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51.
Trace organic contamination in biota collected from the Pearl River Estuary, China: a preliminary risk assessment 总被引：5，自引：0，他引：5
Wei S Lau RK Fung CN Zheng GJ Lam JC Connell DW Fang Z Richardson BJ Lam PK 《Marine pollution bulletin》2006,52(12):1682-1694
The marine ecosystem of the Pearl River Delta, located on the southern coast of China, has been heavily exploited following the rapid economic growth that has occurred since the 1980s. This investigation aimed to elucidate trace organic contamination in marine biota inhabiting the Pearl River Delta area. Biota samples, including green-lipped mussels (Perna viridis), oysters (Crassostrea rivularis) and shrimp (Penaeus orientalis) were sampled from 16 stations fringing the Estuary. Elevated concentrations (on a dry weight basis) of polycyclic aromatic hydrocarbons (27.8–1041.0 ng/g), petroleum hydrocarbons (1.7–2345.4 μg/g), polychlorinated biphenyls (2.1–108.8 ng/g), DDTs (1.9–79.0 ng/g), and hexachlorocyclohexanes (n.d.–38.4 ng/g) were recorded. A human health risk assessment was conducted to estimate the risk to local residents associated with the consumption of biota collected from the Pearl River Estuary. The results indicated that PCBs were at levels that may cause deleterious health effects in populations that consume large amounts of seafood. However, it would be instructive to establish health criteria for trace organic contaminants that are specific to the local populations, in order to derive a more accurate and relevant health risk assessment. 相似文献
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Field methods for amending marine sediment with activated carbon and assessing treatment effectiveness 总被引：1，自引：0，他引：1
Cho YM Smithenry DW Ghosh U Kennedy AJ Millward RN Bridges TS Luthy RG 《Marine environmental research》2007,64(5):541-555
Previous laboratory studies have shown reductions in PCB bioavailability for sediments amended with activated carbon (AC). Here we report results on a preliminary pilot-scale study to assess challenges in scaling-up for field deployment and monitoring. The goals of the preliminary pilot-scale study at Hunters Point Shipyard (San Francisco, USA) were to (1) test the capabilities of a large-scale mixing device for incorporating AC into sediment, (2) develop and evaluate our field assessment techniques, and (3) compare reductions in PCB bioavailability found in the laboratory with well-mixed systems to those observed in the field with one-time-mixed systems. In this study we successfully used a large-scale device to mix 500kg of AC into a 34.4m(2) plot to a depth of 1ft, a depth that includes the majority of the biologically active zone. Our results indicate that after 7 months of AC-sediment contact in the field, the 28-day PCB bioaccumulation for the bent-nosed clam, Macoma nasuta, field-deployed to this AC-amended sediment was approximately half of the bioaccumulation resulting from exposure to untreated sediment. Similar PCB bioaccumulation reductions were found in laboratory bioassays conducted on both the bivalve, M. nasuta and the estuarine amphipod, Leptocheirus plumulosus, using sediment collected from the treated and untreated field plots one year after the AC amendment occurred. To further understand the long-term effectiveness of AC as an in situ treatment strategy for PCB-contaminated sediments under field conditions, a 3-year comprehensive study is currently underway at Hunters Point that will compare the effectiveness of two large-scale mixing devices and include both unmixed and mixed-only control plots. 相似文献
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Since 1995, a network of municipal wells in Iowa, representing all major aquifer types (alluvial, bedrock/karst region, glacial drift, bedrock/nonkarst region), has been repeatedly sampled for a broad suite of herbicide compounds yielding one of the most comprehensive statewide databases of such compounds currently available in the United States. This dataset is ideal for documenting the insight that herbicide degradates provide to the spatial and temporal distribution of herbicides in ground water. During 2001, 86 municipal wells in Iowa were sampled and analyzed for 21 herbicide parent compounds and 24 herbicide degradates. The frequency of detection increased from 17% when only herbicide parent compounds were considered to 53% when both herbicide parents and degradates were considered. Thus, the transport of herbicide compounds to ground water is substantially underestimated when herbicide degradates are not considered. A significant difference in the results among the major aquifer types was apparent only when both herbicide parent compounds and their degradates were considered. In addition, including herbicide degradates greatly improved the statistical relation to the age of the water being sampled. When herbicide parent compounds are considered, only 40% of the wells lacking a herbicide detection could be explained by the age of the water predating herbicide use. However, when herbicide degradates were also considered, 80% of the ground water samples lacking a detection could be explained by the age of the water predating herbicide use. Finally, a temporal pattern in alachlor concentrations in ground water could only be identified when alachlor degradates were considered. 相似文献
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Produced water is a high salinity by-product resulting from oil and gas production. Disposal methods include surface water discharge. The current field method used to determine its fate in estuarine systems involves extending a compass oriented transect (COT) from the point source discharge--a method designed for a uniformly dispersing effluent discharged into a uniform offshore environment that may be inappropriate for the hydrologic and geomorphologic complexities found in estuarine systems. Prior research established the viability of the salinity stratification transect (SST) method. Both COT and SST methods were used in a small open bay to determine which more accurately detected effluent dispersion. Determination was based on sediment contaminant indicators (SCIs), including interstitial salinity, hydrocarbons, metals, and radium concentrations. Additionally, SCIs were evaluated for their ability to serve as indicators of effluent dispersion. The data revealed that SST stations exhibited higher contaminant concentrations and that this approach was more accurate in tracking the produced water plume. The data also suggested that SCIs varied in their ability to serve as indicators. Good indicators included interstitial salinity, total targeted aromatic hydrocarbons substantiated with a modified fossil fuel pollution index value, certain metals, and radium-228. 相似文献
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Impairment of sea urchin sperm quality by UV-B radiation: predicting fertilization success from sperm motility 总被引：4，自引：0，他引：4
Sperm quality of the sea urchin, Anthocidaris crassispina, after exposure to environmentally realistic UV-B irradiances, was assessed by changes in sperm motility (measured by the computer-assisted sperm analysis (CASA) system), and related to subsequent fertilization success. Percentage motile sperm of A. crassispina declined significantly after exposure to a UV-B dose of 16.2 kJ m(-2), while sperm motion velocity as measured by curvilinear velocity (VCL), straight line velocity (VSL), and average path velocity (VAP) showed significant reduction after exposure to a UV-B dose of 5.4 kJ m(-2). A parallel study showed that fertilization success was significantly reduced after sperm were exposed to UV-B doses > or = 5.4 kJ m(-2). Notably, the four sperm motility parameters were strongly correlated with fertilization success (P < 0.001), followed the increasing order: VSL (r = 0.8) < % motile sperm (r = 0.804) < VCL (r = 0.912) < VAP (r = 0.928). Fertilization success is best predicted by VAP using the exponential model: y = 8.678 + 90.202/[1 + exp(82.83 - x)/10.27)] (r(2) = 0.95). Thus, impairment of sperm motility of sea urchin, as measured by the CASA method, can be used to predict reproductive success and ecological effects. 相似文献
56.
Coefficient of permeability determined by measurable parameters 总被引：1，自引：0，他引：1
Barr DW 《Ground water》2001,39(3):356-361
Selection of a coefficient of permeability or the hydraulic conductivity in practical situations has required a fair amount of judgment and the expectation of accuracy can range over an order of magnitude. A determination of the coefficient based on measurable characteristics would greatly reduce the judgment aspect. The coefficient of permeability of a porous media can be derived from the following measurable parameters: the density and viscosity of the permeating fluid, the porosity of the media, the average hydraulic radius of the pores, and the gravitation constant. The hydraulic radius is calculated from the grain size distribution analysis of the porous media assuming spherical particles and a factor to account for the shape of the particles. The shape factor ranges from 1.0 to 1.4 in the extreme but, for common porous media, ranges only from 1.0 to about 1.1. All of the variables, except the shape factor, are measurable by standard test procedures. An important advantage of using this procedure for determining permeability is that the factors can be visualized as part of the physical flow process. The procedure assumes laminar flow and applies equally to liquid or gas fluids. 相似文献
57.
Barr DW 《Ground water》2001,39(5):646-650
The pressure driving flow through porous media must be equal to the viscous resistance plus the inertial resistance. Formulas are developed for both the viscous resistance and the inertial resistance. The expression for the coefficient of permeability consists of parameters which describe the characteristics of the porous medium and the permeating fluid and which, for unconsolidated isotropic granular media, are all measurable. A procedure is proposed for testing for the occurrence of turbulence and calculating the effective permeability when it occurs. The formulas are applied to a set of data from 588 permeameter runs ranging from laminar to highly turbulent. The equations fit the data from the permeameter closely through the laminar flow conditions and quite closely through the turbulent conditions. In the turbulent range, the plotting of the data separates into three distinct lines for each of the three shapes of particles used in the tests. For the porous medium and fluid of these tests, turbulence begins at a head gradient of about 0.1. 相似文献
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