Petrology and mineralogy of granulite-facies mafic xenoliths (Sardinia, Italy): Evidence for KCl metasomatism in the lower crust     

Alessandra Montanini  Daniel Harlov 《Lithos》2006,92(3-4):588-608

Here new mineralogical data is presented on the occurrence of K-feldspar in granulite-facies metagabbronorite xenoliths found in recent alkaline lavas from Western Sardinia, Italy. The xenoliths originated from the underplating of variably evolved subduction-related basaltic liquids, which underwent cooling and recrystallisation in the deep crust (T = 850–900 °C, P = 0.8–1.0 GPa). They consist of orthopyroxene + clinopyroxene + plagioclase porphyroclasts (An = 50–66 mol%) in a granoblastic, recrystallised, quartz-free matrix composed of pyroxene + plagioclase (An = 56–72 mol%) + Fe–Ti oxides ± K-feldspar ± biotite ± fluorapatite ± Ti-biotite. Texturally, the K-feldspar occurs in a variety of different modes. These include: (1) rods, blebs, and irregular patches in a random scattering of plagioclase grains in the form of antiperthite; (2) micro-veins along plagioclase–plagioclase and plagioclase–pyroxene grain rims; (3) myrmekite-like intergrowths with Ca-rich plagioclase along plagioclase–plagioclase grain boundaries; and (4) discrete anhedral grains (sometimes microperthitic). The composition of each type of K-feldspar is characterized by relatively high albite contents (16–33 mol%). An increasing anorthite content in the plagioclase towards the contact with the K-feldspar micro-vein and myrmekite-like intergrowths into the K-feldspar along the plagioclase–K-feldspar grain boundary are also observed. Small amounts of biotite (TiO₂ = 4.7–6.5 wt.%; F = 0.24–1.19 wt.%; Cl = 0.04–0.20 wt.%) in textural equilibrium with the granulite-facies assemblage is present in both K-feldspar-bearing and K-feldspar-free xenoliths. These K-feldspar textures suggest a likely metasomatic origin due to solid-state infiltration of KCl-rich fluids/melts. The presence of such fluids is supported by the fluorapatite in these xenoliths, which is enriched in Cl (Cl = 6–50% of the total F + Cl + OH). These lines of evidence suggest that formation of K-feldspar in the mafic xenoliths reflects metasomatic processes, requiring an external K-rich fluid source, which operated in the lower crust during and after in-situ high-T recrystallisation of relatively dry rocks.  相似文献   

Effect of oxidation potential and zinc sulphate on the separation of chalcopyrite from pyrite     

Shuhua He  William Skinner  Daniel Fornasiero   《International Journal of Mineral Processing》2006,80(2-4):169-176

The effects of oxidation potential (Eh) and zinc sulphate on the separation of chalcopyrite from pyrite were investigated at pH 9.0. The flotation recovery of these minerals is Eh dependent with maximum separation obtained at 275 mV SHE. Zinc sulphate addition improved this mineral separation at an Eh value of 275 mV by selectively depressing pyrite flotation. A different result was obtained at lower Eh values where zinc sulphate addition improved chalcopyrite flotation but had no or little effect on pyrite flotation. These opposite effects of zinc sulphate on mineral flotation were reconciled by examining the surface species of these minerals. The selective depression of pyrite flotation by zinc sulphate was also confirmed in the flotation of two copper ores.  相似文献   

Influence of streambed hydraulic conductivity on solute exchange with the hyporheic zone     

Robert J. Ryan  Michel C. Boufadel 《Environmental Geology》2006,51(2):203-210

A conservative solute tracer experiment was conducted in Indian Creek, a small urban stream in Philadelphia, Pennsylvania to investigate the role of subsurface properties on the exchange between streamwater and the hyporheic zone (subsurface surrounding the stream). Sodium Bromide (NaBr) was used as a conservative tracer, and it was monitored in the surface water at two stations and in the upper bed sediments (shallow hyporheic zone extending from 7.5 to 10 cm below the streambed). The hydraulic conductivity (K) of the upper bed sediments and the lower bed sediments (10–12.5 cm below the streambed) was measured in situ. High tracer concentrations were observed in the upper layer at locations where the hydraulic conductivity of the upper layer was larger than that of the lower layer. Low concentrations in the upper layer were observed in the converse case. A statistically significant relationship between the mass retained in the upper layer and the difference of K values between layers was observed.  相似文献   

Turbulence Over Urban-type Roughness: Deductions from Wind-tunnel Measurements     

Ian P. Castro  Hong Cheng  Ryan Reynolds 《Boundary-Layer Meteorology》2006,118(1):109-131

Turbulence data from experiments conducted over a staggered cube array, modelling a neutrally stable atmospheric boundary layer in an urban environment, are presented. The results support the contention that organised eddy structures in the near-wall region differ significantly from those in regular smooth-wall flows or in rough-wall boundary layers with much smaller h/δ ratios (where δ and h are the boundary-layer thickness and the height of the roughness elements, respectively). Attention is concentrated on spatial correlations, spectra (and thus the dominant length and time scales), maps of anisotropy invariants and quadrant analyses of the stress tensor. Results are obtained within both the roughness sublayer (i.e. the region above the roughness but within which the flow is spatially inhomogeneous) and the canopy region (i.e. below the height of the roughness elements) and discussion includes consideration of the turbulence kinetic energy balance at various heights.  相似文献   

Human Strategies for Coping with El Niño Related Drought in Amazônia     

Emilio F. Moran  Ryan Adams  Bryn Bakoyéma  Stefano Fiorini T.  Bruce Boucek 《Climatic change》2006,77(3-4):343-361

This article reports on findings of a research project examining farmers' coping strategies in the Brazilian Amazon in response to El Niño related weather events. We examine the extent of vulnerability of small and large farmers to these events in a tropical rainforest environment. Little attention has been given to the impact of ENSO events in Amazônia, despite evidence for devastating fires during ENSOs. Although we found a range of locally developed forecasting techniques and coping mechanisms, farmers have sustained significant losses, and we suggest that increased access to scientific forecasts would greatly enhance the ability of the farmers in our study area to cope with El Niño related weather events. In Amazônia the El Niño phase of the El Niño-Southern Oscillation (ENSO) climate pattern leads to an extended period of reduced rainfall (Hobbs et al., 1998). This period of reduced rainfall can result in significant agricultural losses for farmers and ranchers in the area and in increased forest flammability. We have found that the majority of our study population uses several methods of forecasting, coping with, and adapting to drought events – and they recognize the economic losses they can experience and the loss of forests through the accidental spread of fire. The poorest farmers in our study area experience El Niño related drought events as a serious threat to their livelihoods. Their vulnerability is heightened during extreme climate events and our observations revealed that all of the farmers in our study would benefit from increased availability of improved forecast information relevant to their locality and their current farming strategies. This paper examines the availability and use of forecasts, the occurrence of accidental fires and techniques to prevent fire related losses, and the coping mechanisms for dealing with El Niño related drought in the agricultural regions surrounding the cities of Altamira and Santarém, in Pará State, Brazil. Distribution of an El Niño Prediction Kit at the end of the study and a series of workshops may lead to better local information on rainfall variability and create a farmer-maintained grid of collecting stations to sensitize farmers to the variability of precipitation in the region, and on their property.  相似文献   

A lumped parameter approach to model the treatment of organic contaminants by a granular iron filled fracture     

Zuansi Cai  Neil R. Thomson  Ryan D. Wilson  Sascha E. Oswald 《Advances in water resources》2006

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Contaminant Hydrogeology in Developing Countries: Benefiting from Experience in Developed Countries     

David N. Bethune  M. Cathryn Ryan  Marcelino Losilla P. 《Ground water》1998,36(3):385-386

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Characterizing a Ground Water Basin in a New England Mountain and Valley Terrain   总被引：2，自引：0，他引：2  

Claire R. Tiedeman  Daniel J. Goode  Paul A. Hsieh 《Ground water》1998,36(4):611-620

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Biogeochemical processes controlling methane in gassy coastal sediments—Part 2: groundwater flow control of acoustic turbidity in Eckernförde Bay Sediments     

Daniel B. Albert  Christopher S. Martens  Marc J. Alperin 《Continental Shelf Research》1998,18(14-15)

To understand the origin of the methane distributions in sediments of Eckernförde Bay, three sites were sampled in May 1994 for determination of methane, sulfate and chloride concentrations in the sediment porewaters. In much of the Bay, bubbles of biogenic methane gas within the sediments lead to widespread ‘acoustic turbidity’ seen in acoustic surveys, masking the sedimentary structure below the gassy horizon. Acoustic windows, where the gas does not appear to be present, occur in several locations in the Bay, often surrounded by acoustically turbid sediments. Pockmarks, shallow depressions in the sediment, are also found in Bay sediments and may show acoustic turbidity at even shallower depths below the interface than surrounding sediments. One site of each type was sampled in this study. The site probably representative of much of the bay below 20 m water depth, revealed methane saturated conditions by about 75 cm depth below the interface, confirming inferences from acoustic scattering data that free gas was present in the sediment. Above this, the methane concentration profile was concave-upward, indicative of methane oxidation in the overlying, sulfate-reducing sediments. These porewaters showed a slightly decreasing chlorinity with depth. At an acoustic window site, methane concentrations rose to a maximum at about 125 cm depth, but did not reach saturation. Below this depth they decreased in a concave-down pattern. Chloride concentrations decreased markedly with depth, indicative of vertical freshwater flow from below. The third site was a pockmark exhibiting very shallow acoustic turbidity at about 25 cm depth. Here methane concentrations rose to exceed saturation within 25 cm depth below the interface and the porewaters became almost fresh by 1.5 m depth, indicative of a stronger flow of freshwater from below. These groundwater flows have competing effects on the methane inventory. They help exclude sulfate from the sediment, allowing the earlier/shallower onset of methanogenesis, but they also aid loss of methane through advection. A diagenetic model that couples the biogeochemistry of sulfate and methane is used to explain the presence or absence of methane gas in these sediments in relation to the flow rate of fresh groundwater from below. Model results indicate that acoustic windows within otherwise acoustically turbid sediments of the bay are likely due to relatively higher rates of vertical advection of fresh groundwater. The gassy pockmark, however, with an even higher vertical advection rate, seems to require the input of additional reactive organic carbon to explain its vertical methane distribution.  相似文献   

The alkaline–peralkaline granitic post-collisional Tin Zebane dyke swarm (Pan-African Tuareg shield, Algeria): prevalent mantle signature and late agpaitic differentiation     

Zakia Hadj-Kaddour  Jean-Paul Li  geois  Daniel Demaiffe  Renaud Caby 《Lithos》1998,45(1-4):223-243

The Tin Zebane dyke swarm was emplaced at the end of the Pan-African orogeny along a mega-shear zone separating two contrasting terranes of the Tuareg shield. It is located along the western boundary of the Archaean In Ouzzal rigid terrane, but inside the adjacent Tassendjanet terrane, strongly remobilized at the end of the Precambrian. The Tin Zebane swarm was emplaced during post-collisional sinistral movements along the shear zone at 592.2±5.8 Ma (19WR Rb–Sr isochron). It is a dyke-on-dyke system consisting of dykes and stocks of gabbros and dykes of metaluminous and peralkaline granites. All rock types have Sr and Nd isotopic initial ratios (Sr_i=0.7028 and _Nd=+6.2) typical of a depleted mantle source, similar to the prevalent mantle (PREMA) at that period. No crustal contamination occurred in the genesis of the Tin Zebane swarm. Even the samples showing evidence of fluid interaction (essentially alkali mobility) have the same isotopic signature. The peralkaline granites have peculiar geochemical characteristics that mimic subduction-related granites: this geochemical signature is interpreted in terms of extensive differentiation effects due to late cumulates comprising aegirine, zircon, titanite, allanite and possibly fergusonite, separated from the liquid in the swarm itself due to magmatic flow turbulence. The Tin Zebane dyke swarm is thus of paramount importance for constraining the differentiation of mantle products to generate highly evolved alkaline granites without continental crust participation, in a post-collisional setting.  相似文献