Calcium Carbonate and Phosphate Reference Materials for Monitoring Bulk and Microanalytical Determination of Sr Isotopes          下载免费PDF全文

Michael Weber  Federico Lugli  Klaus Peter Jochum  Anna Cipriani  Denis Scholz 《Geostandards and Geoanalytical Research》2018,42(1):77-89

In situ laser ablation analyses rely on the microanalytical homogeneity of reference materials (RMs) and a similar matrix and mass fraction between unknown samples and RMs to obtain reliable results. Suitable carbonate and phosphate RMs for determination of Sr isotope ratios in such materials are limited. Thus, we determined ⁸⁷Sr/⁸⁶Sr ratios of several carbonate (JCt‐1, JCp‐1, MACS‐1, MACS‐3) and phosphate (MAPS‐4, MAPS‐5, NIST SRM 1400, NIST SRM 1486) international RMs using dissolved samples and two different multi‐collector inductively coupled plasma‐mass spectrometers (MC‐ICP‐MS). Our Sr isotope data are in agreement with published data and have an improved measurement precision for some RMs. For MACS‐1, we present the first ⁸⁷Sr/⁸⁶Sr value. We tested the suitability of these materials for microanalytical analyses by LA‐MC‐ICP‐MS, with two different laser ablation systems: a conventional nanosecond laser and a state‐of‐the‐art femtosecond laser. We investigated the RMs micro‐homogeneity and compared the data with our solution data. Both laser ablation systems yielded identical ⁸⁷Sr/⁸⁶Sr ratios within uncertainty to the solution data for RMs with low interferences of REEs. Therefore, these carbonate and phosphate RMs can be used to achieve accurate and precise results for in situ Sr isotope investigations by LA‐MC‐ICP‐MS of similar materials.  相似文献   

Assessing the performance and uncertainty analysis of the SWAT and RBNN models for simulation of sediment yield in the Nagwa watershed,India     

Ajai Singh  Mohd. Imtiyaz  R.K. Isaac  D.M. Denis 《水文科学杂志》2013,58(2):351-364

Abstract

The process-based Soil and Water Assessment Tool (SWAT) model and the data-driven radial basis neural network (RBNN) model were evaluated for simulating sediment load for the Nagwa watershed in Jharkhand, India, where soil erosion is a severe problem. The SWAT model calibration and uncertainty analysis were performed with the Sequential Uncertainty Fitting algorithm version 2 and the bootstrap technique was applied on the RBNN model to analyse uncertainty in model output. The percentage of data bracketed by the 95% prediction uncertainty (95PPU) and the r factor were the two measures used to assess the goodness of calibration. Comparison of the results of the two models shows that the value of r factor (r = 0.41) in the RBNN model is less than that of SWAT model (r = 0.79), which means there is a wider prediction interval for the SWAT model results. More values of observed sediment yield were bracketed by the 95PPU in the RBNN model. Thus, the RBNN model estimates the sediment yield values more accurately and with less uncertainty.

Editor D. Koutsoyiannis; Associate editor H. Aksoy

Citation Singh, A., Imtiyaz, M., Isaac, R.K., and Denis, D.M., 2014. Assessing the performance and uncertainty analysis of the SWAT and RBNN models for simulation of sediment yield in the Nagwa watershed, India. Hydrological Sciences Journal, 59 (2), 351–364.  相似文献   

Long-term relationships between climate oscillation and basin-scale hydrological variability during rainy season in eastern Northeast Brazil     

Denis Duda Costa  Cintia B. Uvo  Adriano Rolim Da Paz  Frede De Oliveira Carvalho  Carlos R. Fragoso Jr 《水文科学杂志》2013,58(11):1636-1652

ABSTRACT

The high variability in the hydrological regime of the Eastern Hydrological Region (EHR) of Northeast Brazil often results in floods and droughts, leading to serious socio-economic issues. Therefore, this work aimed to investigate connections between spatiotemporal hydrological variability of the EHR and large-scale climate phenomena. Multivariate statistical techniques were applied to relate climate indices with hydrological variables within two representative river basins in the EHR. The results indicated a multi-annual relationship between the state of the sea surface temperature of the Atlantic and Pacific oceans and anomalous hydrological variability in the basins. In addition, the northern Tropical Atlantic conditions were shown to play an important role in modulating the long-term variability of the hydrological response of the basins, whilst only extreme ENSO anomalies seemed to affect the rainy season. This knowledge is an important step towards long-term prediction of hydrological conditions and contributes to the improvement of water resources planning and management in the EHR.  相似文献   

Facing climatic and anthropogenic changes in the Mediterranean basin: What will be the medium-term impact on water stress?     

Marianne Milano  Denis Ruelland  Sara Fernandez  Alain Dezetter  Julie Fabre  Eric Servat 《Comptes Rendus Geoscience》2012,344(9):432-440

The Mediterranean basin has been identified as one of the world's most vulnerable regions to climatic and anthropogenic changes. A methodology accounting for the basin specific conditions is developed to assess the current and future water stress state of this region. The medium-term evolution of water stress is investigated using climatic scenarios and a water-use scenario based on efficiency improvements following the recommendations of the Mediterranean Strategy for Sustainable Development. Currently, the southern and eastern rims are experiencing high to severe water stress. By the 2050 horizon, a 30–50% decline in freshwater resources is simulated over most of the Mediterranean basin. While total water withdrawals would stabilize, or even decrease (10–40%), in several northern catchments, they would double in southern and eastern catchments. These changes should significantly increase water stress over the Mediterranean basin and exacerbate the disparities between rims.  相似文献   

Water quality and hydrogeochemistry of a basin and range watershed in a semi-arid region of northern New Mexico     

Benjamin Linhoff  Patrick Longmire  Michael Rearick  Denis McQuillan  George Perkins 《Environmental Earth Sciences》2016,75(8):640

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Evolution of calculations of the virtual dipole moment of the Earth for reconstructing the oceanic inversion magnetic layer’s parameters     

A. A. Schreider  A. A. Ignatova  Al. A. Schreider  A. E. Sajneva  P. Varga  C. Denis 《Oceanology》2016,56(3):428-434

The VDM (virtual dipole moment) is one of the most significant characteristics describing the behavior of the time evolution of the terrestrial magnetic field. However, we have revealed that the formulas with which VDM calculations are performed often do not coincide with each other in various literature sources. Hence, results are obtained from these calculations that cannot be identical. Their correctness is verified by comparing the dimension and obtained results with the known value of the VDM for our time.  相似文献   

Compressibility of Ca3Al2Si3O12 perovskite up to 55 GPa     

Steeve Gréaux  Denis Andrault  Laurent Gautron  Nathalie Bolfan-Casanova  Mohamed Mezouar 《Physics and Chemistry of Minerals》2014,41(6):419-429

Compressibility of perovskite-structured Ca₃Al₂Si₃O₁₂ grossular (GrPv) was investigated at high pressure and high temperature by means of angle-dispersive powder X-ray diffraction using a laser-heated diamond anvil cell. We observed the Pbnm orthorhombic distortion for the pure phase above 50 GPa, whereas below this pressure, Al-bearing CaSiO₃ perovskite coexists with an excess of corundum. GrPv has a bulk modulus (K ₀ = 229 ± 5 GPa; \(K_{0}^{{\prime }}\) fixed to 4) almost similar to that reported for pure CaSiO₃ perovskite. Its unit-cell volume extrapolated to ambient conditions (V ₀ = 187.1 ± 0.4 Å³) is found to be ~2.5 % larger than for the Al-free phase. We observe an increasing unit-cell anisotropy with increasing pressure, which could have implications for the shear properties of Ca-bearing perovskite in cold slabs subducted into the Earth’s mantle.  相似文献   

Advanced methods in landslide modelling     

Giulio Iovine  Denis Cohen 《Natural Hazards》2014,72(1):1-4

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Lake Shira Level Changes in Late Holocene     

Andrey DARIN  Ivan KALUGIN  Natalya MAKSIMOVA  Tatiana MARKOVICH  Yakov RAKSHUN  Dmitryi SOROKOLETOV  Fedor DARIN  Denis RAGOZIN 《《地质学报》英文版》2014,88(Z1):3-4

正1 Introduction Meromictic Shira Lake is a good represfor detail climate modeling due to its locainformation and annually laminated bottomsediment column of 155 cm in length wahammer corer in the deepest(24 m)central in 2009.2 Sample Preparations and Measuring  相似文献   

Katy?     

Denis Wood 《The Cartographic journal》2014,51(2):179-186

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