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71.
Abstract— Active capture is a new process for the incorporation of large quantities of heavy noble gases into growing surfaces. Adsorption in the conventional sense involves surface bonding by polarization (Van der Waals forces). What is referred to as “anomalous adsorption” of heavy noble gases involves chemical bonds and can occur when other (more chemically active) species are not available to preempt sites with unfilled bonds. Anomalous adsorption has been observed under conditions of fracture, vacuum deposition and ionizing radiation. Active capture depends upon anomalous adsorption to retain noble gases on a surface long enough to be captured in a growing surface film as it is deposited. The fundamental principle may be the impingement onto the growing film with sufficient energy to liberate surface electrons (work function energy of a few electronvolts) so that they are retained by anomalous adsorption long enough to be entrapped in the growing surface. Trapping efficiencies of ?1% have been observed for Kr and Xe in laboratory experiments, implying a fundamentally new mechanism for the incorporation of heavy noble gases onto surfaces. It may play a role in explaining the large concentrations of planetary noble gases contained in phase‐Q. 相似文献
72.
We present our observations of the galaxy UGS 5600 with a long-slit spectrograph (UAGS) and a multipupil field spectrograph (MPFS) attached to the 6-m Special Astrophysical Observatory telescope. Radial-velocity fields of the stellar and gaseous components were constructed for the central region and inner ring of the galaxy. We proved the existence of two nearly orthogonal kinematic subsystems and conclude that UGC 5600 is a galaxy with an inner polar ring. In the circumnuclear region, we detected noncircular stellar motions and suspected the existence of a minibar. The emission lines are shown to originate in H II regions. We estimated the metallicity from the intensity ratio of the [N II]λ6583 and Hα lines to be nearly solar, which rules out the possibility that the polar ring was produced by the accretion of gas from a dwarf companion. 相似文献
73.
We present our spectroscopic observations of the novae V1425, V1493, and V1494 Aql carried out with the 125-cm telescope at the Crimean Station of the Sternberg Astronomical Institute in the wavelength range 4000–11000 Å. We measured the emission-line intensities, determined the nova shell expansion velocities from the line profile FWHMs and components, and estimated the interstellar reddening from the first members of the Balmer series. The chemical composition of the nova shells is analyzed. Nitrogen and oxygen were found to be overabundant in V1425 and V1494 Aql; the helium abundance turned out to be normal in the two stars. 相似文献
74.
The magnetic-field distribution outside a flat, infinitely conductive unbounded disk in the field of a point magnetic dipole is determined. A relationship is established between the problem of magnetic-field determination and the problem of the flow of an ideal incompressible fluid around an infinitely thin disk. 相似文献
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青藏高原隆升的非线性动态有限元仿真研究 总被引:7,自引:4,他引:3
根据青藏高原的地质特征建立分析模型,采用3维动态有限元方法,在计算仿真板块速度场的基础上,计算在青藏高原的隆升过程中该地区地壳岩石的等效应力和位移随时间的变化,计算仿真得到的速度场与1998年GPS观测的速度场吻合良好;与过去一贯的假设相反,计算结果反映出地壳应力场不是静态的,而是此起彼伏,不断变化的,应力值最大且变化最剧烈的地区在克什米尔地区、鄂尔多斯地区和鲜水河-小江断裂带,与地震多发区域吻合。 相似文献
80.
The kinetics of the reactions of C2H radical with ethane (k1), propane (k2), and n-butane (k3) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C2H decay profiles in the presence of both the alkane reactant and O2 are monitored by the CH(A2Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k1(T) = (0.51 ± 0.06) × 10−10 exp[(−76 ± 30)K/T] cm3 molecule−1 s−1 (T = 96-800 K), k2(T) = (0.98 ± 0.32) × 10−10exp[(−71 ± 60)K/T] cm3 molecule−1 s−1 (T = 96-361 K), and k3(T) = (1.23 ± 0.26) × 10−10 cm3 molecule−1 s−1 (T = 96-297 K). At T = 296 K, k1 is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed. 相似文献