional sources are used at the same source locations. The technique corrects for the large discrepancies which exist between the estimates obtained using different source combinations. Application of the technique to three wells in the survey region reveals a nearly isotropic subsurface, except for a few isolated zones of moderate to high (2 to 8%) anisotropy which lie close to the expected depth for the reservoir. Although there is no significant correlation with the production figures for each well, the qS1 polarization azimuth within the reservoir does vary at each well location, suggesting that this may be a more sensitive indicator of reservoir Drocess.  相似文献   

Biotransformation at 10° C of Di-n-Butyl Phthalate in Subsurface Microcosms     

Christian Chauret  William E. Inniss  Colin I. Mayfield 《Ground water》1996,34(5):791-794

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Storm solute behaviour in a montane Mediterranean forested catchment     

Anna vila  Josep Piol  Ferran Rod  Colin Neal 《Journal of Hydrology》1992,140(1-4):143-161

The results of an extensive study of streamwater chemistry during stormflow events, for a montane Mediterranean area, are presented. Four groups of variables are identified as having contrasting behaviour: alkalinity and pH; nitrate and potassium; sulphate and chloride; sodium, calcium and magnesium. The results show a complex pattern of response to flow that can be broadly linked to: (1) antecedent hydrological conditions; (2) rainfall intensity; (3) supplies of water from chemically distinct areas within the catchment. However, comparisons between this study and a parallel one which examined the composition of waters within the catchment, show that it is presently impossible to quantify the relative supplies from each part of the catchment. The findings are reviewed in relation to analogous studies within a European setting and in relation to modelling initiatives.  相似文献   

Environmental management in Antarctica Instruments and institutions     

Colin M. Harris  Janice Meadows 《Marine pollution bulletin》1992,25(9-12):239-249

Instruments and institutions for environmental management in Antarctica have evolved from beginnings in the Antarctic Treaty, with subsequent introduction of the Convention for the Conservation of Antarctic Seals, the Convention on the Conservation of Antarctic Marine Living Resources, and recommendations made at Treaty meetings. The Protocol on Environmental Protection to the Antarctic Treaty will improve existing provisions for environmental management in Antarctica. When it enters into force the Protocol will apply to all activities in the Treaty area: it provides rules for environmental impact assessment, conservation of fauna and flora, disposal of wastes, prevention of marine pollution and specially protected and managed areas. The Protocol's Committee for Environmental Protection will facilitate discussion and advice on environmental management. Management of information is a vital part of ensuring measures are effective. The Protocol should be ratified quickly to improve the basis for environmental protection, but the test will be whether and how it is implemented in practice.  相似文献   

Lateral migration,thermoluminescence chronology and colour variation of longitudinal dunes near Birdsville in the Simpson Desert,central Australia     

G. C. Nanson  X. Y. Chen  D. M. Price 《地球表面变化过程与地形》1992,17(8):807-819

The longitudinal dunes of the Simpson Desert, in the vicinity of Birdsville, have been reworked largely during the Holocene from dunes deposited up to 80000 years ago or earlier. The widespread asymmetry of these roughly northward-trending dunes, with steeper eastern faces and more gentle western faces, supports wind-rose data showing sand-transporting winds from the southwest obliquely intersecting the dunes. While this suggests a change in the wind pattern since the dune field was oriented, it does not indicate that the dunes are necessarily shifting leeward (eastward) as a consequence. It is hypothesized that the direction of migration is controlled by the extent to which the dunes are vegetated. Relatively well-vegetated dunes can accrete sand on their gentle stoss slopes and erode on their lee slopes causing them to shift westward and hence obliquely into the wind, a condition that probably prevails in wetter regions and during episodes of relatively humid climate. In contrast, in very dry areas or during arid phases, sand can move unimpeded up a sparsely vegetated stoss face and over the crest to form an avalanche or slip face on the lee side, thereby causing the dunes to shift eastward. Despite evidence that longitudinal dune crests can shift laterally to some extent, the dunes in the western part of the Simpson Desert have not migrated, either westward or eastward, more than 100m or so from their Pleistocene cores. Aeolian transport and partial or complete removal of iron cutans from around quartz grains results in dunes of widely varying colour yet of similar age.  相似文献   

Sedimentological evaluation of general circulation model simulations for the “greenhouse” Earth: Cretaceous and Jurassic case studies     

G. D. Price  B. W. Sellwood  P. J. Valdes 《Sedimentary Geology》1995,100(1-4)

Conceptual climate models, based on the workings of the present-day climate system, provided a first-order approach to ancient climate systems. They are potentially very subjective in character. Their main drawback was that they involved the relocation of continents beneath a stable atmospheric circulation modelled upon that of the present. General circulation models (GCMs) use the laws of physics and an understanding of past geography to simulate climatic responses. They are objective in character. However, they require super computers to handle vast numbers of calculations. Nonetheless it is now possible to compare results from different GCMs for a range of times and over a wide range of parameterisations. GCMs are currently producing simulated climate predictions which compare favourably with the distributions of climatically sensitive facies (e.g. coals, evaporites and palaeosols). They have been used effectively in the prediction of oceanic upwelling sites and the distribution of petroleum source-rocks and phosphorites. Parameterisation is the main weakness in GCMs (e.g. sea-surface temperature, orography, cloud behaviour). Sensitivity experiments can be run on GCMs which simulate the effects of Milankovitch forcing and thus provide insights into possible patterns of climate change both globally and locally (i.e. provide predictions that can be evaluated against the rock record). Future use of GCMs could be in the forward modelling of sequence stratigraphic evolution and in the prediction of the diagenetic characteristics of reservoir units in frontier exploration areas. The sedimentary record provides the only way that GCMs may themselves be evaluated and this is important because these same GCMs are being used currently to predict possible changes in future climate.  相似文献   

Apollo 16 neutron stratigraphy     

G. Price Russ 《Earth and Planetary Science Letters》1973,19(2):275-289

The Apollo 16 soils have the largest low energy neutron fluences (up to 10¹⁷ n/cm², E < 0.18eV) yet observed in lunar samples. Variations in the isotopic ratios ¹⁵⁸Gd/¹⁵⁷Gd and ¹⁵⁰Sm/¹⁴⁹Sm (up to 1.9% and 2.0% respectively) indicate that the low energy neutron fluence in the Apollo 16 drill stem increases with depth throughout the section sampled. Such a variation implies that accretion has been the dominant regolith “gardening” process at this location. The data may be fit by a model of continuous accretion of pre-irradiated material at a rate of ～70 g/(cm² · 10⁸yr) or by models involving as few as two slabs of material in which the first slab could have been deposited as long as 10⁹ yr ago.The ratio of the number of neutrons captured per atom by Sm to the number captured per atom by Gd is lower than in previously measured lunar samples, which implies a lower energy neutron spectrum at this site. The variation of this ratio with chemical composition is qualitatively similar to that predicted by Lingenfelter, Canfield and Hampel.Variations are observed in the ratio ¹⁵²Gd/¹⁶⁰Gd which are fluence correlated and probably result from neutron capture by¹⁵¹Eu.  相似文献   

The theory of geomagnetic induction     

Albert T. Price 《Physics of the Earth and Planetary Interiors》1973,7(3):227-233

The theoretical basis of electromagnetic induction methods in geophysics is considered with special reference to the interplay of physical ideas and mathematical arguments. The design of mathematical problems to elucidate observed physical phenomena, and methods of solving them, are discussed. Earth models suitable for various types of investigation are considered. The importance of getting the correct physical interpretation of the solution of a mathematical problem is stressed.  相似文献   

High Resolution Radio Observations of Luminous IR Galaxies     

Colin J. Lonsdale 《Astrophysics and Space Science》1999,266(1-2):119-124

High resolution radio observations provide a unique tool for investigation ofultraluminous infrared galaxies, due to the combination of high angularresolution and source transparency available at centimeter wavelengths. Thetypical angular size of the IR emitting region in the most luminous systems isof order 0.1 arcsec, while dust absorption appears to obscure this region fromdirect view at wavelengths shorter than 100 microns. Radio observationswith VLBI and MERLIN are revealing compact radio structures indicative of bothstarburst and AGN activity in these systems. Additional observations arerequired to clarify relationships between radio structures and the energygeneration mechanisms, and to realize the full potential of radio interferometryfor ULIRG studies.  相似文献