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81.
Combining Lu–Hf garnet geochronology with in situ trace element analyses in garnet allowed us to gain new insight into the metamorphic evolution of UHP–UHT rocks in the Stary Gierałtów region, in the Polish Sudetes. Prograde garnet growth recorded by Rayleigh-type heavy REE (HREE) zoning in the felsic granulites indicates that the obtained 386.6 ± 4.9 Ma Lu–Hf age represents the time of garnet crystallization on a prograde UHP metamorphic path. The surrounding rocks were metamorphosed at the same time as indicated by 381.2 ± 6.7 Ma Sm–Nd garnet age obtained for the mid-crustal metapelites. The second metamorphic episode, which affected most of the lower crust in the Orlica–Śnieżnik Massif (OSM) occurred at ca. 340 Ma as determined by U–Pb zircon and Sm–Nd garnet dating of granulites in this and previous studies is interpreted as a high temperature event, which took place on a retrograde path.

Trace element distribution in garnets from the layered granulites showed significant differences in distribution of medium and HREE in garnets from mafic and felsic protoliths over the course of the metamorphic evolution. This had strong impact on the isotopic dating results and led to “decoupling” of the Sm–Nd and Lu–Hf clocks, which recorded timing of the two different metamorphic episodes separated by as much as 40 Ma. Moreover, the preservation of the HREE growth zonation profile in garnets from the felsic granulites whose minimum metamorphic temperature was established at 900 °C implies that the Lu–Hf system under relatively dry conditions does not undergo significant diffusional re-equilibration even at such extreme temperatures and therefore it sill provides the age of prograde garnet growth. Under hydrous conditions, at least some resetting will take place, as documented by the partially relaxed HREE zonation profile in the amphibolitised mafic granulite, which yielded a 10 Ma younger age. The HREE distribution study appeared to be a particularly valuable and essential tool, which allowed us to distinguish garnet growth from post-growth complexities and hence, provide improved age interpretation. Medium REE, on the other hand, did not show any obvious correlation with the isotopic signature of garnet.

Two distinct metamorphic episodes recorded in the Stary Gierałtów region show that buoyancy-driven uplift of UHP rocks can be arrested at the base of a continental crust if not supported by any additional force. In our case study, the UHP rocks would have never reached the surface if their uplift had not been resumed after a long pause under a different tectonic regime. The multistage, discontinuous uplift revealed by the UHP rocks of the OSM provides a new scenario for the exhumation of continental crust from mantle depths distinct from the fast-track exhumation histories recognized in UHP terranes elsewhere.  相似文献   

82.
Human activities in the Arctic are often mentioned as recipients of climate-change impacts. In this paper we consider the more complicated but more likely possibility that human activities themselves can interact with climate or environmental change in ways that either mitigate or exacerbate the human impacts. Although human activities in the Arctic are generally assumed to be modest, our analysis suggests that those activities may have larger influences on the arctic system than previously thought. Moreover, human influences could increase substantially in the near future. First, we illustrate how past human activities in the Arctic have combined with climatic variations to alter biophysical systems upon which fisheries and livestock depend. Second, we describe how current and future human activities could precipitate or affect the timing of major transitions in the arctic system. Past and future analyses both point to ways in which human activities in the Arctic can substantially influence the trajectory of arctic system change.  相似文献   
83.
Pyrite: physical and chemical textures   总被引:9,自引:0,他引:9  
Pyrite may crystallize initially in forms as diverse as framboids or cubes depending upon the temperatures and pressures. Fluid-rich diagenesis or low-grade metamorphism clearly results in thorough recrystallization and the common formation of cubes. Once these have formed, the pyrite becomes much more refractory and retains many characteristics even in deposits which have undergone penetrative deformation. This is in strong contrast to the behavior of most of the accompanying sulfides, which often undergo ductile deformation, solid state or chemical remobilization, and annealing. Pyrite deforms sparingly until there is brittle failure; however, there may be significant pyrite corrosion and regrowth during metamorphism as the result of sulfur exchange with other minerals, especially pyrrhotite. Pyrite fabrics may also be significantly modified by pressure solution or Coble creep. Optical microscopic examination and electron microprobe chemical mapping of pyrites from a variety of mineral deposits, including several high-grade metamorphic ones, reveals that the pyrites frequently contain both physical and chemical textures that may be interpreted in terms of the depositional and the post-depositional history of the deposits. Inclusions of sulfides or other minerals reveal information on the timing of the crystallization or recrystallization of the pyrite; chemical mapping of elements such as Ni, Co, and As reveals information on the relative time of transport of these elements in the ore fluids. Received: 19 March 1997 / Accepted: 14 May 1998  相似文献   
84.
Magnesium self-diffusion coefficients were determined experimentally for diffusion parallel to each of the three crystallographic directions in natural orthoenstatite (En88Fs12). Experiments were conducted at 1 atm in CO-CO2 gas mixing furnaces, which provided oxygen fugacities equivalent to the iron-wüstite buffer. Diffusion of 25Mg was induced in polished samples of oriented orthoenstatite using a film of isotopically enriched 25MgO as the source material. Very short (<0.15 μm) diffusional penetration profiles were measured by ion microprobe depth profiling. The diffusion coefficients determined for four temperatures (900, 850, 800, 750 °C) provide the activation energies, E a , and frequency factors, D o, where D = D o exp (−E a /RT) for Mg self-diffusion parallel to each crystallographic direction: a-axis, E a  = 360 ± 52 kJ/mole and D o = 1.10 × 10−4 m2/s; b-axis, E a  = 339 ± 77 kJ/mole and D o = 6.93 × 10−6 m2/s and c-axis, E a  = 265 ± 66 kJ/mole and D o = 4.34 × 10−9 m2/s. In this temperature range, any possible anisotropy of cation diffusion is very small, however the activation energy for diffusion parallel to the c-axis (001) is the lowest and the activation energies for diffusion parallel to the a-axis (100) and b-axis (010) are higher. Application of these diffusion results to the silicate phases of the Lowicz mesosiderite meteorite provides cooling rates for the silicate portion of the meteorite (4–11 °C/100 years) that are similar, although slower, to previous estimates. These silicate cooling rates are still several orders of magnitude faster than the cooling rates (0.1 °C/106 years) for the metal portions. Received: 22 January 1997 / Accepted: 2 October 1997  相似文献   
85.
Abstract: Low sulphidation epithermal Au-Ag deposits constitute a major exploration target for many mining companies worldwide. These deposits are commonly characterized by quartz vein systems which formed at temperatures often in the range 150–250°C giving rise to major alteration halos. Accompanying mineralization and associated alteration is the destruction and redistribution of magnetite in the host rocks and the formation of various K-bearing minerals such as adularia, illite and alunite. These alteration halos can often cover an area of at least several square kilometres and as such have the potential to be detected during reconnaissance geological surveys utilizing high resolution airborne aeromagnetic and radiometric sensors.
Analysis of airborne magnetic and radiometric data recently acquired over the Hokusatsu Region of SW Kyushu indicates that major low sulphidation epithermal Au-Ag deposits are characterized by several distinct geophysical features varying with the degree of post-mineralization cover and level of erosion. Several deposits coincide with extensive magnetic "flat" and high radiometric K–counts. In addition, several workers have shown that a very close association exists between Bouguer gravity highs and epithermal Au mineralization in the Hokusatsu Region. The combined use of areomagnetics, radiometrics and gravity data therefore provides an exceptionally effective approach to exploration for low sulphidation epithermal Au–Ag deposits in the Hokusatsu Region of Japan.  相似文献   
86.
The methods used to monitor five cases of plug flow in mudslides in east County Antrim, Northern Ireland, are given. Assuming the mudslide material acts as a Bingham substance, the five cases are analysed. The results show a general agreement between the observed and predicted behaviours. An analysis derived to model submarine landslide behaviour is employed to represent the five plug-flow cases, and the results are reasonably close to those achieved in former analyses.  相似文献   
87.
Predictions of global changes in relative sea level caused by retreat of the Antarctic Ice Sheet from its 18,000 yr B.P. maximum to its present size are calculated numerically. When combined with the global predictions of relative sea-level change resulting from retreat of the Northern Hemisphere ice sheets, the results may be compared directly to observations of sea-level change on the Antarctic continent as well as at distant localities. The comparison of predictions to the few observations of sea-level change on Antarctica supports the view that the Antarctic Ice Sheet was larger 18,000 years ago than at present. The contribution of the Antarctic Ice Sheet to the total eustatic sea-level rise is assumed to be 25 m (25% of the assumed total eustatic rise). If as little as 0.7 m of this 25-m rise occurred between 5000 yr B.P. and the present, few mid-oceanic islands would emerge. If the Antarctic Ice Sheet attained its present dimensions by 6000 yr B.P., however, and if the volume of the ocean has remained constant for the past 5000 years, numerous islands throughout the Southern Hemisphere would emerge. It is suggested that a thorough study of Pacific islands, believed by some to have slightly emerged shorelines of Holocene age, would yield useful information about ocean volume changes during the past 5000 years, and hence on the glacial history of the Antarctic Ice Sheet.  相似文献   
88.
Systematic trends in the geometry of 149 oxide and 80 sulfide binary and ternary spinels have been examined from the standpoint of ionic radius and electronegativity. The mean ionic radii of the octahedral and tetrahedral cations, taken together, account for 96.9 and 90.5% of the variation in the unit cell parameter, a, of the oxides and sulfides, respectively, with the octahedral cation exerting by far the dominant influence in sulfides. The mean electronegativity of the octahedral cation exerts an additional, but small, influence on the cell edge of the sulfides. The equation a=(8/3√d)d tet+(8/3)d oct, where d tet and d oct are the tetrahedral and octahedral bond lengths obained from the sum of the ionic radii, accounts for 96.7 and 83.2% of the variation in a in the oxides and sulfides, respectively, again testifying to the applicability of the hard-sphere ionic model in the case of the spinel structure. Comparison of observed and calculated u values for 94 spinels indicates that up to 40% of the experimentally measured anion coordinates may be significantly in error. In addition to these compounds, u values are given for 52 spinels for which no data have previously been determined. Diagrams are presented for the rapid interpretation of the internal consistency of published data and the prediction of the structural parameters of hypothetical or partially studied spinels.  相似文献   
89.
90.
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