Mechanisms of weathering of meteorites recovered from hot and cold deserts and the formation of phyllosilicates     

Martin R. Lee  Philip A. Bland 《Geochimica et cosmochimica acta》2004,68(4):893-916

Petrographic, mineralogical and chemical analysis of naturally weathered equilibrated ordinary chondrites collected from ‘ hot’ deserts and Antarctica has revealed striking similarities and also pronounced differences in weathering between the two environments. Terrestrial weathering in all meteorites studied is dominated by oxidation and hydration of Fe,Ni metal, producing Fe-oxides and oxyhydroxides that have partially replaced the metal grains and have also occluded primary intergranular pores to form veins. Troilite weathers readily in ‘ hot’ desert environments but undergoes very little alteration under Antarctic conditions. Most of the primary porosity of ordinary chondrites has been occluded by the time that ∼ 15 to 25% of the initial Fe⁰ and Fe²⁺ has been oxidised to Fe³⁺ in both environments. Results from modelling the volume changes upon alteration of primary minerals to a range of weathering products demonstrates that the primary porosity of most meteorites is sufficient to accommodate weathering products. Dilation of primary pores and brecciation, which has been observed in parts of some meteorites, will only occur if the meteorite is especially metal-rich, or has a low primary porosity. These weathering products are absent from recent falls but have formed in a fall after ∼ 100 yr of museum storage.Cl-bearing akaganéite and hibbingite are common weathering products in Antarctic finds but occur in abundance in only one ‘ hot’ desert meteorite, Daraj 014. The majority of Fe-rich weathering products in meteorites from both environments contain low, but variable concentrations of Si, Mg and Ca. In most meteorites a proportion of these elements are inferred to be present as a very finely crystalline mineral with a ∼ 1.0-nm lattice fringe spacing; where seen within intragranular fractures this mineral has a topotactic relationship with olivine and orthopyroxene. In the heavily-weathered Antarctic finds ALHA 78045 and 77002, Si is concentrated in cronstedtite, a Fe-rich phyllosilicate. An unidentified hydrous Si-Fe-Ni-Mg mineral or gel has also partially replaced taenite in ALHA 78045. In addition to Fe-rich weathering products, ‘ hot’ desert meteorites contain sulphates, Ca-carbonate and silica, whereas such minerals are largely absent from Antarctic finds. The abundance of silicate weathering products in Antarctic meteorites is unexpected and indicates that olivine and pyroxene undergo significant chemical weathering in these environments. As preterrestrial cronstedtite is abundant in CM2 carbonaceous chondrites, the Antarctic environment may be a powerful analog for aqueous alteration in the asteroidal parent bodies of primitive meteorites.  相似文献   

Habitat requirements for submerged aquatic vegetation in Chesapeake Bay: Water quality, light regime, and physical-chemical factors   总被引：1，自引：0，他引：1  

W. Michael Kemp  Richard Batleson  Peter Bergstrom  Virginia Carter  Charles L. Gallegos  William Hunley  Lee Karrh  Evamaria W. Koch  Jurate M. Landwehr  Kenneth A. Moore  Laura Murray  Michael Naylor  Nancy B. Rybicki  J. Court Stevenson  David J. Wilcox 《Estuaries and Coasts》2004,27(3):363-377

We developed an algorithm for calculating habitat suitability for seagrasses and related submerged aquatic vegetation (SAV) at coastal sites where monitoring data are available for five water quality variables that govern light availability at the leaf surface. We developed independent estimates of the minimum light required for SAV survival both as a percentage of surface light passing though the water column to the depth of SAV growth (PLW _min) and as a percentage of light reaching reaching leaves through the epiphyte layer (PLL _min). Value were computed by applying, as inputs to this algorithm, statistically dervived values for water quality variables that correspond to thresholds for SAV presence in Chesapeake Bay. These estimates ofPLW _min andPLL _min compared well with the values established from a literature review. Calcultations account for tidal range, and total light attenuation is partitioned into water column and epiphyte contributions. Water column attenuation is further partitioned into effects of chlorophylla (chla), total suspended solids (TSS) and other substances. We used this algorithm to predict potential SAV presence throughout the Bay where calculated light available at plant leaves exceededPLL _min. Predictions closely matched results of aerial photographic monitoring surveys of SAV distribution. Correspondence between predictions and observations was particularly strong in the mesohaline and polythaline regions, which contain 75–80% of all potential SAV sites in this estuary. The method also allows for independent assessment of effects of physical and chemical factors other than light in limiting SAV growth and survival. Although this algorithm was developed with data from Chesapeake Bay, its general structure allows it to be calibrated and used as a quantitative tool for applying water quality data to define suitability of specific sites as habitats for SAV survival in diverse coastal environments worldwide.  相似文献   

Electromagnetic fields in a steel-cased borehole   总被引：1，自引：0，他引：1  

Ki Ha Lee  Hee Joon Kim  Toshihiro Uchida 《Geophysical Prospecting》2005,53(1):13-21

The development of an electromagnetic numerical modelling scheme for a magnetic dipole in an arbitrary casing segment in an inhomogeneous conductivity background has been difficult, due to the very high electrical conductivity and magnetic permeability contrasts between the steel casing and the background medium. To investigate the effect of steel casing efficiently, we have developed an accurate but simple finite‐element modelling scheme to simulate electromagnetic fields in a medium of cylindrically symmetric conductivity structures. In order to preserve the cylindrical symmetry in the resulting electromagnetic fields, a horizontal loop current source is used throughout. One of the main advantages of the approach is that the problem is scalar when formulated using the azimuthal electric field, even if the casing is both electrically conductive and magnetically permeable. Field calculations have been made inside the cased borehole as well as in another borehole which is not cased. Careful analyses of the numerical modelling results indicate that the anomaly observed in a cross‐borehole configuration is sensitive enough to be used for tomographic imaging.  相似文献   

The Devonian–Lower Carboniferous succession in Northwest Peninsular Malaysia     

Hakif Hassan Meor  Chai Peng Lee 《Journal of Asian Earth Sciences》2005,24(6):719

A new stratigraphic nomenclature is proposed for the approximately 600 m thick, mainly clastic transitional sequence between the underlying Mempelam Limestone and overlying Kubang Pasu/Singa Formation in northwest Peninsular Malaysia. This sequence represents shallow marine deposits of the continental margin of the Sibumasu Terrane during the Middle Palaeozoic (Devonian–Carboniferous). It is separated into several formations. The Timah Tasoh Formation is an approximately 76 m sequence consisting of 40 m of laminated tentaculitid shales at the base, containing Monograptus yukonensis Jackson and Lenz and Nowakia (Turkestanella) acuaria Alberti, giving an Early Devonian (Pragian–Emsian) age, and about 36 m of rhythmically interbedded, light coloured argillo-arenites. The Chepor Formation is about 90 m thick and consists mainly of thick red mudstone interbedded with sandstone beds, of Middle to Late Devonian age. A new limestone unit is recognized and named the Sanai Limestone, which contains conodonts of Famennian age. The Binjal Formation consists of red and white mudstone interbedded with sandstone beds showing Bouma sequences. The Telaga Jatoh Formation is 9 m thick and consists mainly of radiolarian chert. The Wang Kelian Formation is composed of thick red mudstone beds interbedded with silty sandstone, and contain fossils indicative of an Early Carboniferous (Visean) age. The succession was deposited on the outer shelf, with depositional environments vertically fluctuating from prodelta to basinal marine. The Devonian–Carboniferous boundary is exposed at Hutan Aji and Kampung Guar Jentik, and indicates a major regressive event during the latest Devonian.  相似文献   

Hydrochemistry of urban groundwater in Seoul, South Korea: effects of land-use and pollutant recharge   总被引：1，自引：0，他引：1  

Byoung-Young Choi  Seong-Taek Yun  Soon-Young Yu  Pyeong-Koo Lee  Seong-Sook Park  Gi-Tak Chae  Bernhard Mayer 《Environmental Geology》2005,48(8):979-990

The ionic and isotopic compositions (δD, δ¹⁸O, and ³H) of urban groundwaters have been monitored in Seoul to examine the water quality in relation to land-use. High tritium contents (6.1–12.0 TU) and the absence of spatial/seasonal change of O–H isotope data indicate that groundwaters are well mixed within aquifers with recently recharged waters of high contamination susceptibility. Statistical analyses show a spatial variation of major ions in relation to land-use type. The major ion concentrations tend to increase with anthropogenic contamination, due to the local pollutants recharge. The TDS concentration appears to be a useful contamination indicator, as it generally increases by the order of forested green zone (average 151 mg/l), agricultural area, residential area, traffic area, and industrialized area (average 585 mg/l). With the increased anthropogenic contamination, the groundwater chemistry changes from a Ca–HCO₃ type toward a Ca–Cl(+NO₃) type. The source and behavior of major ions are discussed and the hydrochemical backgrounds are proposed as the basis of a groundwater management plan.  相似文献   

地下圆形衬砌隧道对沿线地震动的影响(I):级数解     

梁建文  纪晓东  Vincent W Lee 《岩土力学》2005,(4)

利用波函数展开法,给出了地下圆形衬砌隧道对入射平面P波和SV波散射问题的一个级数解答,当衬砌与半空间介质相同时,该解答退化为文献中的无衬砌隧道的解答。级数解答为进一步定量研究隧道对入射平面P波和SV波的放大作用以及入射波长、入射角度、隧道直径和衬砌刚度等参数对隧道沿线地震动的影响奠定了理论基础。  相似文献   

Nb/Zr fractionation on the Moon and the search for extinct Nb     

Maria Schönbächler  Der-Chuen Lee  Mark Rehkämper  Bodo Hattendorf 《Geochimica et cosmochimica acta》2005,69(3):775-785

A comprehensive Zr isotopic study was conducted on eleven lunar basalts and highland rocks to search for evidence of the extinct nuclide ⁹²Nb, which decays to ⁹²Zr with a half-life of 36 Ma. Internal isochrons were determined for two early highland rocks, 77215 and 60025. No resolvable Zr isotopic variations were detected in this wide range of lunar samples and thus there is no evidence for the former existence of live ⁹²Nb on the Moon. The Nb/Zr ratios of lunar ilmenites and bulk rock samples vary by only a factor of two to three relative to the chondritic Nb/Zr ratio. No evidence for larger Nb/Zr fractionation was found. This limited fractionation and late isotopic closure of the source region prevents the formation of measurable ⁹²Zr anomalies in high-Ti mare basalts. As a consequence, it is not possible to draw conclusions from the ⁹²Nb-⁹²Zr chronometer about the timing of early lunar differentiation and to constrain the role of ilmenite in the source region of high-Ti mare basalts. However, the fractionation is still sufficient to deduce an upper limit for the initial ⁹²Nb/⁹³Nb ratio of the solar system of <5 × 10⁻⁴.  相似文献   

Hydrogeochemical Anomalies in the Springs of the Chiayi Area in West-central Taiwan as Possible Precursors to Earthquakes   总被引：1，自引：0，他引：1  

S. R. Song  W. Y. Ku  Y. L. Chen  C. M. Liu  H. F. Chen  P. S. Chan  Y. G. Chen  T. F. Yang  C. H. Chen  T. K. Liu  M. Lee 《Pure and Applied Geophysics》2006,163(4):675-691

Water samples from both hot and artesian springs in Kuantzeling in west-central Taiwan have been collected on a regular basis from July 15, 1999 to the end of August 2001 to measure cation and anion concentrations as a tool to detect major earthquake precursors. The data identify chloride and sulfate ion anomalies few days prior to major quakes and lasting a few days afterward. These anomalies are characterized by increases in Cl^- concentrations from 34.9% to 41.2% and 71.5% to 138.1% as well as increases in SO₄^2- concentrations from 232.7% to 276.8% and 100.0% to 155.1% above the means in both hot and artesian springs. The occurrence of these anomalies is probably explained first as stress/strain-induced pressure changes in the subsurface water systems which then generate precursory limited geochemical discharges at the levels of subsurface reservoirs. Therefore, finally leading to the mixing of previously separated subsurface water bodies occurs. This suggests that the hot and artesian springs in the Kuantzeling area are possible ideal sites for recording strain changes serving well as earthquake precursors.  相似文献   

Estimation of groundwater recharge using water balance coupled with base-flow-record estimation and stable-base-flow analysis   总被引：1，自引：0，他引：1  

Cheng-Haw Lee  Wei-Ping Chen  Ru-Huang Lee 《Environmental Geology》2006,51(1):73-82

In this paper, the long-term mean annual groundwater recharge of Taiwan is estimated with the help of a water-balance approach coupled with the base-flow-record estimation and stable-base-flow analysis. Long-term mean annual groundwater recharge was derived by determining the product of estimated long-term mean annual runoff (the difference between precipitation and evapotranspiration) and the base-flow index (BFI). The BFI was calculated from daily streamflow data obtained from streamflow gauging stations in Taiwan. Mapping was achieved by using geographic information systems (GIS) and geostatistics. The presented approach does not require complex hydrogeologic modeling or detailed knowledge of soil characteristics, vegetation cover, or land-use practices. Contours of the resulting long-term mean annual P, BFI, runoff, groundwater recharge, and recharge rates fields are well matched with the topographical distribution of Taiwan, which extends from mountain range toward the alluvial plains of the island. The total groundwater recharge of Taiwan obtained by the employed method is about 18 billion tons per year.An erratum to this article can be found at  相似文献   

Landslide susceptibility mapping in the Damrei Romel area, Cambodia using frequency ratio and logistic regression models   总被引：24，自引：0，他引：24  

Saro Lee  Touch Sambath 《Environmental Geology》2006,50(6):847-855

This study applied, tested and compared a probability model, a frequency ratio and statistical model, a logistic regression to Damre Romel area, Cambodia, using a geographic information system. For landslide susceptibility mapping, landslide locations were identified in the study area from interpretation of aerial photographs and field surveys, and a spatial database was constructed from topographic maps, geology and land cover. The factors that influence landslide occurrence, such as slope, aspect, curvature and distance from drainage were calculated from the topographic database. Lithology and distance from lineament were extracted and calculated from the geology database. Land cover was classified from Landsat TM satellite imagery. The relationship between the factors and the landslides was calculated using frequency ratio and logistic regression models. The relationships, frequency ratio and logistic regression coefficient were overlaid to make landslide susceptibility map. Then the landslide susceptibility map was compared with known landslide locations and tested. As the result, the frequency ratio model (86.97%) and the logistic regression (86.37%) had high and similar prediction accuracy. The landslide susceptibility map can be used to reduce hazards associated with landslides and to land cover planning.  相似文献