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381.
Air pollution has been a major transboundary problem and a matter of global concern for decades. Climate change and air pollution are closely coupled. Just as air pollution can have adverse effects on human health and ecosystems, it can also impact the earth’s climate. As we enter an era of rapid climate change, the implications for air quality need to be better understood, both for the purpose of air quality management and as one of the societal consequences of climate change. In this study, an attempt has been made to estimate the current air quality to forecast the air quality index of an urban station Kolkata (22.65°N, 88.45°E), India for the next 5 years with neural network models. The annual and seasonal variability in the air quality indicates that the winter season is mostly affected by the pollutants. Air quality index (AQI) is estimated as a geometric mean of the pollutants considered. Different neural network models are attempted to select the best model to forecast the AQI of Kolkata. The meteorological parameters and AQI of the previous day are utilized to train the models to forecast the AQI of the next day during the period from 2003 to 2012. The selection of the best model is made after validation with observation from 2013 to 2015. The radial basis functional (RBF) model is found to be the best network model for the purpose. The RBF model with various architectures is tried to obtain precise forecast with minimum error. RBF of 5:5-91-1:1 structure is found to be the best fit for forecasting the AQI of Kolkata. 相似文献
382.
Calcium Carbonate and Phosphate Reference Materials for Monitoring Bulk and Microanalytical Determination of Sr Isotopes 下载免费PDF全文
Michael Weber Federico Lugli Klaus Peter Jochum Anna Cipriani Denis Scholz 《Geostandards and Geoanalytical Research》2018,42(1):77-89
In situ laser ablation analyses rely on the microanalytical homogeneity of reference materials (RMs) and a similar matrix and mass fraction between unknown samples and RMs to obtain reliable results. Suitable carbonate and phosphate RMs for determination of Sr isotope ratios in such materials are limited. Thus, we determined 87Sr/86Sr ratios of several carbonate (JCt‐1, JCp‐1, MACS‐1, MACS‐3) and phosphate (MAPS‐4, MAPS‐5, NIST SRM 1400, NIST SRM 1486) international RMs using dissolved samples and two different multi‐collector inductively coupled plasma‐mass spectrometers (MC‐ICP‐MS). Our Sr isotope data are in agreement with published data and have an improved measurement precision for some RMs. For MACS‐1, we present the first 87Sr/86Sr value. We tested the suitability of these materials for microanalytical analyses by LA‐MC‐ICP‐MS, with two different laser ablation systems: a conventional nanosecond laser and a state‐of‐the‐art femtosecond laser. We investigated the RMs micro‐homogeneity and compared the data with our solution data. Both laser ablation systems yielded identical 87Sr/86Sr ratios within uncertainty to the solution data for RMs with low interferences of REEs. Therefore, these carbonate and phosphate RMs can be used to achieve accurate and precise results for in situ Sr isotope investigations by LA‐MC‐ICP‐MS of similar materials. 相似文献
383.
C.L. Djebebe-Ndjiguim A. Denis E. Foto G. Moloto-a-Kenguemba H. Celle-Jeanton 《水文科学杂志》2013,58(8):1760-1778
AbstractThis paper presents the results of a survey carried out in 2010 aimed at evaluating the type and quality of the groundwater resources of the Bangui region of the Central African Republic. This work is the first step towards the development of groundwater resources in the Central African Republic in order to find alternatives to direct pumping from the Ubangi River and provide the population of the suburbs with a safer drinking water supply from deep boreholes. By combining both geological and hydrogeochemical approaches, it appears that the geology of Bangui is favourable to the development of a secure and sustainable water supply from groundwater provided that the conditions of exploitation would be constrained by the local authorities. The deep Precambrian carbonate aquifers, known as the Bimbo and Fatima formations, are identified as target resources in view of the relatively good quality of their water from the chemical point of view, and the semi-confined structure of the aquifers that prevents the mixing with shallow aquifers that are already strongly affected by domestic and industrial pollution. The main difficulty in terms of exploitation is to appreciate the depth of the resource and the more or less fractured/palaeo-karstified type of the porosity.Editor Z.W. KundzewiczCitation Djebebe-Ndjiguim, C.L., Huneau, F., Denis, A., Foto, E., Moloto-a-Kenguemba, G., Celle-Jeanton, H., Garel, E., Jaunat, J., Mabingui, J., and Le Coustumer, P., 2013. Characterization of the aquifers of the Bangui urban area, Central African Republic, as an alternative drinking water supply resource. Hydrological Sciences Journal, 58 (8), 1760–1778. 相似文献
384.
Laura Valentina Socco Denis Jongmans Daniele Boiero Stefano Stocco Margherita Maraschini Ken Tokeshi Didier Hantz 《Journal of Applied Geophysics》2010,70(4):277-291
In the study of rock avalanche phenomena, numerical modelling makes use of back analyses of the rock avalanche propagation for calibration of the modelling assumptions and parameters. The back analyses require knowledge of the run-out area boundaries and the thickness distribution of the deposit. Geophysical methods can be applied to retrieve the thickness distribution, but, due to strong heterogeneities and logistic problems they are seldom applied. The aim of this work is to assess the potential of integrated geophysical methods to recognise and characterise a deposit created by two rock avalanches which occurred in the Sandalp valley (Switzerland) in 1996. The topography of the site before and after the rock avalanche is known and can be used as a benchmark. Resistivity tomography, seismic P-wave tomography, and active and passive surface wave analysis have been applied on several profiles deployed both on the rock avalanche deposit and in the surrounding area. Innovative approaches for surface wave analysis based on laterally constrained inversion and multimodal inversion have been applied to the data. A comparison of the results of the geophysical investigations with the topographic benchmark has shown the capability of the geophysical methods to locate the bottom of the deposit in the areas where the contrast with the host sediments properties is significant. In these areas, the deposit has higher resistivities and lower seismic velocities than the underlying materials. In the areas where the deposit is thicker and richer in fine-grained materials the geophysical parameters are not able to discriminate between the rock avalanche deposit and the underlying sediments. As a secondary task, the geophysical methods also allowed the bedrock pattern to be outlined. 相似文献
385.
Denis Samyn Sean J. Fitzsimons Reginald D. Lorrain 《International Journal of Earth Sciences》2010,99(8):1849-1857
Structural analyses were conducted in the basal zone of an Antarctic glacier. The studied basal ice sequence was retrieved
from a 20-m-long subglacial tunnel dug at the margin of the glacier and is at the temperature of −17°C. For the first time,
rotating clast systems embedded within debris-rich ice were thin-sectioned using specially designed cutting techniques. The
observed structures reflect the occurrence of pervasive shearing at the base of the glacier, and can be used as shear sense
indicators. In addition, some of these structures provide evidence for the presence of thin liquid films at the time of formation
despite the marked freezing temperature of the ice. It is showed here that cautious analysis of deformation structures present
in debris-bearing ice may bring insights not only into the flow dynamics of the embedding matrix, but also into the behaviour
of the interstitial fluid network at the base of cold glaciers and ice sheets. 相似文献
386.
Geochemical study of clays used as barriers in landfills 总被引:1,自引:0,他引:1
This is a hydraulic and geochemical study on 2 materials: natural clay (AN) and a regenerated material made up of a sand-bentonite (SB) mixture. The hydraulic part allowed us to conclude that a 10% industrial bentonite content mixed with sand offers hydraulic properties that are similar to those of AN material and are lower than the required standards. The geochemical properties of both AN and SB matrixes are comparable with those of some of the synthetic leachates studied. Furthermore, the Langmuir model helped us to identify the adsorption capacities of both matrixes with the following selectivities: Pb > Cu > Cd > Zn. 相似文献
387.
This study is the result of many years of research on the ecology of the marine benthos of Russian Arctic seas. We used samples collected at various locations from the Russian continental shelf during 1993–2009 as the basis of our study. Our main aim was to analyze the spatial distribution of taxonomic and quantitative characteristics of the meiobenthos (small bottom-dwelling animals, 0.1–3.0 mm in size). Statistical analysis of the data revealed that the factors determining the spatial distribution of meiobenthic organisms under natural conditions, and conditions impacted upon by human activity, were salinity, water depth, hydrocarbons, heavy metals and radiocaesium volumetric activity. The possible use of the meiobenthos as a tool for environmental impact assessment is proposed and discussed on the level of higher taxa. 相似文献
388.
Massimo Chiaradia Othmar Müntener Bernardo Beate Denis Fontignie 《Contributions to Mineralogy and Petrology》2009,158(5):563-588
In the Northern Andes of Ecuador, a broad Quaternary volcanic arc with significant across-arc geochemical changes sits upon
continental crust consisting of accreted oceanic and continental terranes. Quaternary volcanic centers occur, from west to
east, along the Western Cordillera (frontal arc), in the Inter-Andean Depression and along the Eastern Cordillera (main arc),
and in the Sub-Andean Zone (back-arc). The adakite-like signatures of the frontal and main arc volcanoes have been interpreted
either as the result of slab melting plus subsequent slab melt–mantle interactions or of lower crustal melting, fractional
crystallization, and assimilation processes. In this paper, we present petrographic, geochemical, and isotopic (Sr, Nd, Pb)
data on dominantly andesitic to dacitic volcanic rocks as well as crustal xenolith and cumulate samples from five volcanic
centers (Pululagua, Pichincha, Ilalo, Chacana, Sumaco) forming a NW–SE transect at about 0° latitude and encompassing the
frontal (Pululagua, Pichincha), main (Ilalo, Chacana), and back-arc (Sumaco) chains. All rocks display typical subduction-related
geochemical signatures, such as Nb and Ta negative anomalies and LILE enrichment. They show a relative depletion of fluid-mobile
elements and a general increase in incompatible elements from the front to the back-arc suggesting derivation from progressively
lower degrees of partial melting of the mantle wedge induced by decreasing amounts of fluids released from the slab. We observe
widespread petrographic evidence of interaction of primary melts with mafic xenoliths as well as with clinopyroxene- and/or
amphibole-bearing cumulates and of magma mixing at all frontal and main arc volcanic centers. Within each volcanic center,
rocks display correlations between evolution indices and radiogenic isotopes, although absolute variations of radiogenic isotopes
are small and their values are overall rather primitive (e.g., εNd = +1.5 to +6, 87Sr/86Sr = 0.7040–0.70435). Rare earth element patterns are characterized by variably fractionated light to heavy REE (La/YbN = 5.7–34) and by the absence of Eu negative anomalies suggesting evolution of these rocks with limited plagioclase fractionation.
We interpret the petrographic, geochemical, and isotopic data as indicating open-system evolution at all volcanic centers
characterized by fractional crystallization and magma mixing processes at different lower- to mid-crustal levels as well as
by assimilation of mafic lower crust and/or its partial melts. Thus, we propose that the adakite-like signatures of Ecuadorian
rocks (e.g., high Sr/Y and La/Yb values) are primarily the result of lower- to mid-crustal processing of mantle-derived melts,
rather than of slab melts and slab melt–mantle interactions. The isotopic signatures of the least evolved adakite-like rocks
of the active and recent volcanoes are the same as those of Tertiary ”normal” calc-alkaline magmatic rocks of Ecuador suggesting
that the source of the magma did not change through time. What changed was the depth of magmatic evolution, probably as a
consequence of increased compression induced by the stronger coupling between the subducting and overriding plates associated
with subduction of the aseismic Carnegie Ridge. 相似文献
389.
Laurent Koechlin Denis Serre Paul Deba Roser Pelló Christelle Peillon Paul Duchon Ana Ines Gomez de Castro Margarita Karovska Jean-Michel Désert David Ehrenreich Guillaume Hebrard Alain Lecavelier des Etangs Roger Ferlet David Sing Alfred Vidal-Madjar 《Experimental Astronomy》2009,23(1):379-402
The Fresnel Interferometric Imager has been proposed to the European Space Agency (ESA) Cosmic Vision plan as a class L mission.
This mission addresses several themes of the CV Plan: Exoplanet study, Matter in extreme conditions, and The Universe taking shape. This paper is an abridged version of the original ESA proposal. We have removed most of the technical and financial issues,
to concentrate on the instrumental design and astrophysical missions. The instrument proposed is an ultra-lightweight telescope,
featuring a novel optical concept based on diffraction focussing. It yields high dynamic range images, while releasing constraints
on positioning and manufacturing of the main optical elements. This concept should open the way to very large apertures in
space. In this two spacecraft formation-flying instrument, one spacecraft holds the focussing element: the Fresnel interferometric
array; the other spacecraft holds the field optics, focal instrumentation, and detectors. The Fresnel array proposed here
is a 3.6 ×3.6 m square opaque foil punched with 105 to 106 void “subapertures”. Focusing is achieved with no other optical element: the shape and positioning of the subapertures (holes
in the foil) is responsible for beam combining by diffraction, and 5% to 10% of the total incident light ends up into a sharp
focus. The consequence of this high number of subapertures is high dynamic range images. In addition, as it uses only a combination
of vacuum and opaque material, this focussing method is potentially efficient over a very broad wavelength domain. The focal
length of such diffractive focussing devices is wavelength dependent. However, this can be corrected. We have tested optically
the efficiency of the chromatism correction on artificial sources (500 < λ < 750 nm): the images are diffraction limited, and the dynamic range measured on an artificial double source reaches 6.2
10 − 6. We have also validated numerical simulation algorithms for larger Fresnel interferometric arrays. These simulations yield
a dynamic range (rejection factor) close to 10 − 8 for arrays such as the 3.6 m one we propose. A dynamic range of 10 − 8 allows detection of objects at contrasts as high as than 10 − 9 in most of the field. The astrophysical applications cover many objects in the IR, visible an UV domains. Examples are presented,
taking advantage of the high angular resolution and dynamic range capabilities of this concept. 相似文献
390.
Abstract Thirty-six fragments of meteorite falls, never touched by water or other possible sources of B contamination, were analyzed for B by prompt gamma-ray neutron activation analysis at McMaster University and at the U.S. National Institute of Standards and Technology. Boron concentrations are close to the sensitivity limit in both laboratories. Results between the two laboratories agree well but with slight systematic differences attributable to blank and background correction factors. The mean B concentrations in different meteorites are similar, from 0.5 to 1.1 ppm. The ranges in different CC, OC and ACH classes overlap, mostly from 0.4 to 1.4 ppm, which is similar to previous measurements on falls. The H, L and LL meteorites overlap in B content with Antarctic chondrites. The solar system abundance, taken as the mean B content of the matrix in all CC, was calculated from seven samples and is 0.69 ± 0.09 ppm. When normalized, this abundance is 16.9 ± 2.2 (atoms/106Si). Normalized B and S concentrations show a linear relationship in the CC; the average OC lies on the same line, but individual OCs are dispersed. 相似文献