Microbial activity and chemical weathering in the Middendorf aquifer,South Carolina     

Jungho Park  Robert A. Sanford  Craig M. Bethke 《Chemical Geology》2009,258(3-4):232-241

We use reactive transport modeling to better understand the kinetics of chemical weathering in the Cretaceous Middendorf aquifer of South Carolina, USA, and the relationship of this process to subsurface microbial activity. We constructed a model accounting for the kinetics of mineral dissolution and precipitation, ion exchange, and the CO₂ and bicarbonate produced by iron reducing and sulfate reducing bacteria in the aquifer. We then fit the model to observed trends in the chemical composition of groundwater along the aquifer by adjusting the rate constants for the kinetic reactions considered. The modeling portrays weathering in the Middendorf as a slow process by which groundwater gradually reacts toward equilibrium with minerals in the aquifer. The rate constants predicted are 6 to 7 orders of magnitude smaller than measured in laboratory experiments and 3 to 4 orders of magnitude less than those inferred from weathering rates in soils. The rate constants are smaller even than expected by projecting observed trends with the duration of weathering to the geologic age of the Middendorf. Weathering is driven largely by biological activity: about half the acid consumed is CO₂ derived from the recharge area, and about half is supplied by iron reducing bacteria in the aquifer; only about 1% of the acid is of atmospheric origin, from CO₂ dissolved in rainwater.  相似文献   

Hypothesis for the origin of convergent margin granitoids and Earth’s continental crust by thermal migration zone refining   总被引：2，自引：0，他引：2  

Craig Lundstrom   《Geochimica et cosmochimica acta》2009,73(19):5709-5729

The production of Earth’s granitoids is generally attributed to magma intrusion, fractional crystallization and assimilation but the details of how granitoid plutons form remains widely debated. In light of recent experimental results which indicate that partially molten wet andesite in a temperature gradient evolves into a granitic bulk composition at the cooler end of the gradient (in a process called thermal migration), I present a model for at least some of Earth’s granitoids forming by a top-down thermal migration zone refining process. According to this model, convergent margin igneous activity builds a thick volcanic pile which becomes a barrier to further ascent of magma, leading to magma underplating by injection of sills at the base of the pile. When magmas arrive at the location of underplating, they react and release heat and water to the overlying materials (previously intruded sills), resulting in a downward moving zone having a near-steady-state temperature gradient. This leads to compositional differentiation by wet thermal migration taking place over million year time scales; this in situ differentiation process occurs in the middle of the underplated region but not on the more rapidly cooled edges of the sills. Modeling using the IRIDIUM program shows this process can produce sequences of granitoid that are kilometer or greater in thickness; regardless of granitoid thickness, the bottom of the system maintains a near constant thickness of hornblende gabbros. The model provides a logical connection between andesitic stratovolcanoes and underlying, more silicic intrusive series plutons—both reflect ascent of andesitic composition magmas, with the implication that convergent margin magmatic systems evolve temporally from stratovolcanoes to plutons once magma ascent is inhibited and underplating begins.The model provides an alternative to the standard view that granitoids result from cooling of large bodies of magma and could help to resolve long-standing questions concerning: geophysical observations of magma chambers; the compositions of minerals in granitoids; and the development of preferred mineral orientations in granitoids. It provides a consistent model in that it explains the systematic normal compositional zoning of plutons within the context of an incremental growth process dictated by geochronology. Most importantly, the model is predictive, emphasizing the importance of examining granitoids in the vertical dimension. The hypothesis that thermal migration plays a role in granitoid formation can be tested by analysis of non-traditional stable isotope systems such as Fe, Mg and Si that should show a signature of thermal diffusion. The model predicts that the tops of overlying granitoids will have relatively heavy isotopic compositions whereas underlying hornblende gabbros will have relatively light isotopic compositions. Examination of existing iron isotope data and new silicon isotope data are consistent with the hypothesis and point to the need for more thorough testing.  相似文献   

Raman spectroscopy and biomarker analysis reveal multiple carbon inputs to a Precambrian glacial sediment     

Alison Olcott Marshall  Frank A. Corsetti  Alex L. Sessions  Craig P. Marshall 《Organic Geochemistry》2009,40(11):1115-1123

Extractable biomarkers can help elucidate the environment and biota of ancient glaciations, although the method must be applied with care, as glacial sediments have a potential for incorporation of older detrital carbon. In Phanerozoic glacial sediments, the distinct elemental, molecular and isotopic compositions of the terrestrial and marine biomass allow discrimination between primary marine and redeposited terrestrial organic matter. However, as the Proterozoic biosphere was largely microbial and marine, biomarker and isotopic analyses are insufficient for distinguishing primary organic matter from secondary reworked organic matter. Here, we report the combined application of Raman spectroscopy and biomarker analysis to Precambrian glacial sediments, which, together, allows discrimination between mixed pools of organic carbon and provides a promising new approach for rapidly screening Precambrian sediments for immature organic matter amenable to biomarker analysis.  相似文献   

Cognitive and Affective Predictors of Illinois Residents’ Perceived Risks from Gray Wolves     

Adam C. Landon  Maarten H. Jacobs  Craig A. Miller  Jerry J. Vaske  Brent D. Williams 《社会与自然资源》2020,33(5):574-593

Abstract

Increasing wolf populations are a concern for wildlife managers in the Midwestern U.S. Understanding the psychological mechanisms that contribute to public perceptions of risk will enable development of strategies that seek to mitigate these risks, and suggest where outreach efforts may facilitate acceptance of wolves. We examined the psychological factors that influence Illinois residents’ perceived risks from wolves. We hypothesized that individuals’ perceived risks from wolves were a function of their attitudes toward wolves, negative affect toward wolves, and basic beliefs about wildlife. Data were obtained from a survey of the Illinois public (n?=?784). Negative affect and attitudes toward wolves were direct predictors of perceived risks. Basic beliefs predicted attitudes and negative affect toward wolves. Negative affect predicted attitudes. Basic beliefs had direct and indirect effects on perceived risks.  相似文献   

Sea‐level rise impact on fresh groundwater lenses in two‐layer small islands          下载免费PDF全文

Hamed Ketabchi  Davood Mahmoodzadeh  Behzad Ataie‐Ashtiani  Adrian D. Werner  Craig T. Simmons 《水文研究》2014,28(24):5938-5953

The fresh groundwater lenses (FGLs) of small islands can be highly vulnerable to climate change impacts, including sea‐level rise (SLR). Many real cases of atoll or sandy islands involve two‐layer hydrogeological conceptualizations. In this paper, the influential factors that affect FGLs in two‐layer small islands subject to SLR are investigated. An analytical solution describing FGLs in circular islands, composed of two geological layers, is developed for the simplified case of steady‐state and sharp‐interface conditions. An application of the developed model is demonstrated to estimate the FGL thickness of some real‐world islands by comparison with existing FGL thickness data. Furthermore, numerical modelling is applied to extend the analysis to consider dispersion effects and to confirm comparable results for both cases. Sensitivity analyses are used to assess the importance of land‐surface inundation caused by SLR, relative to other parameters (i.e. thickness of aquifer layers, hydraulic conductivity, recharge rate and land‐surface slope) that influence the FGL. Dimensionless parameters are used to generalize the findings. The results demonstrate that land‐surface inundation has a considerable impact on a FGL influenced by SLR, as expected, although the FGL volume is more sensitive to recharge, aquifer thickness and hydraulic conductivity than SLR impacts, considering typical parameter ranges. The methodology presented in this study provides water resource managers with a rapid‐assessment tool for evaluating the likely impacts of SLR and accompanying LSI on FGLs.  相似文献   

Complex zoning between super-calcic pigeonite and augite from the Graveyard Point sill, Oregon: a record of the interplay between bulk and interstitial liquid fractionation     

Gregor Markl  Craig White 《Contributions to Mineralogy and Petrology》1999,137(1-2):170-183

The 150 m thick late Miocene Graveyard Point sill (GPS) is situated at the Idaho-Oregon border near the southwestern edge of the western Snake River Plain. It records from bottom to top continuous fractional crystallization of a tholeiitic parent magma (lower chilled border, FeO/(FeO+MgO) = 0.59, Ni = 90 ppm) towards granophyres (late pods and dikes, FeO/(FeO+MgO) = 0.98, 78 wt% SiO₂ 3.5 wt% K₂O, <4 ppm Ni) showing a typical trend of Fe and P enrichment. Fractionating minerals are olivine (Fo₇₉-Fo₂), augite (X _Fe = 0.18−0.95), feldspars (An₈₀Or₁-An₁Or₆₂), Fe-Ti oxides (Ti-rich magnetite and ilmenite), apatite and in two samples super-calcic pigeonite (Wo_18–28 Fs_41–54). The granophyres may bear some quartz. Compositionally zoned minerals record a large interval of the fractionation process in every single sample, but this interval changes with stratigraphic height. In super-calcic pigeonite-bearing samples, olivine is scarce or lacking and because super-calcic pigeonite occurs as characteristic overgrowths on augite, its formation is interpreted to be related to the schematic reaction: augite + olivine (component in melt) + SiO₂ (in melt) = pigeonite, that defines the cotectic between augite and pigeonite in olivine-saturated basaltic systems. Line measurements with the electron microprobe reveal that the transition from augite to super-calcic pigeonite is continuous. However, some crystals show an abrupt “reversal” towards augite after super-calcic pigeonite growth. Two processes compete with each other in the GPS: fractional crystallization of the bulk liquid (the bulk melt separates from solids and interstitial liquids in the solidification front) and fractional crystallization of interstitial melt in the solidification front itself. Interplay between those two processes is proposed to account for the observed variations in mineral chemistry and mineral textures. Received: 25 November 1998 / Accepted: 14 June 1999  相似文献   

In Situ Chemical Treatment: A Love‐Hate Relationship          下载免费PDF全文

Suthan Suthersan  Jeff McDonough  Matt Schnobrich  Craig Divine 《Ground Water Monitoring & Remediation》2017,37(1):17-26

  相似文献   

Closed Analytic Elements with Flexible Geometry          下载免费PDF全文

Mark Ranjram  James R. Craig 《Ground water》2018,56(5):816-822

A simple and fast treatment of hydrogeologic features with irregularly shaped boundaries in two‐dimensional analytic element groundwater flow models is presented. The star domain shapes of the features are restricted to closed shapes represented as smooth and continuous single‐valued functions of distance from a focus point, . The element can be used to treat a variety of boundary and continuity conditions, including those of irregularly shaped lakes or heterogeneities in hydraulic conductivity. The new element is demonstrated via some simple illustrative test cases and shown to be efficient, accurate, and much simpler to implement than existing solutions for irregular shapes.  相似文献   

Grain Size Analysis and Permeametry for Estimating Hydraulic Conductivity in Engineered Porous Media     

Allison Cormican  J.F. Devlin  Craig Divine 《Ground Water Monitoring & Remediation》2020,40(2):65-72

Grain size analysis and permeametry are common methods for estimating the hydraulic conductivity (K) of porous media. It is well known that these methods have limited accuracy when they are used to characterize natural sediments. However, hydrogeological research has increasingly introduced technologies dependent on engineered porous media that may be less problematic because complex geologic structures are eliminated in the lab and field-scale packings. The recently introduced Horizontal Reactive Media Treatment Wells (HRX® Wells), for in situ, passive remediation of groundwater is one such example. The HRX Well passively collects groundwater and directs it through a horizontal pipe packed with an engineered porous medium. In this project, grain size analysis was conducted for sand and sand-iron mixtures to estimate K using the 16 algorithms provided in the HydrogeoSieveXL2.3.2 software. The results were compared to K determined by permeametry and a field-scale column, 30 cm long and 25 cm in diameter, representing an HRX Well. The best comparability of K estimates from grain size analysis and permeametry were obtained using the USBR, Slichter, and Shepherd K estimation methods. These also showed good agreement between lab-scale and field-scale K estimations, with reproducibility within the range ±20%. This study shows that laboratory K estimations can be representative across various relevant scales, including the field-scale, for engineered porous media. This finding extends to filter packs, and other engineered porous media design methods by emphasizing and demonstrating one case of accuracy in lab-scale permeability estimation for field-scale implementations.  相似文献   

Hydraulic Performance of the Horizontal Reactive Media Treatment Well: Pilot and Numerical Study     

Blossom N. Nzeribe  Wen Li  Michelle Crimi  Guangming Yao  Craig E. Divine  Jeff McDonough  Jack Wang 《Ground Water Monitoring & Remediation》2020,40(3):30-41

This study is focused on a passive treatment system known as the horizontal reactive treatment well (HRX Well®) installed parallel to groundwater flow, which operates on the principle of flow focusing that results from the hydraulic conductivity (K) ratio of the well and aquifer media. Passive flow and capture in the HRX Well are described by simplified equations adapted from Darcy's Law. A field pilot-scale study (PSS) and numerical simulations using a finite element method (FEM) were conducted to verify the HRX Well concept and test the validity of the HRX Well-simplified equations. The hydraulic performance results from both studies were observed to be within a close agreement to the simplified equations and their hydraulic capture width approximately five times greater than the well diameter (0.20 m). Key parameters affecting capture included the aquifer thickness, well diameter, and permeability ratio of the HRX Well treatment media and aquifer material. During pilot testing, the HRX Well captured 39% of flow while representing 0.5% of the test pit cross-sectional volume, indicating that the well captures a substantial amount of surrounding groundwater. While uncertainty in the aquifer and well properties (porosity, K, well losses), including the effects of boundary conditions, may have caused minor differences in the results, data from this study indicate that the simplified equations are valid for the conceptual design of a field study. A full-scale HRX Well was installed at Site SS003 at Vanderberg Air Force Base, California, in July/August 2018 based on outcomes from this study.  相似文献