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31.
In the present study both the synthetic media composition as well as some process parameters in the anaerobic decolorization of Reactive Black 5 (RB5) by activated sludge were studied and optimized using statistical design of experiments (DOEs). Statistical analysis of the results of Plackett–Burman DOE showed that the addition of Mn or Fe, or increase in concentration of Mg, had a positive effect on the anaerobic decolorization efficiency whereas the effect of increase in concentration of glucose, ammonium chloride, and calcium chloride was negative. The effect of change in the concentration of glucose, mixed liquor suspended solid (MLSS), and RB5 on the anaerobic decolorization efficiency and rate and chemical oxygen demand (COD) removal was studied using central composite design methodology. Statistical analysis of the data showed that all the factors had significant effect on both the dye decolorization efficiency and rate. The interaction of glucose with MLSS and with dye and the interaction of MLSS with glucose and with dye were significant when the response was decolorization efficiency and rate, respectively. When COD removal was the response, the effect of change in glucose and MLSS concentration and the interaction between these two factors had statistically significant effect on the response.  相似文献   
32.
In this research, the main hydrological characteristics (such as trend, stationarity, and normalization of hydrological data) of the Kasilian watershed are considered from 1970 to 2009. For forecasting of discharge, gene expression programming (GEP) method is applied. Normality and stationarity of time series are necessary for application of GEP method. For this purpose, third edition of Mann-Kendall trend test and skewness test are used for detection of trend and normalization of data, respectively. Also, five methods are applied for detection of stationarity of data. Modified Mann-Kendall trend test and Theil and Sen’s median slope method illustrate that annual and monthly precipitation data have slight decreasing trend, annual and monthly discharge data have insignificant decreasing trend, and annual and monthly temperature data have an increasing trend. Skewness test illustrates that annual, monthly, and daily discharge and precipitation data are not normal. By using logarithm function, skewness is minimized and symmetry of data is improved. After normalization of time series by logarithm function, five methods are applied for testing of stationarity of time series. These methods show that different normalized time series are stationarity and stationarity of time series is improved by elimination of periodic properties of data. For forecasting of daily discharge by GEP method, 85% of data are used for training and 15% of data are used for testing. By using data of 3 days ago, the GEP has the best efficiency. Coefficient of correlation (CC), root mean square error (RMSE), mean absolute error (MAE), and mean absolute relative error (MARE) are 0.9, 0.495 lit/s, 0.288 lit/s, and 0.053, respectively.  相似文献   
33.
Zusammenfassung 139 Proben von Gesteinen und Mineralen des Villacher Granites und von Pegmatitvorkommen im Kärntner Altkristallin (Kärnten/Österreich) sowie vergleichsweise 13 Proben von anderen Pegmatiten der Ostalpen und solchen der Böhmischen Masse wurden mit Hilfe flammenphotometrischer, emissionsspektrographischer, röntgenfluoreszenzspektrometrischer und teilweise auch gammaspektrometrischer Methoden auf die Elemente Li, Na, K, Rb, Be, Ca, Sr, Ba, B, Sc, Y, Yb, (Th, U), Ti, Zr, Ni und Ga analysiert.Es konnte gezeigt werden, daß zwischen dem voralpidischen Villacher Granit und dem pegmatitischen und aplitischen Ganggefolge im Kärntner Altkristallin zwischen Ossiacher See und Drautal Blutsverwandtschaft bestehen sollte.Mit zunehmender Größe des Pegmatitvorkommens und offenbar auch mit Annäherung an den Granit nimmt der Gehalt an Li, Rb, Be, B, Ga und Pb zu, der Gehalt an Ca, Sr, Ba, Ti, Sc u. a. hingegen ab. Das K/Rb-Verhältnis ist ebenso ein verläßlicher Indikator. In kleineren Pegmatitkörpern nähert sich der Gehalt der pegmatophilen Spurenelemente dem des Nebengesteins.Es werden Abhängigkeiten zwischen Mindestkonzentrationen und Mineralisationen gefunden: Granite der Ostalpen mit Berylliumgehalten über 5 ppm Be lassen Beryllmineralisationen in ihren Pegmatiten erwarten. In Pegmatit-Proben mit über 50 ppm Be sind unter dem Mikroskop Beryllnädelchen nachweisbar.Zinnstein tritt auf, wenn das Pegmatitgestein mehr als 20 ppm Sn enthält, Spodumen bei>0,1% Li und Xenotim bei>20 ppm Y.
Contribution to the geochemistry of some pegmatites in the Eastern Alps
Summary 139 samples of rocks and minerals from the granite of Villach and from pegmatites of the Carinthian Old Cristalline Complex (Austria) and additional 13 samples for comparison purposes from other pegmatites in the Eastern Alps and the Bohemian Mass were analyzed for the elements Li, Na, K, Rb, Be, Ca, Sr, Ba, B, Sc, Y, Yb, (Th, U), Ti, Zr, Mn, Co, Ni, and Ga using flamephotometric, emission-spectrographic, x-ray-fluorescence spectrometric and partially gamma-spectrometric methods.It could be shown that the prealpidic granite of Villach and the pegmatites of the Carinthian Old Cristalline Complex lying between the Lake of Ossiach and the Drau Valley are probably consanquineous. The contents of Li, Rb, Be, B, Ga, and Pb increase with the size of the pegmatite and with increasing proximity to the granite. Other elements, like Ca, Sr, Ba, Ti, Sc, show the reverse relation.Also the K/Rb-ratio is a good indicator. The trace-element content of small pegmatite bodies approaches that of the wall rocks.Relationships between the concentration of some elements and the mineralization have been found: One may expect beryllium minerals in pegmatites of granites of the Eastern Alps if the granite contains more than 5 ppm Be. Pegmatites samples containing more than 50 ppm Be show needles of beryll under the microscope. Cassiterite appeares, if the content of the pegmatitic rock reaches 20 ppm Sn, spodumen, if it exceeds 0,1% Li, and Xenotim, if it exceeds 20 ppm Y.


Mit 7 Abbildungen  相似文献   
34.
Grain yield reliability analysis with crop water demand uncertainty   总被引:4,自引:3,他引:4  
A new method of reliability analysis for crop water production function is presented considering crop water demand uncertainty. The procedure uses an advanced first-order second moment (AFOSM) method in evaluating the crop yield failure probability. To determine the variance and the mean of actual evapotranspiration as the component of interest for AFOSM analysis, an explicit stochastic optimization model for optimal irrigation scheduling is developed based on the first and second-order moment analysis of the soil moisture state variables. As a result of the study, the violation probabilities of crop yield at different levels were computed from AFOSM method. Also using the optimization results and the double bounded density function estimation methodology, the weekly soil moisture density function is derived which can be used as a short term reliability index. The proposed approach does not involve any discretization of system variables. The results of reliability analysis and optimization model compare favorably with those obtained from simulation.  相似文献   
35.
A comprehensive framework to define the constitutive behaviour of unsaturated soils is developed within the theory of mixtures applied to three‐phase porous media. Each of the three phases is endowed with its own strain and stress. Elastic and elastic–plastic constitutive equations are developed. Particular emphasis is laid on the interactions between the phases both in the elastic and plastic regimes. Nevertheless, the clear structure of the constitutive equations requires a minimal number of material parameters. Their identification is provided: in particular, it incorporates directly the soil–water characteristic curve. Crucial to the formulation is an appropriate definition of the effective stress. The coupled influence of this effective stress and of suction makes it possible to describe qualitatively many of the characteristic features observed in experiments, e.g. for normally consolidated soils, a plastic behaviour up to air entry followed by an elastic behaviour at increasing suctions, and, on the way back, an elastic behaviour, unless compression is applied in which case plastic collapse occurs. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   
36.
As part II of a sequence of two papers, previously developed L-moments by Hosking (1990), and the LH-moments by Wang (1997) are further investigated. The LH-moments (L to L4) are used to develop the regional parameters of the generalized extreme value distribution, generalized Pareto (GPA) distribution and the generalized logistic (GLO) distributions. These respective probability distribution functions (PDFs) are evaluated in terms of their performances. Flood peaks by the corresponding PDFs are compared with those generated by Monte Carlo simulation of randomized data, considering the respective LH-moments. The influence of the LH-moments on estimated PDFs are studied by evaluating the relative bias (RBIAS) in quantile estimation due to variability of the k parameter. Karkhe watershed located in western Iran was used as a case study area. Part I of this study identified the study area as regions A and B. The minimum calculated relative root mean square error (RRMSE) and RBIAS between simulated flood peaks and flood peaks by the corresponding PDFs were used in PDF selection, considering the respective LH-moments. The boxplots of the RRMSE tests identified the L3 level of the GPA distribution as the suitable PDF for sample sizes 20 and 80; for region A. Similar results were found for the RBIAS test. As for region B, the boxplots of the RRMSE tests indicated similar results for the three PDFs. However, the boxplots of the RBIAS tests identified the L4 level of the GLO most suitable for sample sizes 20 and 80. Relative efficiencies of the LH-moments were investigated, measured as RRMSE ratios of L-moments over the respective LH-moments. For the most parts the findings of this part of the study were similar to those of part I.  相似文献   
37.
In this paper, a study is made of the generalization of constitutive models for geomaterials from two‐dimensional stress and strain states to three‐dimensional stress and strain states. Existing methods of model generalization are reviewed and their deficiencies are highlighted. A new method is proposed based on geometries of the model imprints on two normal planes. Using the proposed method, various three‐dimensional failure criterions suitable for geomaterials are implemented directly into a two‐dimensional model and the generalized model is identical to its original form for the axially symmetric condition. To demonstrate the application of the proposed method, the Modified Cam Clay model is extended using the Matsuoka–Nakai failure criterion. Simulations of soil behaviour for loading in the principal stress space are presented and analysed. Copyright © 2008 John Wiley & Sons, Ltd.  相似文献   
38.
Stochastic multi-site generation of daily weather data   总被引:1,自引:1,他引:0  
Spatial autocorrelation is a correlation between the values of a single variable, considering their geographical locations. This concept has successfully been used for multi-site generation of daily precipitation data (Khalili et al. in J Hydrometeorol 8(3):396–412, 2007). This paper presents an extension of this approach. It aims firstly to obtain an accurate reproduction of the spatial intermittence property in synthetic precipitation amounts, and then to extend the multi-site approach to the generation of daily maximum temperature, minimum temperature and solar radiation data. Monthly spatial exponential functions have been developed for each weather station according to the spatial dependence of the occurrence processes over the watershed, in order to fulfill the spatial intermittence condition in the synthetic time series of precipitation amounts. As was the case for the precipitation processes, the multi-site generation of daily maximum temperature, minimum temperature and solar radiation data is realized using spatially autocorrelated random numbers. These random numbers are incorporated into the weakly stationary generating process, as with the Richardson weather generator, and with no modifications made. Suitable spatial autocorrelations of random numbers allow the reproduction of the observed daily spatial autocorrelations and monthly interstation correlations. The Peribonca River Basin watershed is used to test the performance of the proposed approaches. Results indicate that the spatial exponential functions succeeded in reproducing an accurate spatial intermittence in the synthetic precipitation amounts. The multi-site generation approach was successfully applied for the weather data, which were adequately generated, while maintaining efficient daily spatial autocorrelations and monthly interstation correlations.  相似文献   
39.
As part I of a sequence of two papers, previously developed L-moments by Hosking (J R Stat Soc Ser B Methodol 52(2):105–124, 1990), and the LH-moments by Wang (Water Resour Res 33(12):2841–2848, 1997) are re-visited. New relationships are developed for regional homogeneity analysis by the LH-moments, and further establishment of regional homogeneity is investigated. Previous works of Hosking (J R Stat Soc Ser B Methodol 52(2):105–124, 1990) and Wang (Water Resour Res 33(12):2841–2848, 1997) on L-moments and LH-moments for the generalized extreme value (GEV) distribution are extended to the generalized Pareto (GPA) and the generalized logistic (GLO) distributions. The Karkhe watershed, located in western Iran is used as a case study area. Regional homogeneity was investigated by first assuming the entire study area as one regional cluster. Then the entire study area was designated “homogeneous” by the L-moments (L); and was designated “heterogeneous” by all four levels of the LH-moments (L1 to L4). The k-means method was used to investigate the case of two regional clusters. All levels of the L- and LH-moments designated the upper watershed (region A), “homogeneous”, and the lower watershed (region B) “possibly-homogeneous”. The L3 level of the GPA and the L4 level of the GLO were selected for regions A and B, respectively. Wang (Water Resour Res 33(12):2841–2848, 1997) identified a reversing trend in improved performance of the GEV distribution at the LH-moments level of L3 (during the goodness-of-fit test). Similar results were also obtained in this research for the GEV distribution. However, for the case of the GPA distribution the reversing trend started at L4 for region A; and at L2 for region B. As for the case of the GLO, an improved performance was observed for all levels (moving from L to L4); for both regions.  相似文献   
40.
Thermal recovery from a hot dry rock (HDR) reservoir viewed as a deformable fractured medium is investigated with a focus on the assumption of local thermal non‐equilibrium (LTNE). Hydraulic diffusion, thermal diffusion, forced convection and deformation are considered in a two‐phase framework, the solid phase being made by impermeable solid blocks separated by saturated fractures. The finite element approximation of the constitutive and field equations is formulated and applied to obtain the response of a generic HDR reservoir to circulation tests. A change of time profile of the outlet fluid temperature is observed as the fracture spacing increases, switching from a single‐step pattern to a double‐step pattern, a feature which is viewed as characteristic of established LTNE. A dimensionless number is proposed to delineate between local thermal equilibrium (LTE) and non‐equilibrium. This number embodies local physical properties of the mixture, elements of the geometry of the reservoir and the production flow rate. All the above properties being fixed, the resulting fracture spacing threshold between LTNE and LTE is found to decrease with increasing porosity or fluid velocity. The thermally induced effective stress is tensile near the injection well, illustrating the thermal contraction of the rock, while the pressure contribution of the fracture fluid is negligible during the late period. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   
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