Lithium Isotope Composition of Ultramafic Geological Reference Materials JP‐1 and DTS‐2     

Yongjun Gao  John F. Casey 《Geostandards and Geoanalytical Research》2012,36(1):75-81

An organic solvent‐free two‐step column procedure is presented that provided robust, high yield and super clean separation of Li from silicate rock sample matrices. The measured δ⁷Li value for BHVO‐2 of +4.29 ± 0.23‰ (1s) is comparable with the reported values. The δ⁷Li values for GSJ JP‐1 (+3.14 ± 0.41‰, 1s) and USGS DTS‐2 (+4.91 ± 0.34‰, 1s) presented here provide new reference values for ultramafic rock reference materials.  相似文献   

Field‐Scale Relationships Among Soil Properties and Shallow Groundwater Quality     

Nathan E. Derby  Scott F. Korom  Francis X.M. Casey 《Ground water》2013,51(3):373-384

It is important to understand the link between land surface/soil properties and shallow groundwater quality. To that end, soil properties and near‐water‐table groundwater chemistry of a shallow, unconfined aquifer were measured on a 100‐m grid on a 64‐ha irrigated field in southeastern North Dakota. Soil properties and hydrochemistry were compared via multivariate analysis that included product‐moment correlations and factor analysis/principal component analysis. Topographic low areas where the water table was in close proximity to the soil surface generally had higher apparent electrical conductivity (EC_a) and higher percent silt and clay than higher positions on the landscape. The majority of the groundwater was characterized by Ca‐ and Mg‐HCO₃ type water and was associated with topographic high areas with lower EC_a and net groundwater recharge. Small topographic depressions were areas of higher EC_a (net groundwater discharge) where salts that precipitated via evapotranspiration and evaporative discharge dissolved and leached to the groundwater during short‐term depression‐focused recharge events. At this site, groundwater quality and soil EC_a were related to surface topography. High‐resolution topography and EC_a measurements are necessary to characterize the land surface/soil properties and surficial groundwater quality at the field‐scale and to delineate areas where the shallow groundwater is most susceptible to contamination.  相似文献   

Maze or Labyrinth: Identifying PTSD Stressors in the Built Space of Zaatari and Calais Refugee Camps     

Samuel N. Chambers  W. Jake Jacobs  Casey Lindberg 《The Professional geographer》2013,65(4):552-565

In this study, we analyze the structure of paths within two refugee camps (Calais, France, and Zaatari, Jordan) as a preliminary study examining posttraumatic stress disorder (PTSD) stressors within such camps. We do so through a geospatial analysis of intersections and viewsheds within the camps. Given that anxiety, and the avoidance associated with it, is a primary characteristic of PTSD, refugees might prefer built environments with fewer stressors or anxiety triggers. This study provides a baseline for analyzing basic stressors in a way to test whether design supports anxiety-based avoidance. The planned structure of Zaatari shows a high prevalence of spatial PTSD stressors with lower visibility and a more maze-like structure than that of Calais. This suggests a coping strategy taken by refugees to produce a more suitable and less stressing labyrinth structure. To properly treat PTSD in geographical space, we suggest a need for consideration of this in the planning, function, and very existence of refugee camps and settlements.  相似文献   

Impact of beaver dam analogues on hydrology in a semi-arid floodplain     

Casey Pearce  Philippe Vidon  Laura Lautz  Christa Kelleher  Julianne Davis 《水文研究》2021,35(7):e14275

Natural beaver ponds help connect the stream to the floodplain, maintain late summer low flows and reduce peak flow during high flow events by offering temporary surface water (SW) storage. When beavers are extirpated from the landscape, stream degradation often ensues. This study assesses the impact of beaver dam analogues (BDA) as a stream restoration technique to help maintain low flow water levels and enhance stream-floodplain interactions on a seasonal basis in Red Canyon Creek, Lander, WY. BDAs increased SW and groundwater (GW) levels, favoured the occurrence of flow reversals (i.e., stream-to-floodplain GW flow) during high flow events associated with mid-winter and early-spring thaw events, and reduced the groundwater-to-stream hydraulic gradient on an annual basis. Although GW temperatures varied seasonally, relatively cooler GW temperatures were observed in the BDA impacted reach compared to the control reach away from BDA influence. BDAs however did not significantly impact stream temperatures. Overall, results suggest that when installed in sequence, BDA complexes can successfully reconnect the stream to its floodplain, and ultimately increase SW-GW exchange at the floodplain scale by allowing flow reversals to occur and by reducing the GW to stream hydraulic gradient. Although BDAs built with fence posts, willow branches, sediments and small boulders are naturally porous and require regular maintenance, this study also highlights the viability of small BDAs as a restoration practice to enhance landscape resilience to drought and high flow events in deeply incised channels where beavers would not come back naturally.  相似文献   

Seasonal and intra-seasonal rainfall and drought characteristics as indicators of climate change and variability in Southern Africa: a focus on Kabwe and Livingstone in Zambia     

Cuthbert Casey Makondo  David S. G. Thomas 《Theoretical and Applied Climatology》2020,140(1):271-284

This paper addresses two fundamental questions on climate change and variability: to what extent has climate changed and/or varied over years in two districts of different agro-ecological regions or zones and how do any changes differ between the zones or districts? Given the rural-rural migration pattern observed between the districts, understanding climate change risk to rural livelihoods cannot be overemphasised. To assess change and variability, we utilise rainfall data-records over a 36-year period from 1980 to 2016. Results show that there are wide variations and differences within and between the districts. Evidence suggests a general reduction in both annual rainfall and wet days. There is also ground to suggest that the rainy season duration is becoming shorter, given that rainfall onset is increasingly starting late, while cessation is increasingly coming early. Dry spells frequency and duration trends within rainy season show an increase over the period examined. We conclude that local climate in both areas has changed over the period investigated. However, while Livingstone seems to have experienced more droughts and unreliable rainfall, Kabwe experienced a bigger change in both rainfall and rainy season duration. We further conclude that migrants into Kabwe and other inhabitants are not any safer from climate change risk.  相似文献   

Behavior of a chlorinated ethene plume following source-area treatment with Fenton's reagent   总被引：1，自引：0，他引：1  

Francis H. Chapelle  Paul M. Bradley  Clifton C. Casey 《Ground Water Monitoring & Remediation》2005,25(2):131-141

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Geophysical monitoring of a field-scale biostimulation pilot project     

Lane JW  Day-Lewis FD  Casey CC 《Ground water》2006,44(3):430-443

The USGS conducted a geophysical investigation in support of a U.S. Naval Facilities Engineering Command, Southern Division field-scale biostimulation pilot project at Anoka County Riverfront Park (ACP), down-gradient of the Naval Industrial Reserve Ordnance Plant, Fridley, Minnesota. The goal of the pilot project is to evaluate subsurface injection of vegetable oil emulsion (VOE) to stimulate microbial degradation of chlorinated hydrocarbons. To monitor the emplacement and movement of the VOE and changes in water chemistry resulting from VOE dissolution and/or enhanced biological activity, the USGS acquired cross-hole radar zero-offset profiles, travel-time tomograms, and borehole geophysical logs during five site visits over 1.5 years. Analysis of pre- and postinjection data sets using petrophysical models developed to estimate VOE saturation and changes in total dissolved solids provides insights into the spatial and temporal distribution of VOE and ground water with altered chemistry. Radar slowness-difference tomograms and zero-offset slowness profiles indicate that the VOE remained close to the injection wells, whereas radar attenuation profiles and electromagnetic induction logs indicate that bulk electrical conductivity increased down-gradient of the injection zone, diagnostic of changing water chemistry. Geophysical logs indicate that some screened intervals were located above or below zones of elevated dissolved solids; hence, the geophysical data provide a broader context for interpretation of water samples and evaluation of the biostimulation effort. Our results include (1) demonstration of field and data analysis methods for geophysical monitoring of VOE biostimulation and (2) site-specific insights into the spatial and temporal distributions of VOE at the ACP.  相似文献   

Submillimetre detection of the z=2.83 Lyman-break galaxy, Westphal–MM8, and implications for SCUBA2     

S. C. Chapman †  C. M. Casey 《Monthly notices of the Royal Astronomical Society》2009,398(4):1615-1620

We present confusion-limited submillimetre (submm) observations with the Submillimetre Common-User Bolometer Array (SCUBA) camera on the James Clerk Maxwell Telescope of the   z = 2.83  Lyman-break galaxy (LBG), Westphal–MM8, reaching an 850 μm sensitivity even greater than that achieved in the SCUBA map of the Hubble Deep Field region. The detection of MM8  ( S _850 μm= 1.98 ± 0.48 mJy)  , along with the literature submm detections of lensed LBGs, suggests that the LBG population may contribute significantly to the source counts of submm-selected galaxies in the 1–2 mJy regime. Additionally, submm-luminous LBGs are a viable progenitor population for the recently discovered evolved galaxies at   z ∼ 2–2.5  . These observations represent an important baseline for SCUBA2 observations which will regularly map large regions of the sky to this depth.  相似文献   

Lattice preferred orientation and seismic anisotropy in sedimentary rocks     

S. L. A. Valcke  M. Casey  G. E. Lloyd  J.-M. Kendall †  Q. J. Fisher 《Geophysical Journal International》2006,166(2):652-666

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Dissolution kinetics of experimentally shocked silicate minerals     

Randall T. Cygan  William H. Casey  Mark B. Boslough  Henry R. Westrich  Martin J. Carr  George R. Holdren Jr. 《Chemical Geology》1989,78(3-4):229-244

The effect of lattice strain on mineral dissolution rates was examined by comparing the dissolution rates of shocked and unshocked minerals. Labradorite, oligoclase and hornblende were explosively shocked at mean pressures ranging from 4 to 22 GPa. The labradorite was examined with transmission electron microscopy to estimate the density of dislocations produced by the shock-loading experiment. Subsamples of the labradorite were then thermally annealed to remove some of the dislocations, and to evaluate the importance of such thermal pre-treatment in preparing mineral surfaces for experiments. The dissolution rates of these minerals were measured in batch experiments at pH-values of 2.7 and 4.0.

Shock-loading did not produce extremely high dislocation densities in the labradorite. The density of dislocations in the unshocked labradorite is ≤ 10¹⁰ m⁻². After shocking, the density increases to 10¹²-10¹³ m⁻². The distribution of dislocations is heterogeneous, and the amount of deformation does not increase substantially with shock pressure. These results are highly atypical of shock-modified minerals, where relatively low shock pressures usually induce high ( 10¹⁵ m⁻²) densities of dislocations. Thermal annealing for 1 hr. at 900°C in a dry furnace removes many dislocations from the shocked labradorite.

The difference in observed dissolution rates between shocked and unshocked minerals appears to have a weak correlation with the increase in the density of dislocations on the mineral surface. The unshocked and shocked oligoclase and hornblende samples exhibit limited dissolution enhancement at pH 4.0. Increasing the density of dislocations by several orders of magnitude with shock-loading causes a relatively small increase in dissolution rates for these silicate minerals. These results suggest that the surface dislocations produced by the shock treatment are not the primary sites for dissolution reactions.  相似文献